Abstract: A synchronizer ring performing synchronous sliding operation with and separating operation from a rotating object member, is composed of an Fe sintered alloy. The Fe sintered alloy comprises carbon of from 1.2 wt. % to 2.0 wt. %, copper of from over 15.0 wt. % to 25.0 wt. %, and the balance being iron and incidental impurities. A free Cu phase is precipitated in a matrix of the synchronizer ring. The synchronizer ring has a high scuffing resistance, an excellent friction characteristic, and sufficient abrasion resisting property and strength, and moreover, provides an easy manufacture thereof by means of a size working and is stable in quality.