Abstract: An iridium complex for an organic light-emitting device includes the chemical structural formula shown below, where the ring A is selected from C12-C30 polycyclic groups formed by fusing three or more monocyclic groups with each other, and the precondition is that the ring A at least includes the structure of general formula II: R1-R5 are the same or different, and each independently is H, deuterium, halogen, —CF3, CN, amino, substituted or unsubstituted C1-C10 alkoxyl, or substituted or unsubstituted C1-C30 alkyl, hydrogens on the alkyl chain of the C1-C10 alkoxyl and C1-C30 alkyl may each be independently substituted by deuterium, halogen, —CF3 or CN, where the halogen is selected from fluorine, chlorine, bromine or iodine; Rx and Ry are the same or different, and each independently includes saturated aliphatic ring structure. The iridium complex has excellent red-light saturation, luminous efficiency and thermal stability.