Patents by Inventor Kunihiro Shima

Kunihiro Shima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11807925
    Abstract: A probe pin material including a Ag—Pd—Cu-based alloy essentially including Ag, Pd and Cu, B as a first additive element, and at least any element of Zn, Bi and Sn, as a second additive element. A concentration of the first additive element is 0.1 mass % or more and 1.5 mass % or less, and a concentration of the second additive element is 0.1 mass % or more and 1.0 mass % or less. A Ag concentration, a Pd concentration and a Cu concentration in the Ag—Pd—Cu-based alloy are required as follows: a Ag concentration (SAg), a Pd concentration (SPd) and a Cu concentration (SCu) converted as given that a Ag—Pd—Cu ternary alloy is formed from only such three elements all fall within a predetermined range in a Ag—Pd—Cu ternary system phase diagram. The probe pin material is excellent in resistance value and hardness/wear resistance, and also is enhanced in bending resistance.
    Type: Grant
    Filed: November 7, 2022
    Date of Patent: November 7, 2023
    Assignee: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Takeshi Fuse, Kunihiro Shima, Takeyuki Sagae, Shinji Kouno
  • Patent number: 11795527
    Abstract: The present invention relates to an alloy for medical use, including Pt, Co, Cr, Ni, and Mo. The alloy includes 10 atom % or more and 30 atom % or less of Pt, 20 atom % or more and 31 atom % or less of Cr, 5 atom % or more and 24 atom % or less of Ni, 4 atom % or more and 8 atom % or less of Mo, the balance Co, and unavoidable impurities, and a ratio of the Ni content (CNi) to the Pt content (CPt), CNi/CPt is 1.5 or less. The present invention can be applied to various kinds of devices for medical use, such as catheter, embolic coils, and guide wires, in addition to stents such as flow-diverter stents.
    Type: Grant
    Filed: November 18, 2019
    Date of Patent: October 24, 2023
    Assignee: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Shubham Yadav, Yuya Kato, Kenji Goto, Kunihiro Shima
  • Publication number: 20230250513
    Abstract: A probe pin material including a Ag—Pd—Cu-based alloy essentially including Ag, Pd and Cu, B as a first additive element, and at least any element of Zn, Bi and Sn, as a second additive element. A concentration of the first additive element is 0.1 mass % or more and 1.5 mass % or less, and a concentration of the second additive element is 0.1 mass % or more and 1.0 mass % or less. A Ag concentration, a Pd concentration and a Cu concentration in the Ag—Pd—Cu-based alloy are required as follows: a Ag concentration (SAg), a Pd concentration (SPd) and a Cu concentration (SCu) converted as given that a Ag—Pd—Cu ternary alloy is formed from only such three elements all fall within a predetermined range in a Ag—Pd—Cu ternary system phase diagram. The probe pin material is excellent in resistance value and hardness/wear resistance, and also is enhanced in bending resistance.
    Type: Application
    Filed: November 7, 2022
    Publication date: August 10, 2023
    Applicant: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Takeshi FUSE, Kunihiro SHIMA, Takeyuki SAGAE, Shinji KOUNO
  • Publication number: 20230113633
    Abstract: The present invention relates to a medical Au-Pt-Pd alloy including Au, Pt,Pd, and inevitable impurities. The Au-Pt-Pd alloy has an alloy compositioninside a polygon (A1-A2-A3-A4) surrounded by straight lines connected at pointA1 (Au: 53 atom%, Pt: 4 atom%, and Pd: 43 atom%), point A2 (Au: 70 atom%,Pt: 4 atom%, and Pd: 26 atom%), point A3 (Au: 69.9 atom%, Pt: 30 atom%, and Pd: 0.1 atom%), and point A4 (Au: 49.9 atom%, Pt: 50 atom%, and Pd: 0.1 atom%) in a Au-Pt-Pd ternary state diagram. In a metal structure of the alloy, at least one of a Au-rich phase and a Pt-rich phase is distributed, and the total of the area ratio of the Au-rich phase and the area ratio of the Pt-rich phase is 1.5% or more and 25.4% or less.
