Abstract: The present invention includes metal materials 42a and 52a made of thermally expandable members that thermally expand, and insulating metal oxide layers 42b and 52b. The metal materials 42a and 52a and the metal oxide layers 42b and 52b formed in an annular shape have through holes 42c and 52c thereinside.

Abstract: Provided is a film forming apparatus capable of stably supplying a large amount of ceramic raw material powder for a long time and forming a homogeneous and dense film. A film forming apparatus 1 for forming a film on a base material K includes an aerosol transport path 10 for ejecting an aerosol obtained by dispersing a ceramic raw material powder in a gas, from an ejection end 10a toward the base material K, in which a flow path cross-section at an ejection end 10a of the aerosol transport path 10 has a substantially circular shape with an area of 10 mm2 or more.

Abstract: Provided is a low-cost electrochemical element that includes a high-performance electrode layer. The electrochemical element includes an electrode layer, and the electrode layer contains small particles and large particles. The small particles have a particle diameter of 200 nm or less in the electrode layer, and the large particles have a particle diameter of 500 nm or more in the electrode layer.

Abstract: A metal support for an electrochemical element has a plate shape as a whole, and is provided with a plurality of penetration spaces that pass through the metal support from a front face to a back face. The front face is a face to be provided with an electrode layer. Each of front-side openings that are openings of the penetration spaces formed in the front face has an area of 3.0×10?4 mm2 or more and 3.0×10?3 mm2 or less.

Abstract: Provided is a low-cost electrochemical element that has excellent performance, reliability, and durability. Also, provided is a manufacturing method for an electrochemical element including a metal substrate (metal support) and an electrode layer formed on/over the metal substrate. The method includes an electrode layer forming step of forming an electrode layer having a region with a surface roughness of 1.0 ?m or less on/over the metal substrate, and an electrolyte layer forming step of forming an electrolyte layer by spraying aerosolized metal oxide powder onto the electrode layer.

Abstract: Realized is an element having an electrolyte layer that is dense and has high gas barrier characteristics. A metal-supported electrochemical element includes at least a metal substrate as a support, an electrode layer formed on/over the metal substrate, a buffer layer formed on the electrode layer, and an electrolyte layer formed on the buffer layer. The electrode layer is porous and the electrolyte layer is dense. The buffer layer has density higher than density of the electrode layer and lower than density of the electrolyte layer.

Abstract: Realized is an element having an electrolyte layer that is dense and has high gas barrier characteristics. A metal-supported electrochemical element includes at least a metal substrate as a support, an electrode layer formed on/over the metal substrate, a buffer layer formed on the electrode layer, and an electrolyte layer formed on the buffer layer. The electrode layer is porous and the electrolyte layer is dense. The buffer layer has density higher than density of the electrode layer and lower than density of the electrolyte layer.

Abstract: Provided is a low-cost electrochemical element that has excellent reliability and durability. A substrate with an electrode layer for a metal-supported electrochemical element includes a metal support and an electrode layer formed on/over the metal support, and the electrode layer has a region with a surface roughness of 1.0 ?m or less.

Abstract: A metal support for an electrochemical element has a plate shape as a whole, and is provided with a plurality of penetration spaces 1c that pass through the metal support from a front face 1a to a back face. The front face 1a is a face to be provided with an electrode layer. A region of the front face 1a provided with the penetration spaces is a hole region, and openings of the penetration spaces formed in the front face are front-side openings. An aperture ratio that is a ratio of the front-side openings to the hole region is 0.1% or more and 7.0% or less.

Abstract: A metal support for an electrochemical element has a plate shape as a whole, and is provided with a plurality of penetration spaces that pass through the metal support from a front face to a back face. The front face is a face to be provided with an electrode layer. Each of front-side openings that are openings of the penetration spaces formed in the front face has an area of 3.0×10?4 mm2 or more and 3.0×10?3 mm2 or less.

Abstract: Provided is a low-cost electrochemical element that includes a high-performance electrode layer. The electrochemical element includes an electrode layer, and the electrode layer contains small particles and large particles. The small particles have a particle diameter of 200 nm or less in the electrode layer, and the large particles have a particle diameter of 500 nm or more in the electrode layer.

Abstract: Realized is an element having an electrolyte layer that is dense and has high gas barrier characteristics. A metal-supported electrochemical element includes at least a metal substrate as a support, an electrode layer formed on/over the metal substrate, a buffer layer formed on the electrode layer, and an electrolyte layer formed on the buffer layer. The electrode layer is porous and the electrolyte layer is dense. The buffer layer has density higher than density of the electrode layer and lower than density of the electrolyte layer.

