Patents by Inventor Kunihiko Ishizaki
Kunihiko Ishizaki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240253013Abstract: An object lies in providing a novel water-absorbing resin and a novel absorbent body both of which enable provision of an absorbent article that prevents swelling of a water-absorbing portion when used in a thin absorbent article. The object is achieved by providing a water-absorbing resin that is a particulate poly(meth)acrylic acid (salt)-based water-absorbing resin and has a swollen gel compressibility rate of 3% or more expressed by Formula 1: Swollen gel compressibility rate [%]=(D1?D2)/D1×100 (Formula 1), where D1 represents a thickness of a swollen gel before compression, and D2 represents a thickness of a swollen gel after compression.Type: ApplicationFiled: April 25, 2022Publication date: August 1, 2024Inventors: Sachie KITABATA, Satoshi MATSUMOTO, Kanako TSURU, Kunihiko ISHIZAKI
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Patent number: 12030997Abstract: A production method includes a surface-crosslinking step of heating a mixture of a surface-crosslinking agent and a particulate dried polymer obtained with an acid group-containing unsaturated monomer as a main component. A moisture content of the particulate dried polymer is not greater than 15% by mass. A heating device including a rotary container and a plurality of heating tubes that are located within the rotary container, extend in an axial direction of the rotary container, and rotate together with the rotary container, is used in the surface-crosslinking step. The heating device includes a means for introducing and discharging a gas into and from the rotary container.Type: GrantFiled: May 15, 2019Date of Patent: July 9, 2024Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Ryota Wakabayashi, Shin-ichi Fujino, Mai Sato, Yoshihiro Shobo, Shin-ya Katsube, Kunihiko Ishizaki
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Patent number: 11970585Abstract: The present invention addresses the problem of reducing the undried residue when recycling a fine powder of water-absorbing resin. The present invention is a method for producing a water-absorbing resin, wherein: a fine powder recycling step includes vi-1) a granulation step for obtaining a granulated gel, vi-2) a granulated gel addition step, and vi-3) a gel mixing step; the solids content of the granulated gel in the granulated gel addition step is 50-90% by mass; and the temperature of the granulated gel and the temperature of the water-containing gel-like crosslinked polymer is 50-100° C.Type: GrantFiled: May 16, 2019Date of Patent: April 30, 2024Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Satoshi Matsumoto, Kenji Kadonaga, Kunihiko Ishizaki
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Patent number: 11931290Abstract: An object of the present invention is to provide a water absorbent resin powder for a heat-generating element composition, which suppresses the generation of the aggregates derived from the water absorbent resin and the adhesion of the water absorbent resin in the production of a heat-generating element composition. A present inventive water absorbent resin powder for a heat-generating element composition includes polyacrylic acid (salt)-based water absorbent resin powder which have a bulk specific gravity (specified by JIS K3362) of 0.630 g/cm3 or less, fluid retention capacity without load (CRC) for a 0.9% by weight aqueous solution of sodium chloride (specified by ERT441.01-2) of 32.0 g/g or less, a weight-average particle diameter (specified by sieve classification) of 250 ?m or more, and an amount of a residual glycidyl-based crosslinking agent of 10 ppm or less.Type: GrantFiled: December 21, 2018Date of Patent: March 19, 2024Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Sachie Kitabata, Shigeru Sakamoto, Sumito Kumagai, Kozo Nogi, Kunihiko Ishizaki
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Patent number: 11766659Abstract: The production method includes a drying step of drying a particulate crosslinked hydrogel polymer obtained by polymerizing a monomer, which is a material of a water-absorbent resin, using a heating device to obtain dried particles. The heating device includes: a rotary container that contains the particulate crosslinked hydrogel polymer therein and rotates; and a plurality of heating tubes that are located within the rotary container, extend in an axial direction of the rotary container, and rotate together with the rotary container. A gel temperature of the particulate crosslinked hydrogel polymer to be subjected to the drying step, the gel temperature being measured by a contact thermometer, is not lower than 50° C.Type: GrantFiled: November 16, 2017Date of Patent: September 26, 2023Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Hiroyasu Watabe, Mai Sato, Ryota Wakabayashi, Yoshihiro Shobo, Shin-ya Katsube, Motohiro Imura, Koji Honda, Shin-ichi Fujino, Kunihiko Ishizaki, Tokio Shuto
