Abstract: Disclosed are a lithium-air battery including a redox mediator in an electrolyte and having a protective layer on an anode, and a method of manufacturing the same. The lithium-air battery includes an anode including a lithium metal, a protective layer positioned on the anode and including lithium fluoride (LiF), a cathode, and an electrolyte positioned between the protective layer and the cathode. Particularly, the electrolyte includes a halogen ion (X?) which is a redox mediator.

Abstract: Disclosed are a method of manufacturing a composite anode for a lithium ion battery and a composite anode for a lithium ion battery manufactured thereby. According to the method provide herein, since a metal catalyst precursor is reduced using Joule heating to obtain a carbon-metal catalyst composite layer, composite anode for a lithium ion battery having a large area in a short period of time can be provided, which is excellent in terms of economic feasibility. Further, since it is possible to manufacture a composite anode for a lithium ion battery with the improved lithium electrodeposition density and reversibility of lithium ions, a composite anode for a lithium ion battery having high capacity and improved life stability can be obtained.

Abstract: Disclosed herein are a lithium air battery having a multi-layered electrolyte membrane and a method of manufacturing the same. The lithium air battery includes a first electrolyte membrane capable of obtaining high ionic conductivity on a lithium negative electrode surface while minimizing the content of polymer and positioning a second electrolyte membrane with high resistance to oxygen radicals on the air electrode. Accordingly, the multi-layered electrolyte membrane can improve an electrolyte filling characteristic and a conductive characteristic of lithium ions, suppress oxygen radicals from being carried from an air electrode, and suppress a growth of lithium dendrite to largely improve a battery lifespan.

Abstract: A lithium air battery may include an electrolyte with a donor number of 10 to 40; and a quinone-based liquid catalyst which added to the electrolyte to induce a discharge in the solution.

Abstract: Disclosed herein is a sodium-air battery comprising a high-concentration electrolyte which can increase the chemical stability of the battery material and the discharge product in the sodium-air battery. The use of a liquid electrolyte comprising an ether-based solvent and a sodium salt at a concentration of 4 M or less but exceeding 0.5 M can significantly increase the chemical stability of the sodium-air battery and can suppress the formation of dendrites on the anode.

Abstract: A soluble catalyst for a lithium-air battery is provided. The soluble catalyst including a redox mediator (RM) has an ionization energy of about 5.5 to 7.5 eV under vacuum or an oxidation potential of 3.0 to 4.0 V and is well dissolved in an electrolyte without reacting with the electrolyte. In addition, the soluble catalyst has a HOMO level in an original state (RM), which is less than a formation energy of lithium peroxide (Li2O2) but maximally close to the formation energy, and has a HOMO level in an oxidized state (RM+), which is greater than a HOMO level of the electrolyte.

Abstract: Disclosed is a nanotubular intermetallic compound catalyst for a positive electrode of a lithium air battery and a method of preparing the same. In particular, a porous nanotubular intermetallic compound is simply prepared using electrospinning in which a dual nozzle is used, and, by using the same as a catalyst, a lithium air battery having enhanced discharge capacity, charge/discharge efficiency and lifespan is provided.

Abstract: A lithium air battery may include an electrolyte with a donor number of 10 to 40; and a quinone-based liquid catalyst which added to the electrolyte to induce a discharge in the solution.

Abstract: Disclosed herein are a lithium air battery having a multi-layered electrolyte membrane and a method of manufacturing the same. The lithium air battery includes a first electrolyte membrane capable of obtaining high ionic conductivity on a lithium negative electrode surface while minimizing the content of polymer and positioning a second electrolyte membrane with high resistance to oxygen radicals on the air electrode. Accordingly, the multi-layered electrolyte membrane can improve an electrolyte filling characteristic and a conductive characteristic of lithium ions, suppress oxygen radicals from being carried from an air electrode, and suppress a growth of lithium dendrite to largely improve a battery lifespan.

Abstract: An all solid electrode structure having a solid electrolyte concentration gradient is provided and a method of improving an output performance is provided with improved ion diffusion and obtaining a high capacity battery, by disposing an anode or cathode electrode having a substantially continuous concentration gradient to have a greater solid electrolyte ratio as being closer to a solid electrolyte interface and have a greater active material ratio as being close to a current collector interface. The active material/solid electrolyte ratio of anode and cathode active material layers has a concentration gradient by a single process using an aerosol deposition method.

Abstract: A soluble catalyst for a lithium-air battery is provided. The soluble catalyst including a redox mediator (RM) has an ionization energy of about 5.5 to 7.5 eV under vacuum or an oxidation potential of 3.0 to 4.0 V and is well dissolved in an electrolyte without reacting with the electrolyte. In addition, the soluble catalyst has a HOMO level in an original state (RM), which is less than a formation energy of lithium peroxide (Li2O2) but maximally close to the formation energy, and has a HOMO level in an oxidized state (RM+), which is greater than a HOMO level of the electrolyte.

