Patents by Inventor Lajos Avar
Lajos Avar has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4876299Abstract: A compound of formula I ##STR1## in which R, R.sub.1, R.sub.10 and R.sub.11 are organic radicals. These compounds are suitable as U.V. absorbers.Type: GrantFiled: April 1, 1987Date of Patent: October 24, 1989Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4859725Abstract: A compound of formula I ##STR1## in which R to R.sub.5 are organic radicals, for use as a light stabilizer in polymeric systems.Type: GrantFiled: August 23, 1988Date of Patent: August 22, 1989Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4780492Abstract: A liquid concentrate comprising an oxamide and a 2,2,6,6-tetraalkylpiperidine compound dissolved in an organic solvent is useful for the UV-stabilization of hardenable liquid finishes, particularly automotive finishes.Type: GrantFiled: December 22, 1986Date of Patent: October 25, 1988Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4774332Abstract: A compopund containing one or more units of formula I ##STR1## in which R.sub.1 is --CH.sub.2 C.sub.1-4 alkyl or --CH.sub.3 or both groups R.sub.1 form --(CH.sub.2).sub.5 --;R.sub.2 is --CH.sub.2 C.sub.1-4 alkyl or --CH.sub.3 or both groups R.sub.2 form --(CH.sub.2).sub.5 --;R.sub.3 is furylmethyl, unsubstituted C.sub.1-18 alkyl; C.sub.1-4 alkyl monosubstituted by phenyl, the phenyl group of which is unsubstituted or substituted by 1 to 3 groups selected from --OH and C.sub.1-8 alkyl; C.sub.2-8 alkyl monosubstituted by C.sub.1-4 alkoxy; phenyl, unsubstituted or substituted by 1 to 3 groups selected from C.sub.1-8 alkyl and --OH; or cyclohexy, unsubstituted or monosubstituted by C.sub.1-8 alkyl or --OH.These compounds are useful as light stabilizers for polymeric material.Type: GrantFiled: July 11, 1986Date of Patent: September 27, 1988Assignee: Sandoz, Ltd.Inventor: Lajos Avar
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Patent number: 4730017Abstract: A compound useful as a light-stabilizer for polymeric material of formula I ##STR1## in which R is hydrogen, oxygen, C.sub.1-8 alkyl or --CO--R.sub.5, where R.sub.5 is --C(R.sub.10).dbd.CH.sub.2, C.sub.1-6 alkyl, phenyl, --CO--O--C.sub.1-4 alkyl or --NR.sub.7 R.sub.8 and where R.sub.7 is hydrogen, C.sub.1-12 alkyl, C.sub.5-6 -cycloalkyl, phenyl, phenylC.sub.1-4 alkyl or C.sub.1-12 alkylphenyl and R.sub.8 is C.sub.1-12 alkyl or hydrogen;each R.sub.1, independently, is --CH.sub.3 or --CH.sub.2 (C.sub.1-4 alkyl) or both groups R.sub.1 form a group --(CH.sub.2).sub.5 --;each R.sub.2, independently, is --CH.sub.3 or --CH.sub.2 (C.sub.1-4 alkyl) or both groups R.sub.2 form a group --(CH.sub.2).sub.5);R.sub.10 is hydrogen or C.sub.1-4 alkyl; andR.sub.4 is an amide- or ester-forming group.Type: GrantFiled: September 12, 1986Date of Patent: March 8, 1988Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4716187Abstract: both R.sub.1 's and CH.sub.3 or together form --CH.sub.2).sub.5 ;both R.sub.2 's are CH.sub.3 or together form --CH.sub.2).sub.5 ;R.sub.3 has a significance of R, independently of R, except for oxygen;X is --O--, --NH-- or ##STR2## m is an integer from 1 to 4 inclusive; R.sub.4 is a saturated or unsaturated aliphatic group unsubstituted or substituted by one or two groups selected from --OH and C.sub.1-4 alkoxy and which can be interrupted by an oxygen or sulphur atom; or an aromatic group unsubstituted or substituted by one or two groups selected from --OH, C.sub.1-4 alkyl and C.sub.1-4 alkoxy are useful as U.V. light stabilizers in polymeric organic compounds.Type: GrantFiled: March 15, 1985Date of Patent: December 29, 1987Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4695600Abstract: These compounds are useful as light stabilizers in polymeric systems. ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are organic radicals.Type: GrantFiled: June 17, 1986Date of Patent: September 22, 1987Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4661595Abstract: A method for preparing a compound of formula I ##STR1## in which X is O or S;both groups R together with the two carbon atoms to which they are attached form a fused aromatic group;R.sub.1 is an organic radical; andn is 0, 1, 2 or 3comprising reacting a compound of formula II ##STR2## where R, R.sub.1 and n are defined above and where each R.sub.3, independently, is C.sub.1-12 alkoxy or one R.sub.3 is C.sub.1-12 alkoxy and the other R.sub.3 is halogen,with elemental sulphur in an alkaline medium, a metal sulphide or a metal hydrosulphide.Compounds of formula I and formula II are useful as photoinitiators.Type: GrantFiled: July 10, 1985Date of Patent: April 28, 1987Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4485034Abstract: Oxalanilides of formula I ##STR1## in which R is C.sub.6-22 alkyl or C.sub.6-22 alkoxyR.sub.1 and R.sub.2 are independently, hydrogen, C.sub.1-8 alkyl, C.sub.1-12 alkoxy, C.sub.1-12 alkylthio, phenoxy or phenylthio; provided that R.sub.1 and R.sub.2 may not both be selected from alkylthio, phenoxy and phenylthio;and R.sub.3 is hydrogen or C.sub.1-8 alkylcertain of which are novel, are useful as UV-stabilizers in organic polymers and organic polymer-containing coatings, particularly automotive finishes. The compounds have low volatility and excellent solubility in organic solvents such as are used in liquid finishes.Type: GrantFiled: September 6, 1983Date of Patent: November 27, 1984Assignee: Sandoz Ltd.Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
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Patent number: 4415687Abstract: 1,3-dihydroxy-4,6-bis-4'-(2',2',6',6',-tetramethylpiperidyl) benzene, its 1'-alkyl or 1'-(substituted alkyl) derivatives and monomeric or polymeric products derived from these compounds by substitution of 1- and 3-hydroxy groups and/or by the linking of hydroxy groups on adjacent units through a bridging groups, are useful as light and heat stabilizers for polymeric organic materials.Corresponding bis(3',4'-dehydro) unsaturated compounds are useful as intermediates.Type: GrantFiled: July 2, 1982Date of Patent: November 15, 1983Assignee: Sandoz Ltd.Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
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Patent number: 4412024Abstract: Oxalanilides of formula I ##STR1## in which R is C.sub.6-22 alkyl or C.sub.6-22 alkoxyR.sub.1 and R.sub.2 are independently, hydrogen, C.sub.1-8 alkyl, C.sub.1-12 alkoxy, C.sub.1-12 alkylthio, phenoxy or phenylthio; provided that R.sub.1 and R.sub.2 may not both be selected from alkylthio, phenoxy and phenylthio;andR.sub.3 is hydrogen or C.sub.1-8 alkylcertain of which are novel, are useful as UV-stabilizers in organic polymers and organic polymer-containing coatings, particularly automotive finishes. The compounds have low volatility and excellent solubility in organic solvents such as are used in liquid finishes.Type: GrantFiled: September 14, 1981Date of Patent: October 25, 1983Assignee: Sandoz Ltd.Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