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Patent number: 11465126Abstract: The production method includes: a gel-crushing step of grinding a crosslinked hydrogel polymer to obtain a particulate crosslinked hydrogel polymer; a heating drying step of obtaining dried particles from the particulate crosslinked hydrogel polymer by using a continuous stirring drying machine; a post-crosslinking step of post-crosslinking the particulate crosslinked hydrogel polymer or the dried particles; and a sizing step of adjusting a particle size of the dried particles or the post-crosslinked dried particles to obtain water-absorbent resin powder. The particulate crosslinked hydrogel polymer contains a gel fluidizer. A gel temperature of the particulate crosslinked hydrogel polymer containing the gel fluidizer, the gel temperature being measured by a contact thermometer, is not lower than 50° C. In the production method, the dried particles or the post-crosslinked dried particles is forcedly cooled before the sizing step.Type: GrantFiled: November 16, 2017Date of Patent: October 11, 2022Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Hiroyasu Watabe, Mai Sato, Ryota Wakabayashi, Yoshihiro Shobo, Shin-ya Katsube, Motohiro Imura, Koji Honda, Yoshifumi Adachi, Tsuyoshi Yorino, Masafumi Inoue, Tomoyuki Arake, Hiroki Hayashi, Naoki Katakura, Shin-ichi Fujino, Kunihiko Ishizaki, Tokio Shuto
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Publication number: 20220212995Abstract: Provided is an additive for concrete in which viscosity of a cement composition is low and fluidity is high at an initial stage of casting even when the additive is added, and long-term strength of concrete or the like improves by the addition. A cement additive comprising a water-absorbent resin, wherein the water-absorbent resin is formed by polymerizing a monomer mixture containing no less than 50 mol % of a nonionic non-crosslinkable monomer and no less than 0.1 mol % of a nonionic crosslinkable monomer, and a content of an anionic monomer in the monomer mixture is no more than 20 mol %.Type: ApplicationFiled: March 24, 2020Publication date: July 7, 2022Inventors: Takeshi TAKAYAMA, Kunihiko ISHIZAKI, Shigeru SAKAMOTO
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Publication number: 20210269606Abstract: A production method includes a surface-crosslinking step of heating a mixture of a surface-crosslinking agent and a particulate dried polymer obtained with an acid group-containing unsaturated monomer as a main component. A moisture content of the particulate dried polymer is not greater than 15% by mass. A heating device including a rotary container and a plurality of heating tubes that are located within the rotary container, extend in an axial direction of the rotary container, and rotate together with the rotary container, is used in the surface-crosslinking step. The heating device includes a means for introducing and discharging a gas into and from the rotary container.Type: ApplicationFiled: May 15, 2019Publication date: September 2, 2021Applicant: Nippon Shokubai Co., Ltd.Inventors: Ryota WAKABAYASHI, Shin-ichi FUJINO, Mai SATO, Yoshihiro SHOBO, Shin-ya KATSUBE, Kunihiko ISHIZAKI
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Publication number: 20210147637Abstract: The present invention addresses the problem of reducing the undried residue when recycling a fine powder of water-absorbing resin. The present invention is a method for producing a water-absorbing resin, wherein: a fine powder recycling step includes vi-1) a granulation step for obtaining a granulated gel, vi-2) a granulated gel addition step, and vi-3) a gel mixing step; the solids content of the granulated gel in the granulated gel addition step is 50-90% by mass; and the temperature of the granulated gel and the temperature of the water-containing gel-like crosslinked polymer is 50-100° C.Type: ApplicationFiled: May 16, 2019Publication date: May 20, 2021Inventors: Satoshi MATSUMOTO, Kenji KADONAGA, Kunihiko ISHIZAKI
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Publication number: 20210100684Abstract: An object of the present invention is to provide a water absorbent resin powder for a heat-generating element composition, which suppresses the generation of the aggregates derived from the water absorbent resin and the adhesion of the water absorbent resin in the production of a heat-generating element composition. A present inventive water absorbent resin powder for a heat-generating element composition includes polyacrylic acid (salt)-based water absorbent resin powder which have a bulk specific gravity (specified by JIS K3362) of 0.630 g/cm3 or less, fluid retention capacity without load (CRC) for a 0.9% by weight aqueous solution of sodium chloride (specified by ERT441.01-2) of 32.0 g/g or less, a weight-average particle diameter (specified by sieve classification) of 250 ?m or more, and an amount of a residual glycidyl-based crosslinking agent of 10 ppm or less.Type: ApplicationFiled: December 21, 2018Publication date: April 8, 2021Inventors: Sachie KITABATA, Shigeru SAKAMOTO, Sumito KUMAGAI, Kozo NOGI, Kunihiko ISHIZAKI
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Patent number: 10640588Abstract: Disclosed are a polyacrylate (salt) and a polyacrylate (salt) water-absorbent resin containing a tracer which can be verified back to the manufacturing process of the water-absorbent resin when dealing with various problems with the water-absorbent resin which can occur from the manufacturing process of the water-resistant resin, during the use thereof by a consumer, up until the disposal thereof. The disclosed polyacrylate (salt) and the polyacrylate (salt) water-absorbent resin have a carbon stable isotope ratio (?13C) of at least ?20‰ when measured by accelerator mass spectrometry.Type: GrantFiled: February 23, 2017Date of Patent: May 5, 2020Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Satoshi Matsumoto, Yuki Kabeya, Kunihiko Ishizaki, Shigeru Sakamoto