Abstract: Realized is an element having an electrolyte layer that is dense and has high gas barrier characteristics. A metal-supported electrochemical element includes at least a metal substrate as a support, an electrode layer formed on/over the metal substrate, a buffer layer formed on the electrode layer, and an electrolyte layer formed on the buffer layer. The electrode layer is porous and the electrolyte layer is dense. The buffer layer has density higher than density of the electrode layer and lower than density of the electrolyte layer.

Abstract: Realized is an element having an electrolyte layer that is dense and has high gas barrier characteristics. A metal-supported electrochemical element includes at least a metal substrate as a support, an electrode layer formed on/over the metal substrate, a buffer layer formed on the electrode layer, and an electrolyte layer formed on the buffer layer. The electrode layer is porous and the electrolyte layer is dense. The buffer layer has density higher than density of the electrode layer and lower than density of the electrolyte layer.

Abstract: Provided is a low-cost electrochemical element that has excellent performance, reliability, and durability. Also, provided is a manufacturing method for an electrochemical element including a metal substrate (metal support) and an electrode layer formed on/over the metal substrate. The method includes an electrode layer forming step of forming an electrode layer having a region with a surface roughness of 1.0 ?m or less on/over the metal substrate, and an electrolyte layer forming step of forming an electrolyte layer by spraying aerosolized metal oxide powder onto the electrode layer.

Abstract: Realized are a high-performance electrochemical element and solid oxide fuel cell in which the contact properties between a dense and highly-gastight electrolyte layer and an electrode layer are improved while the treatment temperature during formation of the electrolyte layer is suppressed to a low temperature, and methods for producing the same. An electrochemical element includes an electrode layer 3, and an electrolyte layer 4 arranged on the electrode layer 3, wherein the electrode layer 3 has a plurality of pores that are open on a face thereof in contact with the electrolyte layer 4, and the pores are filled with fine particles made of the same components as the electrolyte layer 4.

Abstract: Realized is an element having an electrolyte layer that is dense and has high gas barrier characteristics. A metal-supported electrochemical element includes at least a metal substrate as a support, an electrode layer formed on/over the metal substrate, a buffer layer formed on the electrode layer, and an electrolyte layer formed on the buffer layer. The electrode layer is porous and the electrolyte layer is dense. The buffer layer has density higher than density of the electrode layer and lower than density of the electrolyte layer.

Abstract: Realized are an electrochemical element and a solid oxide fuel cell that have a dense electrolyte layer and that have excellent durability and robustness, and methods for producing the same. An electrochemical element includes: a metal substrate 2 having a plurality of through holes 21; an electrode layer 3 provided over a front face of the metal substrate 2; and an electrolyte layer 4 provided over the electrode layer 3, wherein the through holes 21 are provided passing through the front face and a back face of the metal substrate 2, the electrode layer 3 is provided in a region larger than a region, of the metal substrate 2, in which the through holes 21 are provided, and the electrolyte layer 4 has a first portion 41 coating the electrode layer 3, and a second portion 42 that is in contact with the front face of the metal substrate 2.

Abstract: Realized are an electrochemical element and a solid oxide fuel cell that have a dense electrolyte layer and that have excellent durability and robustness, and methods for producing the same. An electrochemical element includes: a metal substrate 2 having a plurality of through holes 21; an electrode layer 3 provided over a front face of the metal substrate 2; and an electrolyte layer 4 provided over the electrode layer 3, wherein the through holes 21 are provided passing through the front face and a back face of the metal substrate 2, the electrode layer 3 is provided in a region larger than a region, of the metal substrate 2, in which the through holes 21 are provided, and the electrolyte layer 4 has a first portion 41 coating the electrode layer 3, and a second portion 42 that is in contact with the front face of the metal substrate 2.

Abstract: Realized are a high-performance electrochemical element and solid oxide fuel cell in which the contact properties between a dense and highly-gastight electrolyte layer and an electrode layer are improved while the treatment temperature during formation of the electrolyte layer is suppressed to a low temperature, and methods for producing the same. An electrochemical element includes an electrode layer 3, and an electrolyte layer 4 arranged on the electrode layer 3, wherein the electrode layer 3 has a plurality of pores that are open on a face thereof in contact with the electrolyte layer 4, and the pores are filled with fine particles made of the same components as the electrolyte layer 4.