Abstract: The invention relates to a polymerisable composition comprising (i) 0 to 90% by weight of at least one inorganic filler component, (ii) 5 to 99.98% by weight of at least one urethane (alkyl) acrylate of the idealised formula I, (iii) 0.01 to 25% by weight of at least one di-, tri-, tetra-or multi-functional monomer, not being a urethane (alkyl) acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system as well as optionally of at least one stabiliser and optionally of at least one pigment, the total composition of the composition amounting to 100% by weight, as well as a polymerised composition having improved fracture toughness.

Abstract: An object of the invention is a polymerizable composition comprising. 0.01 to 90 wt.-% of at least one inorganic filler component, 5 to 99.97 wt.-% comprising at least two urethane acrylates, wherein one urethane acrylate corresponding to formula I and the second urethane acrylate having at least one bifunctional thiolurethane group and at least one olefinic group, and mixtures of urethane acrylates comprising these, 0.01 to 25 wt.-% of at least one di-, tri-, tetra- or multi-functional monomer having at least one ether group, thioether group, an at least tri-functional triester and/or a di-functional diester, the diester being selected from tricyclodecanedimethanol dimethacrylate and tricyclodecanedimethanol diacrylate or mixtures of these di-, tri-, tetra- or multi-functional monomers, 0.01 to 10 wt.-% of at least one initiator, an initiator system, and optionally at least one stabilizer and optionally at least one pigment, wherein the total composition of the polymerizable composition is 100 wt.-%.

Abstract: The invention relates to a polymerisable composition comprising (i) 0 to 90% by weight of at least one inorganic filler component, (ii) 5 to 99.98% by weight of at least one urethane (alkyl) acrylate of the idealised formula I, (iii) 0.01 to 25% by weight of at least one di-, tri-, tetra- or multi-functional monomer, not being a urethane (alkyl) acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system as well as optionally of at least one stabiliser and optionally of at least one pigment, the total composition of the composition amounting to 100% by weight, as well as a polymerised composition having improved fracture toughness.

Abstract: The invention relates to a polymerisable composition comprising (i) 0 to 90% by weight of at least one inorganic filler component, (ii) 5 to 99.98% by weight of at least one urethane (alkyl) acrylate of the idealised formula I, (iii) 0.01 to 25% by weight of at least one di-, tri-, tetra- or multi-functional monomer, not being a urethane (alkyl) acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system as well as optionally of at least one stabiliser and optionally of at least one pigment, the total composition of the composition amounting to 100% by weight, as well as a polymerised composition having improved fracture toughness.

Abstract: The invention relates to a polymerisable dental composite material comprising (i) 40 to 90% by weight of an inorganic filler component comprising at least one dental glass, as well as optionally at least one an amorphous metal oxide, (ii) 10 to 60% by weight of at least one urethane (alkyl) acrylate of the idealised formula I, (iii) 0.01 to 15% by weight of at least one di-, tri-, tetra- or multi-functional monomer not being a urethane (alkyl) acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system, as well as optionally of at least one stabiliser, and optionally of at least one pigment, the total composition of the composite material amounting to 100% by weight, as well as to a polymerised composite material for producing direct dental restorations or indirect dental restorations.

Abstract: A polymerisable dental composite material comprising (i) 60 to 85% by weight of an inorganic filler component comprising at least one tectosilicate and optionally at least one dental glass and/or at least one amorphous metal oxide, (ii) 10 to 40% by weight of a mixture of at least two different urethane(meth)acrylates, (iii) 0.01 to 5% by weight of at least one di-, tri-, tetra- or multi-functional monomer not being a urethane(meth)acrylate, (iv) 0.01 to 10% by weight of at least one initiator, an initiator system and optionally at least one stabiliser and optionally at least one pigment, wherein the total composition of the composite material amounts to 100% by weight, and a polymerised composite material having a flexural strength of greater than or equal to 240 MPa and an elastic modulus of 16 to 20 GPa for the production of indirect dentures.

Abstract: A polymerizable dental composite material comprising (i) 70 to 85% by weight of an inorganic filler component comprising at least one dental glass and optionally at least one amorphous metal oxide, (ii) 10 to 30% by weight of a mixture of at least two different urethane (meth)acrylates, (iii) 0.01 to 5% by weight of at least one di-, tri-, tetra- or multi-functional monomer not being a urethane (meth)acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system as well as optionally of at least one stabilizer and optionally of at least one pigment, wherein the total composition of the composite material amounts to 100% by weight, as well as a polymerized composite material having a flexural strength of greater than or equal to 200 MPa and an elastic modulus of 15 to 20 GPa for producing indirect dentures.