    Type: Application
    Filed: December 14, 2022
    Publication date: April 13, 2023
    Applicants: TANAKA KIKINZOKU KOGYO K.K., TOKUSHIMA UNIVERSITY
    Inventors: Michimasa OKUBO, Kenji GOTO, Kunihiro TANAKA, Kojiro SHIRAISHI, Kunihiro SHIMA, Yuya KATO, Kenichi HAMADA, Eiichi HONDA, Emi TAKEGAWA
  • Patent number: 11453931
    Abstract: The present invention relates to a medical Au—Pt—Pd alloy including Au, Pt, Pd, and inevitable impurities. The alloy has an alloy composition inside a polygon (A1-A2-A3-A4-A5-A6) surrounded by straight lines connected at point A1 (Au: 37.9 atom %, Pt: 0.1 atom %, and Pd: 62 atom %), point A2 (Au: 79.9 atom %, Pt: 0.1 atom %, and Pd: 20 atom %), point A3 (Au: 79.9 atom %, Pt: 20 atom %, and Pd: 0.1 atom %), point A4 (Au: 69.9 atom %, Pt: 30 atom %, and Pd: 0.1 atom %), point A5 (Au: 49 atom %, Pt: 30 atom %, and Pd: 21 atom %), and point A6 (Au: 39 atom %, Pt: 40 atom %, and Pd: 21 atom %) in a Au—Pt—Pd ternary state diagram. The metal structure of the alloy is optimized, and the metal structure is close to a single-phase structure, and has little precipitation of a Au-rich phase and a Pt-rich phase different in composition from a mother phase.
    Type: Grant
    Filed: September 24, 2020
    Date of Patent: September 27, 2022
    Assignees: TANAKA KIKINZOKU KOGYO K.K., TOKUSHIMA UNIVERSITY
    Inventors: Michimasa Okubo, Kenji Goto, Kunihiro Tanaka, Kojiro Shiraishi, Kunihiro Shima, Yuya Kato, Kenichi Hamada, Eiichi Honda, Emi Takegawa
  • Publication number: 20220213576
    Abstract: The present invention relates to a medical Au—Pt—Pd alloy including Au, Pt, Pd, and inevitable impurities. The alloy has an alloy composition inside a polygon (A1-A2-A3-A4-A5-A6) surrounded by straight lines connected at point A1 (Au: 37.9 atom %, Pt: 0.1 atom %, and Pd: 62 atom %), point A2 (Au: 79.9 atom %, Pt: 0.1 atom %, and Pd: 20 atom %), point A3 (Au: 79.9 atom %, Pt: 20 atom %, and Pd: 0.1 atom %), point A4 (Au: 69.9 atom %, Pt: 30 atom %, and Pd: 0.1 atom %), point A5 (Au: 49 atom %, Pt: 30 atom %, and Pd: 21 atom %), and point A6 (Au: 39 atom %, Pt: 40 atom %, and Pd: 21 atom %) in a Au—Pt—Pd ternary state diagram. The metal structure of the alloy is optimized, and the metal structure is close to a single-phase structure, and has little precipitation of a Au-rich phase and a Pt-rich phase different in composition from a mother phase.
    Type: Application
    Filed: September 24, 2020
    Publication date: July 7, 2022
    Applicants: TANAKA KIKINZOKU KOGYO K.K., TOKUSHIMA UNIVERSITY
    Inventors: Michimasa OKUBO, Kenji GOTO, Kunihiro TANAKA, Kojiro SHIRAISHI, Kunihiro SHIMA, Yuya KATO, Kenichi HAMADA, Eiichi HONDA, Emi TAKEGAWA
  • Patent number: 11345986
    Abstract: The present invention provides an alloy for medical use including an Au—Pt alloy, in which the Au—Pt alloy has a Pt concentration of 24 mass % or more and less than 34 mass % with the balance being Au, and has at least a material structure in which a Pt-rich phase having a Pt concentration higher than that of an ?-phase is distributed in an ?-phase matrix, the Pt-rich phase has a Pt concentration that is 1.2 to 3.8 times the Pt concentration of the ?-phase, and the Pt-rich phase has an area ratio of 1 to 22% in any cross-section. This alloy is an artifact-free alloy material that exhibits excellent compatibility with a magnetic field environment such as an MRI and has magnetic susceptibility of ±4 ppm with respect to magnetic susceptibility of water.
