Abstract: The invention provides a waterproof self-luminescent spray-painted film with a thickness of 0.150-1.560 mm. The film has, from top to bottom, ink reception layer (1), connection layer (2) and light-storing photo-luminescent film (3); wherein the ink reception layer (1) is prepared by mixing inorganic filler, adhesive, color fixing agent, coupling agent, surfactant, cross-linking agent, fluorescent whitening agent and water at a ratio. The film has good waterproof property, rapid ink-drying, clear image after being ink-jet printed, and high color density. The film is self-luminescent after absorbing external visible light, and is visible and has the illumination function of low lighting intensity in darkness after a pattern or character is printed on the surface of the film. The film can be widely used in various occasions, such as home decoration, hotels, corridors, office buildings, cinemas, warehouses, ship cabins, underpasses and the places in need of large scale printing and high-precision patterns.