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Patent number: 10640593Abstract: A polyacrylic acid (salt), or a polyacrylic acid (salt)-based water-absorbing resin, contains a tracer for detecting various troubles in the water-absorbing resin during the period from the production of the water-absorbing resin to the use and discard thereof by a consumer. The polyacrylic acid (salt)-based water-absorbing resin has a stable carbon isotope ratio, as determined by accelerator mass spectrometry, of less than ?20‰ and a radioactive carbon content of 1.0×10?14 or more. The polyacrylic acid (salt)-based water-absorbing resin has: a CRC of 10 [g/g] or more; an AAP of 20 [g/g] or more; an Ext of 35 wt. % or less; a content of residual monomers of 1,000 ppm or less; a PSD in which the proportion of particles having a particle diameter of 150 ?m or larger but less than 850 ?m is 90 wt. % or more; and an FSR of 0.15 [g/g/s] or more.Type: GrantFiled: February 24, 2017Date of Patent: May 5, 2020Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Satoshi Matsumoto, Yuki Kabeya, Kunihiko Ishizaki, Yoshifumi Adachi
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Publication number: 20200023625Abstract: The present invention provides a water-absorbing sheet suitable for a hygienic material such as a disposable diaper. The water-absorbing sheet in accordance with an aspect of the present invention includes: a first base material; a second base material; and a particulate water-absorbing agent sandwiched between the first base material and the second base material, at least one of the first base material and the second base material being a water-permeable base material, and at least part of the particulate water-absorbing agent satisfying the following physical properties (1), (2), and (3): (1) a centrifuge retention capacity (CRC) is 30 g/g to 50 g/g; (2) a mass average particle diameter (D50) is 200 ?m to 600 ?m; and (3) a DRC index defined by the following Formula (a) is 43 or less: DRC index=(49?DRC5 min)/(D50/1000)?? Formula (a).Type: ApplicationFiled: February 22, 2018Publication date: January 23, 2020Inventors: Kazushi TORII, Kunihiko ISHIZAKI, Kazushi HORIE, Ryuichi HIRAOKA, Takahiro KITANO, Yasuhisa NAKAJIMA, Hiroyuki IKEUCHI, Katsuyuki WADA
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Patent number: 10537874Abstract: Provided is a method for producing a particulate water absorbing agent, the method including the steps of: a polymerization step of polymerizing an acrylic acid (salt)-based aqueous monomer solution so as to obtain a crosslinked hydrogel polymer; a drying step of drying the crosslinked hydrogel polymer so as to obtain a dried polymer; a classification step of classifying a polymer subjected to classification so as to obtain a water-absorbing resin powder having a specific particle size; and a surface-crosslinking step of surface-crosslinking the water-absorbing resin powder that is not surface crosslinked, wherein the classification step is carried out at least either or both of before and/or after the surface-crosslinking step but after said drying step, and wherein a hole shape of a classification sieve used in the classification step is an irregular polygonal or non-circular.Type: GrantFiled: March 30, 2016Date of Patent: January 21, 2020Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Kazushi Torii, Kunihiko Ishizaki, Shinichi Fujino, Ryota Wakabayashi, Motohiro Imura
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Patent number: 10493429Abstract: From a view pint of decreasing an out of spec product after surface crosslinking, particularly, when an alkylene carbonate compound is used as a surface crosslinking agent, influence due to an air temperature is great, and it is necessary to reduce ethylene glycol which is produced as a byproduct. There is provided a process for producing a polyacrylic acid (salt)-based water absorbent resin powder, comprising storing a non-polymerized organic compound being a raw material (modified raw material) of a water absorbent resin powder in a heated state, thereafter, mixing the non-polymerized organic compound with other compound at a predetermined ratio and, further, mixing the mixture into a water absorbent resin powder.Type: GrantFiled: January 30, 2012Date of Patent: December 3, 2019Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Kozo Nogi, Masatoshi Nakamura, Hirofumi Shibata, Koji Honda, Yusuke Watanabe, Satoshi Matsumoto, Reiko Nakatsuru, Kunihiko Ishizaki
