Abstract: A composite battery set, including a metal-ceramic ruthenium-oxide ultracapacitor and a secondary lithium-ion battery, is provided. The composite battery set is electrically connected to an electrical device, which cuts down the total impedance by the metal-ceramic ruthenium-oxide ultracapacitor to increase the output power and the current. The composite battery set is also able to react a pulse rise time less than 5 ms, to speed up the signal react time of the electronic device. And the composite battery set further includes a protective circuit module (PCM) to protect the secondary lithium-ion battery so as to extend the service life and lifespan.