Abstract: A polymerisable dental composite material comprising (i) 70 to 85% by weight of an inorganic filler component comprising at least one dental glass and optionally at least one amorphous metal oxide, (ii) 10 to 30% by weight of at least one monomer comprising 1,3-bis(5?-alkyl-3?,8?-dioxo-2?-aza-4?,7?-dioxa-decyl-9?-en)phenyl and/or 1,3-bis(5?,9?-dialkyl-3?,8?-dioxo-2?-aza-4?,7?-dioxa-decyl-9?-en)phenyl, (iii) 0.01 to 5% by weight of at least one di-, tri-, tetra- or multi-functional monomer not being a urethane (meth)acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system and optionally of at least one stabilizer and optionally of at least one pigment, wherein the total composition of the composite material amounts to 100% by weight, and a polymerized composite material having a flexural strength of greater than or equal to 190 MPa and an elastic modulus of 12 to 21 GPa for the production of indirect dentures.

Abstract: A polymerisable dental composite material comprising (i) 70 to 85% by weight of an inorganic filler component comprising at least one dental glass and optionally at least one amorphous metal oxide, (ii) 10 to 30% by weight of a mixture of at least two different urethane(meth)acrylates, (iii) 0.01 to 5% by weight of at least one di-, tri-, tetra- or multi-functional monomer not being a urethane(meth)acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system and optionally of at least one stabilizer and optionally of at least one pigment, wherein the total composition of the composite material amounts to 100% by weight, as well as a polymerized composite material having a flexural strength of greater than or equal to 200 MPa and an elastic modulus of 15 to 20 GPa for the production of indirect dentures.

Abstract: A polymerisable dental composite material comprising (i) 70 to 85% by weight of an inorganic filler component comprising at least one dental glass and optionally at least one amorphous metal oxide, (ii) 10 to 30% by weight of at least one monomer comprising 1,3-bis(5?-alkyl-3?,8?-dioxo-2?-aza-4?,7?-dioxa-decyl-9?-en)phenyl and/or 1,3-bis(5?,9?-dialkyl-3?,8?-dioxo-2?-aza-4?,7?-dioxa-decyl-9?-en)phenyl, (iii) 0.01 to 5% by weight of at least one di-, tri-, tetra- or multi-functional monomer not being a urethane (meth)acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system and optionally of at least one stabilizer and optionally of at least one pigment, wherein the total composition of the composite material amounts to 100% by weight, and a polymerized composite material having a flexural strength of greater than or equal to 190 MPa and an elastic modulus of 12 to 21 GPa for the production of indirect dentures.

Abstract: A polymerisable dental composite material comprising (i) 60 to 85% by weight of an inorganic filler component comprising at least one tectosilicate and optionally at least one dental glass and/or at least one amorphous metal oxide, (ii) 10 to 40% by weight of a mixture of at least two different urethane(meth)acrylates, (iii) 0.01 to 5% by weight of at least one di-, tri-, tetra- or multi-functional monomer not being a urethane(meth)acrylate, (iv) 0.01 to 10% by weight of at least one initiator, an initiator system and optionally at least one stabiliser and optionally at least one pigment, wherein the total composition of the composite material amounts to 100% by weight, and a polymerised composite material having a flexural strength of greater than or equal to 240 MPa and an elastic modulus of 16 to 20 GPa for the production of indirect dentures.

Abstract: A polymerisable dental composite material comprising (i) 70 to 85% by weight of an inorganic filler component comprising at least one dental glass and optionally at least one amorphous metal oxide, (ii) 10 to 30% by weight of a mixture of at least two different urethane (meth)acrylates, (iii) 0.01 to 5% by weight of at least one di-, tri-, tetra- or multi-functional monomer not being a urethane (meth)acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system and optionally of at least one stabilizer and optionally of at least one pigment, wherein the total composition of the composite material amounts to 100% by weight, as well as a polymerized composite material having a flexural strength of greater than or equal to 200 MPa and an elastic modulus of 15 to 20 GPa for the production of indirect dentures.

