Abstract: A method of conversion of imines substituted with —X—R1 into amidines includes reacting a starting material compound including an imine that comprises —X—R1 bound to an imine carbon atom of the imine with a nitrogen-containing reagent to form a product compound including an amidine in place of the imine —X—R1 in the starting material compound. The nitrogen-containing reagent includes a primary amine, a secondary amine, an ammonium salt, or a combination thereof. The variable X is —S—, —O—, or —NH—. The variable R1 is substituted or unsubstituted (C1-C20) hydrocarbyl, wherein R1 is optionally bonded to a solid support. A method of forming a cyclized product includes intramolecularly reacting an amidine with a carbonyl carbon to form the cyclized product including a 4H-imidazolone and/or a derivative thereof.

Abstract: A method of conversion of thioimidates into amidines includes reacting a starting material compound including a thioimidate with a nitrogen-containing reagent to form a product compound including an amidine in place of the thioimidate in the starting material compound. The nitrogen-containing reagent includes a primary amine, a secondary amine, an ammonium salt, or a combination thereof. The thioimidate includes —S—R1, wherein R1 is substituted or unsubstituted (C1-C20)hydrocarbyl. A method of forming a cyclized product includes intramolecularly reacting an amidine with a carbonyl carbon to form the cyclized product including a 4H-imidazolone and/or a derivative thereof.

Abstract: Selective and efficient multifunctional nanoporous catalysts containing spatially distributed organoamine and silanol groups, and methods of preparation thereof. The catalysts have been observed to be very highly efficient in catalysis of the Henry reaction.

Abstract: Selective and efficient multifunctional nanoporous catalysts containing spatially distributed organoamine and silanol groups, and methods of preparation thereof. The catalysts have been observed to be very highly efficient in catalysis of the Henry reaction.

Abstract: Selective and efficient multifunctional nanoporous catalysts containing spatially distributed organoamine and silanol groups, and methods of preparation thereof. The catalysts have been observed to be very highly efficient in catalysis of the Henry reaction.