Abstract: Disclosed is a nanotubular intermetallic compound catalyst for a positive electrode of a lithium air battery and a method of preparing the same. In particular, a porous nanotubular intermetallic compound is simply prepared using electrospinning in which a dual nozzle is used, and, by using the same as a catalyst, a lithium air battery having enhanced discharge capacity, charge/discharge efficiency and lifespan is provided.

Abstract: The present invention provides a lithium-air hybrid battery and a method for manufacturing the same, which has a structure in which a liquid electrolyte electrode and a solid electrolyte electrode are stacked on both sides of an ion conductive glass ceramic. That is, disclosed is a lithium-air hybrid battery and a method for manufacturing the same, which has a structure in which a lithium metal negative electrode includes a liquid electrolyte and a porous air positive electrode comprising a carbon, a catalyst, a binder and a solid electrolyte are separately stacked on both sides of an impermeable ion conductive glass ceramic, and the liquid electrolyte is present only in the lithium metal negative electrode.

Abstract: A bipolar current collector for a lithium-air battery includes a substrate having a plate shape. A plurality of nanowires are anodized on the substrate and have a pillar shape with a predetermined height. An air path is formed between the plurality of nanowires and through which outside air flowing into a battery moves. The plurality of nanowires include titanium dioxide (TiO2).

Abstract: The present invention relates to an cathode for a lithium-air battery. More particularly, it relates to an cathode for a lithium-air battery having improved life characteristic because it can suppress volatilization of an electrolyte impregnated in the cathode, and can prevent influx of moisture from outside by forming a bipolar material layer wherein a bipolar material consisting of a hydrophilic ion and a hydrophobic ion is coated on the surface of the cathode.

Abstract: A lithium-air battery system having a hermetic structure is provided and eliminates the need to be charged with additional oxygen gas. The system includes a lithium-air battery and an oxygen bombe that stores oxygen gas participating in a lithium-oxygen reaction. A first MFC adjusts a flow rate of oxygen gas supplied from the oxygen bombe to lithium-air battery cells. A blower repeatedly supplies oxygen gas flowing from the first MFC into the lithium-air battery cells. A compressor compresses oxygen generated from the lithium-air battery cells and passes through a second MFC, to a high pressure state to charge the oxygen bombe with the compressed oxygen during a charge operation. The second MFC adjusts a flow rate when oxygen gas generated from the lithium-air battery cells is supplied to the compressor during the charge operation. Additionally, an external power source supplies electric power to the compressor to charge the oxygen bombe.

Abstract: The present invention provides a lithium-air hybrid battery and a method for manufacturing the same, which has a structure in which a liquid electrolyte electrode and a solid electrolyte electrode are stacked on both sides of an ion conductive glass ceramic. That is, disclosed is a lithium-air hybrid battery and a method for manufacturing the same, which has a structure in which a lithium metal negative electrode includes a liquid electrolyte and a porous air positive electrode comprising a carbon, a catalyst, a binder and a solid electrolyte are separately stacked on both sides of an impermeable ion conductive glass ceramic, and the liquid electrolyte is present only in the lithium metal negative electrode.

Abstract: Disclosed is a lithium-air battery or particularly, a high voltage lithium-air battery of a laminated type with a high density. The lithium-air battery may be constructed by laminating a plurality of cells, each of which may comprises a cathode that uses oxygen in air as an active material, a lithium metal anode, a separation film interposed between the cathode and the anode and an electrolyte for ion transmission. In particular, an electrically conductive bipolar plate having a flow path for supplying air to the cathode is interposed between a cathode and an anode of adjacent cell when the cells are laminated and an air inlet manifold for distributing air to the air flow path of the respective bipolar plate and an air outlet manifold for allowing the air passing through the air flow path of the respective bipolar plate to be discharged are provided in the lithium-air battery.

Abstract: An all solid electrode structure having a solid electrolyte concentration gradient is provided and a method of improving an output performance is provided with improved ion diffusion and obtaining a high capacity battery, by disposing an anode or cathode electrode having a substantially continuous concentration gradient to have a greater solid electrolyte ratio as being closer to a solid electrolyte interface and have a greater active material ratio as being close to a current collector interface. The active material/solid electrolyte ratio of anode and cathode active material layers has a concentration gradient by a single process using an aerosol deposition method.

Abstract: An electrode of an all-solid-state battery has an ionic conductive coating active material and an electronically conductive coating active material. Based on a thickness of the electrode, 50% of the electrode near a current collector is VB>VA and remaining portions close to a solid electrolyte are VA>VB, where VA is a volume of the ionic conductive coating active material, and VB is a volume of the electronically conductive coating active material.