Abstract: A semiconductor device includes a random access memory (RAM) structure and a dielectric layer. The RAM structure is over a substrate and includes a bottom electrode layer, a ferroelectric layer over the bottom electrode layer, and a top electrode layer over the ferroelectric layer. The dielectric layer is over the substrate and laterally surrounds a lower portion of the RAM structure. From a cross-sectional view, the bottom electrode layer of the RAM structure has a lateral portion and a vertical portion, and the vertical portion upwardly extends from the lateral portion to a position higher than a top surface of the dielectric layer.

Abstract: Provided is a hydrophilic phosphorus ligand with the structure of formula 1. X is Y is m is an integer from 1 to 20, A independently is *—O(CH2)n—, n is an integer from 1 to 5, *— is a bond close to triphenylphosphine, and — is a bond away from triphenylphosphine.

Abstract: Provided is a hydrophilic phosphorus ligand with the structure of formula 1. X is Y is m is an integer from 1 to 20, A independently is *—O(CH2)n—, n is an integer from 1 to 5, *- is a bond close to triphenylphosphine, and - is a bond away from triphenylphosphine.

Abstract: A catalyst and a method for synthesizing cyclic carbonate using the catalyst are provided. The catalyst includes a metal complex shown in formula (I): wherein R1, R2, R4, and R5 are independently a C1-C25 alkyl group, a C1-C25 alkoxy group, a C3-C8 cycloalkyl group, a C6-C25 aryl group, a C6-C25 aryloxy group, a C7-C25 aralkyl group, a C7-C25 aralkoxy group, or halogen; R3 is hydrogen, a C1-C25 alkyl group, a C3-C8 cycloalkyl group, a C6-C25 aryl group, a C6-C25 aryloxy group, a C7-C25 aralkyl group, or a C7-C25 aralkoxy group; M is Sn or Ti; X is Cl, Br, I, or OAc; and L represents ether or furan.

Abstract: A catalyst system includes a transition metal salt containing a halo group, an acetate group, or a combination thereof, and an organic phosphine ligand. The molar ratio of the organic phosphine ligand to the transition metal salt is greater than 0 and less than or equal to 50.

Abstract: An olefin-metathesis catalyst is provided. The olefin-metathesis catalyst includes a magnetic carrier, a polymer having formula (I) grafted on the magnetic carrier, and a ruthenium complex loaded on the polymer. A method for preparing low-molecular-weight nitrile butadiene rubber is also provided. In formula (I), one of X, Y and Z is nitrogen atom, the others are carbon atoms, R1 and R2, independently, include hydrogen, ester group, C1-10 alkyl group, C3-8 cycloalkyl group, 4-ring to 8-ring heterocycloalkyl or C6-10 aryl group, R3 includes hydrogen or C1-10 alkyl group, m ranges from 10 to 2,000, and n ranges from 0 to 1,000.

Abstract: A hydrogenation catalyst system is provided. The catalyst system includes a metal complex of Formula (I), an organic lithium compound and an organic compound having a cyclic structure including at least one double bond. In Formula (I), M is transition metals. R1, R2, R3, R4 and R5 are the same or different, including hydrogen, C1-8 alkyl, and C1-8 alkoxy, or two of R1, R2, R3, R4 and R5 are linked together to form a ring. X1, X2 and X3 are a cyclic group, hydrogen, chlorine, bromine, alkyl or alkoxy, wherein when one of X1, X2 and X3 is a cyclic group, and the others are the same or different, including hydrogen, chlorine, bromine, alkyl or alkoxy. The invention also provides a selective hydrogenation process utilizing the catalyst system.

Abstract: A catalyst system includes a transition metal salt containing a halo group, an acetate group, or a combination thereof, and an organic phosphine ligand. The molar ratio of the organic phosphine ligand to the transition metal salt is greater than 0 and less than or equal to 50.

Abstract: A catalyst system and a method for manufacturing cyclic carbonate by the same are provided. The catalyst system includes a transition metal salt containing a halo group, an acetate group, or a combination thereof, and an organic phosphine ligand. The molar ratio of the organic phosphine ligand to the transition metal salt is greater than 0 and less than or equal to 50.

Abstract: Disclosed is a method for treating a surface of a PVC product. A PVC product including PVC and plasticizer is provided. A surface of the PVC product is treated by an aqueous solution of a crosslinking agent and a first phase transfer catalyst to form a first surface treated PVC product. The surface of the first surface treated PVC product is treated by an aqueous solution of an aqueous free radical initiator and a second phase transfer catalyst to form a second surface treated PVC product. As such, the release of the plasticizer from the PVC product to an environment is inhibited.