    Type: Grant
    Filed: October 22, 2020
    Date of Patent: May 31, 2022
    Assignees: TANAKA KIKINZOKU KOGYO K.K., KYOTO UNIVERSITY
    Inventors: Kunihiro Shima, Kenji Goto, Yasushi Masahiro, Asaka Ueno, Hiroo Iwata, Ryusuke Nakai, Tomonobu Kodama
  • Patent number: 11303099
    Abstract: The present invention discloses a spark plug electrode material including a substrate formed of Ir or Ir alloy, and an antioxidant film covering a surface of the substrate. Here, an underlying layer formed of Au is formed on a surface of the substrate formed of Ir or Ir alloy, and on the underlying layer, a Ni film having a thickness of 3.0 ?m or more and 8.0 ?m or less is formed as an antioxidant film. The Ni film turns into an antioxidant film formed of Ni oxide in an oxidizing atmosphere at 500° C. or higher. Owing to the antioxidant film, the spark plug electrode material of the present invention has an excellent high-temperature oxidation property.
    Type: Grant
    Filed: September 6, 2019
    Date of Patent: April 12, 2022
    Assignee: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Yuya Saito, Kunihiro Shima, Shinsuke Mano
  • Publication number: 20220042140
    Abstract: The present invention relates to a medical Au—Pt—Pd alloy including Au, Pt, Pd, and inevitable impurities. The Au—Pt—Pd alloy has an alloy composition inside a polygon (A1-A2-A3-A4) surrounded by straight lines connected at point A1 (Au: 53 atom %, Pt: 4 atom %, and Pd: 43 atom %), point A2 (Au: 70 atom %, Pt: 4 atom %, and Pd: 26 atom %), point A3 (Au: 69.9 atom %, Pt: 30 atom %, and Pd: 0.1 atom %), and point A4 (Au: 49.9 atom %, Pt: 50 atom %, and Pd: 0.1 atom %) in a Au—Pt—Pd ternary state diagram. In a metal structure of the alloy, at least one of a Au-rich phase and a Pt-rich phase is distributed, and the total of the area ratio of the Au-rich phase and the area ratio of the Pt-rich phase is 1.5% or more and 25.4% or less.
    Type: Application
    Filed: September 24, 2020
    Publication date: February 10, 2022
    Applicants: TANAKA KIKINZOKU KOGYO K.K., TOKUSHIMA UNIVERSITY
    Inventors: Michimasa OKUBO, Kenji GOTO, Kunihiro TANAKA, Kojiro SHIRAISHI, Kunihiro SHIMA, Yuya KATO, Kenichi HAMADA, Eiichi HONDA, Emi TAKEGAWA
  • Publication number: 20220017996
    Abstract: The present invention relates to an alloy for medical use, including Pt, Co, Cr, Ni, and Mo. The alloy includes 10 atom % or more and 30 atom % or less of Pt, 20 atom % or more and 31 atom % or less of Cr, 5 atom % or more and 24 atom % or less of Ni, 4 atom % or more and 8 atom % or less of Mo, the balance Co, and unavoidable impurities, and a ratio of the Ni content (CNi) to the Pt content (CPt), CNi/CPt is 1.5 or less. The present invention can be applied to various kinds of devices for medical use, such as catheter, embolic coils, and guide wires, in addition to stents such as flow-diverter stents.
    Type: Application
    Filed: November 18, 2019
    Publication date: January 20, 2022
    Applicant: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Shubham YADAV, Yuya KATO, Kenji GOTO, Kunihiro SHIMA
  • Publication number: 20210320480
    Abstract: The present invention discloses a spark plug electrode material including a substrate formed of Ir or Ir alloy, and an antioxidant film covering a surface of the substrate. Here, an underlying layer formed of Au is formed on a surface of the substrate formed of Ir or Ir alloy, and on the underlying layer, a Ni film having a thickness of 3.0 ?m or more and 8.0 ?m or less is formed as an antioxidant film. The Ni film turns into an antioxidant film formed of Ni oxide in an oxidizing atmosphere at 500° C. or higher. Owing to the antioxidant film, the spark plug electrode material of the present invention has an excellent high-temperature oxidation property.
