Patents by Inventor Kunizo Hashiba

Kunizo Hashiba has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5250713
    Abstract: A process for producing desulfurized fats and oils or fatty acid esters is disclosed, which comprises treating fats and oils or fatty acid esters under hydrogen or a mixture of hydrogen and an inert gas atmosphere at a pressure of from 0.1 to 500 kg/cm.sup.2 in the absolute pressure at a temperature of from 100.degree. to 350.degree. C. in the presence of a catalyst of the following formula (I):Cu.multidot.X.sub.x .multidot.Y.sub.y .multidot.O.sub.z (I)wherein all symbols are defined in the disclosure. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.
    Type: Grant
    Filed: March 11, 1992
    Date of Patent: October 5, 1993
    Assignee: Kao Corporation
    Inventors: Hiroyuki Tamura, Yasuyuki Hattori, Kunizo Hashiba, Osamu Tabata, Kiyoshi Tsukada, Noriaki Fukuoka
  • Patent number: 5233099
    Abstract: A process for producing an alcohol by continuously passing a fatty acid ester, a fatty acid triglyceride or a fatty acid through a hydrogenation catalyst to thereby produce the aimed alcohol through catalytic reduction is disclosed, wherein the employed reactor is a fixed bed reactor in which the liquid phase and the gas phase are continuously passed together in descending parallel flows through the hydrogenation catalyst fixed in the reactor; and at least one cooling mean for cooling the reaction system is provided at a position in the vertical direction of the reactor. According to the process of the present invention with the use of a fixed bed reactor, an alcohol, which has extremely high qualities and a high purity and is contaminated with little hydrocarbon and aldehyde by-products, can be produced. The process of the present invention further makes it possible to omit the post-treatment for eliminating the by-products.
    Type: Grant
    Filed: December 24, 1991
    Date of Patent: August 3, 1993
    Assignee: Kao Corporation
    Inventors: Osamu Tabata, Kunizo Hashiba, Takahiro Kawakami
  • Patent number: 5233100
    Abstract: A process for producing an alcohol from a fatty acid ester, a fatty acid triglyceride or a fatty acid by continuously catalytically reducing the starting material in the presence of a hydrogenation catalyst is disclosed. In the process of the present invention, two reactors (i.e., the main reactor located upstream and the after reactor located downstream) being located in series are employed. In the process of the present invention, two reactors are employed and the temperatures thereof are individually controlled, whereby the conversion ratio is elevated while suppressing the formation of hydrocarbon and aldehyde by-products. Thus, an alcohol of extremely high quality and high purity can be produced. Further, the process of the present invention makes it possible to omit any post-treatment for eliminating the by-products. Furthermore, the active life of the hydrogenation catalyst can be remarkably prolonged by using three reactors (i.e., the guard reactor, the main reactor and the after reactor).
    Type: Grant
    Filed: December 27, 1991
    Date of Patent: August 3, 1993
    Assignee: Kao Corporation
    Inventors: Osamu Tabata, Atsuhito Mori, Takahiro Kawakami, Kunizo Hashiba, Kiyoshi Tsukada
  • Patent number: 5120885
    Abstract: A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50.degree. to 200.degree. C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: June 9, 1992
    Assignee: Kao Corporation
    Inventors: Kiyoshi Tsukada, Yasuyuki Hattori, Hiroyuki Tamura, Akira Yamamuro, Kunizo Hashiba, Osamu Tabata
  • Patent number: 5079350
    Abstract: A process for the production of an alkyl glycoside or an aqueous solution thereof is disclosed, comprising the steps of (1) reacting a sugar with alcohol to obtain an alkyl glycoside reaction product containing unreacted alcohol, (2) establishing a moving liquid film of the alkyl glycoside reaction product and (3) contacting the moving liquid film with steam or an inert gas at a temperature of from 50.degree. to 200.degree. C. The alkyl glycoside or aqueous solution thus obtained contains little unreacted alcohol and is excellent in hue and odor.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: January 7, 1992
    Assignee: Kao Corporation
    Inventors: Tadaaki Fujita, Kiyoshi Aimono, Kunizo Hashiba, Koichi Ohori
  • Patent number: 4918248
    Abstract: An alcohol is effective produced by catalytically reducing an organic carboxylic acid ester with hydrogen in the presence of a catalyst obtained by reducing a catalyst precursor comprising (A) copper oxide and (B) titanium oxide and/or titanium hydroxide at a weight ratio of (A) to (B) in the range between 15/85 and 65/35. The component (A) may be alternatively a composite metal oxide comprises copper oxide and up to 20 wt. % of zinc oxide.
    Type: Grant
    Filed: May 22, 1989
    Date of Patent: April 17, 1990
    Assignee: Kao Corporation
    Inventors: Yasuyuki Hattori, Noriaki Fukuoka, Shigeru Tamura, Kunizo Hashiba, Kiyoshi Tsukada, Makoto Misono
  • Patent number: 4144198
    Abstract: Copper-iron-aluminum catalysts are prepared by dissolving a cupric salt, a ferrous salt and an aluminum salt in water, adding an alkali to the solution at a temperature higher than 60.degree. C. whereby to form a precipitate, separating the precipitate and water-washing, drying, calcining and pulverizing the separated precipitate.
    Type: Grant
    Filed: December 22, 1977
    Date of Patent: March 13, 1979
    Assignee: Kao Soap Co., Ltd.
    Inventors: Bunji Miya, Yuzi Sawamoto, Kunizo Hashiba, Shizuo Hisamitsu