Abstract: An extended film and a manufacturing method thereof are provided. The extended film includes a poly(lactic acid) and a block copolymer, wherein the block polymer includes a first block, a second block and a third block that connected with each other by chemical bonds. The extended film is formed by steps of mixing poly(lactic acid) and the block copolymer to form a mixture, compressing the mixture to form a board body and extending the board body to form an extended film, thereby forming an extended film having properties of high thermal-resistance and high transparency, the film thus obtained is applicable for packaging use.

Abstract: The present disclosure provides a fire-resistant composite material comprising: at least one inorganic component and at least one nonisocyanate polyurethane having a formula of: wherein R and R? are each independently chosen from hydrocarbylene groups and hydrocarbylene groups having at least one heteroatom chosen from oxygen, nitrogen, and sulfur; and n is an integer chosen from 1 to 30. Also provided are processes for preparing the disclosed fire-resistant composite material.

Abstract: A catalyst system and a method for manufacturing cyclic carbonate by the same are provided. The catalyst system includes a transition metal salt containing a halo group, an acetate group, or a combination thereof, and an organic phosphine ligand. The molar ratio of the organic phosphine ligand to the transition metal salt is greater than 0 and less than or equal to 50.

Abstract: Disclosed is a method for manufacturing a polyester film with low thermal expansion. 95 wt % to 55 wt % of crystalline polyester and 5 wt % to 45 wt % of amorphous polyester are mixed. The blend is then melt extruded to form a sheet. The sheet is then biaxially stretched to obtain a film. The biaxially stretched film is then treated with a heat-setting procedure.

Abstract: Disclosed is a method for treating a surface of a PVC product. A PVC product including PVC and plasticizer is provided. A surface of the PVC product is treated by an aqueous solution of a crosslinking agent and a first phase transfer catalyst to form a first surface treated PVC product. The surface of the first surface treated PVC product is treated by an aqueous solution of an aqueous free radical initiator and a second phase transfer catalyst to form a second surface treated PVC product. As such, the release of the plasticizer from the PVC product to an environment is inhibited.

Abstract: Disclosed is an amorphous copolyester polymerized of a diacid and diols. The diacid is selected from a group consisting of terephthalic acid, 5-tert-butylisophthalic acid, and dimethyl 2,6-naphthalenedicarboxylate. The diols are selected at least two from a group consisting of ethylene glycol, 2,2-dimethyl-1,3-propanediol, and tricyclodecanedimethanol. The molar ratio of the tricyclodecanedimethanol is 30% to 95% of the diols.

Abstract: Disclosed is an amorphous copolyester polymerized of a diacid and diols. The diacid is selected from a group consisting of terephthalic acid, 5-tert-butylisophthalic acid, and dimethyl 2,6-naphthalenedicarboxylate. The diols are selected at least two from a group consisting of ethylene glycol, 2,2-dimethyl-1,3-propanediol, and tricyclodecanedimethanol. The molar ratio of the tricyclodecanedimethanol is 30% to 95% of the diols.

Abstract: Disclosed is a halogen-free retardant acrylic resin, including a copolymer of an acrylate monomer (I) and a phosphorus-containing monomer (II), wherein R1 is H or methyl; R2 is H, alkyl, ester, alkyl ester, aryl, or heteroaryl, and R3 is H or methyl, and X is (CH2)x, x being an integer of 1-11, (CH2CH2O)y, y being an integer of 1-5, or (CH2)zO, z being an integer of 2-10, and n is an integer or a non-integer of 1-2. A molded article of the halogen-free retardant acrylic resin is also provided.

Abstract: An extended film and a manufacturing method thereof are provided. The extended film includes a poly(lactic acid) and a block copolymer, wherein the block polymer includes a first block, a second block and a third block that connected with each other by chemical bonds. The extended film is formed by steps of mixing poly(lactic acid) and the block copolymer to form a mixture, compressing the mixture to form a board body and extending the board body to form an extended film, thereby forming an extended film having properties of high thermal-resistance and high transparency, the film thus obtained is applicable for packaging use.

Abstract: The present disclosure is related to a carbon-nanomaterial-supported catalyst, including: a carbon nanomaterial, and a polymer grafted onto the carbon nanomaterial, wherein the polymer has a repeat unit containing a phosphonium salt and its molecular weight is 1,000-200,000. The disclosure is also related to a method of preparing carbonate, which includes using the carbon nanomaterial-supported catalyst for the cycloaddition reaction of carbon dioxide into the epoxy group.