    Type: Application
    Filed: September 6, 2019
    Publication date: October 14, 2021
    Applicant: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Yuya SAITO, Kunihiro SHIMA, Shinsuke MANO
  • Publication number: 20210047717
    Abstract: The present invention provides an alloy for medical use including an Au—Pt alloy, in which the Au—Pt alloy has a Pt concentration of 24 mass % or more and less than 34 mass % with the balance being Au, and has at least a material structure in which a Pt-rich phase having a Pt concentration higher than that of an ?-phase is distributed in an ?-phase matrix, the Pt-rich phase has a Pt concentration that is 1.2 to 3.8 times the Pt concentration of the ?-phase, and the Pt-rich phase has an area ratio of 1 to 22% in any cross-section. This alloy is an artifact-free alloy material that exhibits excellent compatibility with a magnetic field environment such as an MRI and has magnetic susceptibility of ±4 ppm with respect to magnetic susceptibility of water.
    Type: Application
    Filed: October 22, 2020
    Publication date: February 18, 2021
    Inventors: KUNIHIRO SHIMA, KENJI GOTO, YASUSHI MASAHIRO, ASAKA UENO, HIROO IWATA, RYUSUKE NAKAI, TOMONOBU KODAMA
  • Patent number: 10883162
    Abstract: The present invention provides an alloy for medical use including an Au—Pt alloy, in which the Au—Pt alloy has a Pt concentration of 24 mass % or more and less than 34 mass % with the balance being Au, and has at least a material structure in which a Pt-rich phase having a Pt concentration higher than that of an ?-phase is distributed in an ?-phase matrix, the Pt-rich phase has a Pt concentration that is 1.2 to 3.8 times the Pt concentration of the ?-phase, and the Pt-rich phase has an area ratio of 1 to 22% in any cross-section. This alloy is an artifact-free alloy material that exhibits excellent compatibility with a magnetic field environment such as an MRI and has magnetic susceptibility of ±4 ppm with respect to magnetic susceptibility of water.
    Type: Grant
    Filed: January 30, 2014
    Date of Patent: January 5, 2021
    Assignees: TANAKA KIKINZOKU KOGYO K.K., KYOTO UNIVERSITY
    Inventors: Kunihiro Shima, Kenji Goto, Yasushi Masahiro, Asaka Ueno, Hiroo Iwata, Ryusuke Nakai, Tomonobu Kodama
  • Patent number: 10220120
    Abstract: The present invention is an alloy for medical use including an Au—Pt alloy, containing 34 to 36 mass % of Pt with the balance being Au, and having an ?-phase single structure in which a ratio of a peak intensity (X) of a Pt (111) plane to a peak intensity (Y) of an Au (111) plane (X/Y) is 0.01 or less in an X-ray diffraction analysis. The alloy can be produced in such a manner that after the Au—Pt alloy ingot is molten and cast, cold working and a heat treatment for homogenization are performed at least two times on the molten and cast alloy. The alloy of the present invention is an artifact-free material that exhibits excellent compatibility with a magnetic field environment such as an MRI and has magnetic susceptibility of ±4 ppm with respect to that of water.
    Type: Grant
    Filed: January 30, 2014
    Date of Patent: March 5, 2019
    Assignees: TANAKA KIKINZOKU KOGYO K.K., KYOTO UNIVERSITY
    Inventors: Kunihiro Shima, Kenji Goto, Yasushi Masahiro, Asaka Ueno, Hiroo Iwata, Ryusuke Nakai, Tomonobu Kodama
  • Patent number: 10153072
    Abstract: The present invention provides a textured substrate for forming an epitaxial film, including a textured metal layer on at least one surface of the layer, the textured metal layer including a copper layer having a cube texture, the textured metal layer having, on a surface of the layer, palladium added in an amount of 10 to 300 ng/mm2 per unit area, the hydrogen content of the surface of the textured metal layer being 700 to 2000 ppm. This textured substrate is produced through a step of adding 10 to 300 ng/mm2 per unit area of palladium by strike plating to a surface of the copper layer having a cube texture.
    Type: Grant
    Filed: July 22, 2014
    Date of Patent: December 11, 2018
    Assignee: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Naoji Kashima, Tomonori Watanabe, Shigeo Nagaya, Kunihiro Shima, Shuichi Kubota, Ryosuke Suganuma
  • Publication number: 20170029927
    Abstract: The present invention provides an alloy for medical use including an Au—Pt alloy, in which the Au—Pt alloy has a Pt concentration of 24 mass % or more and less than 34 mass % with the balance being Au, and has at least a material structure in which a Pt-rich phase having a Pt concentration higher than that of an ?-phase is distributed in an ?-phase matrix, the Pt-rich phase has a Pt concentration that is 1.2 to 3.8 times the Pt concentration of the ?-phase, and the Pt-rich phase has an area ratio of 1 to 22% in any cross-section. This alloy is an artifact-free alloy material that exhibits excellent compatibility with a magnetic field environment such as an MRI and has magnetic susceptibility of ±4 ppm with respect to magnetic susceptibility of water.