Abstract: A polymerizable dental composite material comprising (i) 70 to 85% by weight of an inorganic filler component comprising at least one dental glass and optionally at least one amorphous metal oxide, (ii) 10 to 30% by weight of a mixture of at least two different urethane (meth)acrylates, (iii) 0.01 to 5% by weight of at least one di-, tri-, tetra- or multi-functional monomer not being a urethane (meth)acrylate, (iv) 0.01 to 10% by weight of at least one initiator, of an initiator system as well as optionally of at least one stabilizer and optionally of at least one pigment, wherein the total composition of the composite material amounts to 100% by weight, as well as a polymerized composite material having a flexural strength of greater than or equal to 200 MPa and an elastic modulus of 15 to 20 GPa for producing indirect dentures.

Abstract: Method for adjusting or improving or optimizing the usage properties of filler(s)-containing, flowable dental material, which involves relating to at least one measuring value representing the tackiness to at least one measuring value representing the texturing or plasticity or consistency. Flowable, usage-optimized, usually non-polymerized dental composites contain, as fillers, at least one glass filler and at least one filler from the group of chipped polymers or pre-polymer fillers based on ground polymer that is pre-polymerized together with inorganic particles, and, as additive(s), at least one compound represented through formula H—Y—Z (I), where: Y=—O—, —S—, —CO—, —OSi(OR1)2—, —OE Z=H, OH, SH, NH2, COOH, COOR2 E=—CnHmOp- R1=H, C1-C4-Alkyl R2=C1-C15-Alkyl, interrupted by one or more O atoms. C2-C14-Alkyl, n=2 bis 5 m=4 bis 11 p=n.

Abstract: Method for adjusting or improving or optimising the usage properties of filler(s)-containing, flowable dental material, which involves relating to at least one measuring value representing the tackiness to at least one measuring value representing the texturing or plasticity or consistency. Flowable, usage-optimised, usually non-polymerised dental composites contain, as fillers, at least one glass filler and at least one filler from the group of chipped polymers or pre-polymer fillers based on ground polymer that is pre-polymerised together with inorganic particles, and, as additive(s), at least one compound represented through formula H—Y—Z (I), where: Y?—O—, —S—, —CO—, —OSi(OR1)2—, —OE Z?H, OH, SH, NH2, COOH, COOR2 E=—CnHmOp- R1?H, C1-C4-Alkyl R2?C1-C15-Alkyl, interrupted by one or more O atoms.

Abstract: Dental composite materials based on (meth)acrylate, exhibiting a proportion of TCD monomers in the total composition of 1-15% by weight and the quotient of flexural strength/shrinkage tension is at least 35.

Abstract: Dental composites comprising monomers, crosslinking agents, fillers, and initiators, in which the crosslinking agent comprises more than 50% by weight of the acrylate monomer TCD-DI-HEA, and the cyctotoxicity of the cured composite as determined according to the standard requirements of ISO 10993-5 and DIN EN ISO 7405 is assessed into the category “no cytotoxic potential”.

Abstract: For composite materials having a total filler content of 80 to 95% by weight, containing A) 0.5 to 10% by weight of non-agglomerated nanofillers having particle sizes of 1 to 50 nm in the filler component, B) at least 60% by weight of a filler mixture of 50 to 90% coarse-particle and 10 to 50% fine-particle dental glass in the filler component, having a size ratio, relative to the average particle size (d50 value), of coarse to fine particles of >1:4 to 1:30, C) as monomer component, a monomer mixture of i. 60 to 80% bis-GMA or TCD-di-HEMA or TCD-di-HEA, ii. 10 to 18% UDMA, iii. Residual TEDMA and/or multifunctional crosslinkers, D) up to 1% photoinitiator(s); and E) optionally, at least one additional dental glass in the filler component having a different particle size than the coarse- and fine-particle dental glass, the polymerization shrinkage may be reduced to <1.

Abstract: Dental composite materials based on (meth)acrylate, exhibiting a proportion of TCD monomers in the total composition of 1-15% by weight and the quotient of flexural strength/shrinkage tension is at least 35.

Abstract: Compositions for dental composites comprising monomers, crosslinking agents, fillers, initiators, A the proportion of crosslinking agent being formed in an amount of more than 50% by acrylate monomers with a TCD urethane structure having the general formula in which A, X, Z, R1 R2 R3 and r have the meaning indicated in claim 1, provide polymerized composite materials with a particularly low cytotoxicity according to the standard requirements according to ISO 10993-5 and DIN EN ISO 7405.