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Patent number: 10472429Abstract: A method according to the present invention for producing water absorbent resin powder is a method for producing water absorbent resin having a surface cross-linked structure, and includes: a polymerization step in which an unsaturated monomer aqueous solution is polymerized; a drying step in which a hydrogel cross-linked polymer obtained in the polymerization step is dried; a surface treatment step in which the hydrogel cross-linked polymer or a dried hydrogel cross-linked polymer is subjected to a surface treatment; and a sorting step, carried out after the drying step, in which a foreign matter included in a water absorbent resin is color-sorted from the water absorbent resin entirely or partially. As a result, it is possible to obtain a water absorbent resin which has high properties and is less likely to be colored. In this way, there is provided the water absorbent resin powder production method in which the color sorting technique is used to remove foreign matters from the water absorbent resin.Type: GrantFiled: April 5, 2019Date of Patent: November 12, 2019Assignee: Nippon Shokubai Co., Ltd.Inventors: Katsuhiro Kajikawa, Sumio Okuda, Kazumasa Konishi, Kunihiko Ishizaki
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Publication number: 20190329220Abstract: The production method includes a drying step of drying a particulate crosslinked hydrogel polymer obtained by polymerizing a monomer, which is a material of a water-absorbent resin, using a heating device to obtain dried particles. The heating device includes: a rotary container that contains the particulate crosslinked hydrogel polymer therein and rotates; and a plurality of heating tubes that are located within the rotary container, extend in an axial direction of the rotary container, and rotate together with the rotary container. A gel temperature of the particulate crosslinked hydrogel polymer to be subjected to the drying step, the gel temperature being measured by a contact thermometer, is not lower than 50° C.Type: ApplicationFiled: November 16, 2017Publication date: October 31, 2019Inventors: Hiroyasu WATABE, Mai SATO, Ryota WAKABAYASHI, Yoshihiro SHOBO, Shin-ya KATSUBE, Motohiro IMURA, Koji HONDA, Shin-ichi FUJINO, Kunihiko ISHIZAKI, Tokio SHUTO
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Publication number: 20190329219Abstract: The production method includes: a gel-crushing step of grinding a crosslinked hydrogel polymer to obtain a particulate crosslinked hydrogel polymer; a heating drying step of obtaining dried particles from the particulate crosslinked hydrogel polymer by using a continuous stirring drying machine; a post-crosslinking step of post-crosslinking the particulate crosslinked hydrogel polymer or the dried particles; and a sizing step of adjusting a particle size of the dried particles or the post-crosslinked dried particles to obtain water-absorbent resin powder. The particulate crosslinked hydrogel polymer contains a gel fluidizer. A gel temperature of the particulate crosslinked hydrogel polymer containing the gel fluidizer, the gel temperature being measured by a contact thermometer, is not lower than 50° C. In the production method, the dried particles or the post-crosslinked dried particles is forcedly cooled before the sizing step.Type: ApplicationFiled: November 16, 2017Publication date: October 31, 2019Inventors: Hiroyasu WATABE, Mai SATO, Ryota WAKABAYASHI, Yoshihiro SHOBO, Shin-ya KATSUBE, Motohiro IMURA, Koji HONDA, Yoshifumi ADACHI, Tsuyoshi YORINO, Masafumi INOUE, Tomoyuki ARAKE, Hiroki HAYASHI, Naoki KATAKURA, Shin-ichi FUJINO, Kunihiko ISHIZAKI, Tokio SHUTO
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Publication number: 20190233548Abstract: A method according to the present invention for producing water absorbent resin powder is a method for producing water absorbent resin having a surface cross-linked structure, and includes: a polymerization step in which an unsaturated monomer aqueous solution is polymerized; a drying step in which a hydrogel cross-linked polymer obtained in the polymerization step is dried; a surface treatment step in which the hydrogel cross-linked polymer or a dried hydrogel cross-linked polymer is subjected to a surface treatment; and a sorting step, carried out after the drying step, in which a foreign matter included in a water absorbent resin is color-sorted from the water absorbent resin entirely or partially. As a result, it is possible to obtain a water absorbent resin which has high properties and is less likely to be colored. In this way, there is provided the water absorbent resin powder production method in which the color sorting technique is used to remove foreign matters from the water absorbent resin.Type: ApplicationFiled: April 5, 2019Publication date: August 1, 2019Inventors: Katsuhiro Kajikawa, Sumio Okuda, Kazumasa Konishi, Kunihiko Ishizaki
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Patent number: 10307506Abstract: The disclosed process for continuously producing a water-absorbing resin comprising a plurality of joined continuous steps; a polymerization step of polymerizing an aqueous unsaturated monomer solution, a drying step of drying a particulated water-containing gel-like crosslinked polymer obtained in a finely crushing step during the polymerization or after the polymerization, a pulverizing step after the drying, a classification step after the drying, and a surface treatment step for the water-absorbing resin powder after the classification step. In the process, with some of the above steps kept running, the other steps are interrupted, and subsequently all the steps are restarted.Type: GrantFiled: March 14, 2011Date of Patent: June 4, 2019Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Syuji Kanzaki, Sumio Okuda, Kunihiko Ishizaki, Satoshi Matsumoto