    Type: Application
    Filed: January 30, 2014
    Publication date: February 2, 2017
    Applicants: TANAKA KIKINZOKU KOGYO K.K., KYOTO UNIVERSITY
    Inventors: Kunihiro SHIMA, Kenji GOTO, Yasushi MASAHIRO, Asaka UENO, Hiroo IWATA, Ryusuke NAKAI, Tomonobu KODAMA
  • Publication number: 20160367729
    Abstract: The present invention is an alloy for medical use including an Au—Pt alloy, containing 34 to 36 mass % of Pt with the balance being Au, and having an ?-phase single structure in which a ratio of a peak intensity (X) of a Pt (111) plane to a peak intensity (Y) of an Au (111) plane (X/Y) is 0.01 or less in an X-ray diffraction analysis. The alloy can be produced in such a manner that after the Au—Pt alloy ingot is molten and cast, cold working and a heat treatment for homogenization are performed at least two times on the molten and cast alloy. The alloy of the present invention is an artifact-free material that exhibits excellent compatibility with a magnetic field environment such as an MRI and has magnetic susceptibility of ±4 ppm with respect to that of water.
    Type: Application
    Filed: January 30, 2014
    Publication date: December 22, 2016
    Inventors: Kunihiro SHIMA, Kenji GOTO, Yasushi MASAHIRO, Asaka UENO, Hiroo IWATA, Ryusuke NAKAI, Tomonobu KODAMA
  • Publication number: 20160163425
    Abstract: The present invention provides a textured substrate for forming an epitaxial film, including a textured metal layer on at least one surface of the layer, the textured metal layer including a copper layer having a cube texture, the textured metal layer having, on a surface of the layer, palladium added in an amount of 10 to 300 ng/mm2 per unit area, the hydrogen content of the surface of the textured metal layer being 700 to 2000 ppm. This textured substrate is produced through a step of adding 10 to 300 ng/mm2 per unit area of palladium by strike plating to a surface of the copper layer having a cube texture.
    Type: Application
    Filed: July 22, 2014
    Publication date: June 9, 2016
    Inventors: Naoji KASHIMA, Tomonori WATANABE, Shigeo NAGAYA, Kunihiro SHIMA, Shuichi KUBOTA, Ryosuke SUGANUMA
  • Patent number: 9242433
    Abstract: The present invention relates to a textured substrate for epitaxial film formation, comprising a textured metal layer at least on one side, wherein the textured metal layer includes a copper layer having a cube texture and a nickel layer having a thickness of 100 to 20000 nm formed on the copper layer; the nickel layer has a nickel oxide layer formed on a surface thereof, having a thickness of 1 to 30 nm, and including a nickel oxide; and the nickel layer further includes a palladium-containing region formed of palladium-containing nickel at an interface with the nickel oxide layer. The top layer of the textured substrate, i.e. the nickel oxide layer, has a surface roughness of preferably 10 nm or less.
    Type: Grant
    Filed: March 21, 2013
    Date of Patent: January 26, 2016
    Assignee: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Naoji Kashima, Tomonori Watanabe, Shigeo Nagaya, Kunihiro Shima, Shuichi Kubota
  • Publication number: 20150094208
    Abstract: The present invention relates to a textured substrate for epitaxial film formation, comprising a textured metal layer at least on one side, wherein the textured metal layer includes a copper layer having a cube texture and a nickel layer having a thickness of 100 to 20000 nm formed on the copper layer; the nickel layer has a nickel oxide layer formed on a surface thereof, having a thickness of 1 to 30 nm, and including a nickel oxide; and the nickel layer further includes a palladium-containing region formed of palladium-containing nickel at an interface with the nickel oxide layer. The top layer of the textured substrate, i.e. the nickel oxide layer, has a surface roughness of preferably 10 nm or less.
    Type: Application
    Filed: March 21, 2013
    Publication date: April 2, 2015
    Applicant: TANAKA KIKINZOKU KOGYO K.K.
    Inventors: Naoji Kashimma, Tomonori Watanabe, Shigeo Nagaya, Kunihiro Shima, Shuichi Kubota