Abstract: An organic composite comprising an electroactive material and an organic phosphorescent dye. The electroactive material and organic phosphorescent dye have been functionalized in order that when they are mixed together and a curing amount of radiation or heat is applied, the phosphorescent dye is covalently bonded to the crosslinked electroactive material. The method to prepare the organic composite is given. The invention is suitable for the mass production of any light management system. In one embodiment light emitting diodes are described.

Abstract: The invention includes embodiments that relate to a method of making an organic light-emitting device comprising at least one bilayer structure. The method comprises providing at least one first layer comprising at least one cross-linkable organic material and at least one photo acid generator; exposing the first layer to a radiation source to afford a cross-linked first layer; and disposing at least one second layer on the cross-linked first layer. The method affords a bilayer structure having an enhanced structural integrity relative to the corresponding bilayer structure in which the first layer is not cross-linked. The invention also includes embodiments that relate to an organic light emitting device.

Abstract: An optical article for being transformed from a pre-activated state of functionality to an activated state of functionality is provided. The optical article includes an electro-chromic structure having layers of an electro-chromic material being responsive to an electrical stimulus, and an electrolyte layer interposed between the layers of the electro-chromic material. The electro-chromic structure may alter the optical article from a pre-activated state of functionality to an activated state of functionality upon interaction with the electrical stimulus.

Abstract: A wirelessly powered flexible tag configured to be in contact with a substrate is provided. The tag includes a coupling layer configured to couple the tag to the substrate. An electrical circuit disposed on the coupling layer and configured to interact wirelessly with an external stimulus. The tag further includes at least one electrode or at least one heating element in operative association with the electrical circuit, and configured to generate electrical energy or thermal energy, respectively. Upon wireless interaction with the external stimulus the tag is configured to induce an electrical response, a thermal response, or a combination of both in the substrate.

Abstract: An optical article that can transform from a pre-activated state of functionality to an activated state of functionality is provided. The optical article includes a radio frequency circuitry coupled to the optical article for interacting with a signal, wherein said signal comprises a thermal signal, an electrical signal, or both, and a convertible material in operative association with the radio frequency circuitry for altering the functionality of the optical article from the pre-activated state to the activated state upon interaction with the thermal energy.

Abstract: Novel metal porphyrin compositions useful as organic phosphors are provided. The novel compositions are prepared from commercially available porphyrin-containing starting materials. In one instance a novel palladium-containing porphyrin composition having a number average molecular weight of greater than 12,000 grams per mole was prepared from 5,10,15,20-tetrakis(3?,5?-di(hydroxy)phenyl)-21H-23H-porphyrin by reaction first with palladium(II) acetylacetonate, followed by reaction with 2-bromo-2-methylpropionyl bromide, and subsequent group transfer reaction of the alpha-bromo ester groups with 9,9-dioctyl-2-vinylfluorene in the presence of CuBr as a radical initiator. The product polymer exhibited a number average molecular weight of 12,884 grams per mole, a weight average molecular weight of 14,338 grams per mole, and a robust red phosphorescent emission.

Abstract: An electrooptic device and a surface modified electrode comprising a reduced organic material are provided. The reduced organic materials lower the work function of an electrode surface; they are also electro-active. These capabilities facilitate their use in production of more efficient electrooptic devices. The electrooptic device has at least a first conductive layer, a second conductive layer, and an electro-active layer comprising the reduced organic material disposed between the first and second conductive layers. The surface modified electrode comprises at least one conductive layer and at least one reduced organic material disposed upon a surface of said conductive layer. Methods for using the organic electro-active material for producing electrooptic devices, and operating the electrooptic devices are also disclosed. Coating compositions and coated articles comprising the reduced organic materials are also provided.

Abstract: A surface modified electrode comprising at least one conductive layer, and at least one reduced polymeric material, wherein the reduced polymeric material comprises at least one additional electron relative to a corresponding neutral polymeric precursor; and at least one cationic species is provided. Coating compositions and coated articles comprising the reduced polymeric materials are also provided. The coating compositions lower the work function of the electrode surface, thereby facilitating the production of more efficient electrooptic devices.

Abstract: Disclosed is a polymer composition derived from a bis-phenol comprising a conjugated aromatic radical, optionally comprising nitrogen. Suitable bis-phenols as well as methods for making said polymer are also disclosed. Also disclosed are electroactive layers comprising said polymer and electroactive devices comprising said layer.

Abstract: Disclosed are polymers comprising 2-(7-benzothiazolyl-9,9-disubstituted fluorene) structural units of the formula wherein R1 and R2 are each independently an alkyl group, an aralkyl group, an aryl group, or an —Si(R)3 group wherein R is an alkyl group; R3 is selected from the group consisting of an electron-donating substituent and an electron-withdrawing substituent; x has the value of from zero up to the number of hydrogens available for substitution on the aromatic ring; Z and Q are each independently a group which is in conjugation with both the fluorene group and the benzothiazole group; and the parameters j and k each independently have the value of 0-2. Electroactive devices comprising said polymers, methods for preparing said polymers, and monomers for preparing said polymers are also disclosed.

Abstract: The invention relates to a multi-layered device and a method for making a multi-layered device. The method comprises the steps of determining a desired sequence of two or more polymers in a multi-layered device; for each of the two or more polymers in the desired sequence, identifying a solubility window in a solubility graph, and selecting a solvent based on the solubility window such that the solvent does not dissolve a preceding polymer in the desired sequence; depositing each of the two or more polymers from its selected solvent; and forming a multi-layered device having the two or more polymers in the desired sequence.