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Patent number: 4324628Abstract: The present invention relates to a photopolymerization process comprising irradiating a photopolymerizable material with U.V. light of wave length 250 to 400 nm in the presence of a photosensitizing amount of a photoinitiator of formula I, ##STR1## in which R is hydrogen or halogenR.sub.1 is alkyl, cycloalkyl, benzyl, optionally substituted phenyl or (a) ##STR2## either R.sub.2 is optionally substituted alkyl, benzyl, C.sub.6 H.sub.5 --CH.dbd.CH--, 2-thienyl, 2-furyl, 2-(3-chloro)benzothienyl or optionally substituted phenyl, andR.sub.3 is hydrogen or R.sub.2 and R.sub.3 form a radical of formula (b) ##STR3## in which X is a direct bond, --O--, --S--, --CH.sub.2 --, ##STR4## and R.sub.4 and R' have one of the significances of R.sub.2 and R, respectively,with the proviso that when R.sub.1 is (a) R.sub.3 is hydrogen and R.sub.2 and R.sub.4 are free from halogen atoms.Type: GrantFiled: December 3, 1980Date of Patent: April 13, 1982Assignee: Sandoz Ltd.Inventors: Lajos Avar, Hans-Werner Finck, Evelyne Kalt
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Patent number: 4165267Abstract: The present invention concerns novel photopolymerizable formulations which comprise a photopolymerizable system in association with a photosensitizing amount of the compound of formula ##STR1## WHEREIN R is an unsubstituted or substituted binuclear aromatic group, e.g. phenoxy phenyl,M is 0, 1 or 2 andHal is halogen.Type: GrantFiled: March 6, 1973Date of Patent: August 21, 1979Assignee: Sandoz Ltd.Inventors: Lajos Avar, Kurt Hofer
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Patent number: 4146540Abstract: The present invention concerns certain novel compounds falling under the general formula: ##STR1## WHEREIN R.sub.1, R.sub.2 and R.sub.3 are substituents, e.g. alkyl and Me is hydrogen or a metal cation.The compounds are useful stabilizers of organic material against the degradative effect of heat, oxidation and U.V. light.Type: GrantFiled: October 21, 1977Date of Patent: March 27, 1979Assignee: Sandoz Ltd.Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
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Patent number: 4102857Abstract: New ultraviolet light-absorbing compounds of the formula ##STR1## IN WHICH R.sub.1 is a substituent, e.g. alkyl,R.sub.2 is a substituent, e.g. alkyl,R.sub.3 is hydrogen or a substituent, e.g. alkyl,N is 1, 2 or 3, andR is an n-valent, optionally substituted benzene radical, or a 1- or 2-valent naphthalene or heterocyclic radical, which are producible by known processes. Such compounds are useful as stabilizers of organic materials, particularly plastics materials, against the degrading action of ultraviolet light and can be either applied as a coating on the organic material, or incorporated therein.Such compounds are useful as stabilizers of organic materials, particularly plastics materials, against the degrading action of ultraviolet light and can be either applied as a coating on the organic material, or incorporated therein.Type: GrantFiled: August 20, 1976Date of Patent: July 25, 1978Assignee: Sandoz Ltd.Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
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Patent number: 4036812Abstract: The present invention concerns novel nickel complexes (I) possessing U.V. stabilizing properties characterized by bearing per molecule 2 monodentate nickel coordinated 1,3-hydrocarbyl-4-(greater than C.sub.1)-acyl-pyrazole-5-oxy ligands and one bidentate or two monodentate nickel coordinated primary or secondary amine ligands, and their use as U.V. stabilizers for e.g. plastics materials.Type: GrantFiled: December 17, 1975Date of Patent: July 19, 1977Assignee: Sandoz Ltd.Inventors: Lajos Avar, Kurt Hofer
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Patent number: 4029684Abstract: The present invention concerns novel 2-hydroxybenzophenone derivatives and metal complexes thereof of the formula: ##STR1## wherein Z.sub.1, Z.sub.2, Y.sub.1 and Y.sub.2 are each, independently, hydrogen or a substituent, at least one of Y.sub.1 and Y.sub.2 being a group ##STR2## wherein, R.sub.1 is alkyl R.sub.2 is hydrogen or a substituent andA is oxygen, sulphur or ##STR3## The compounds are useful for stabilizing organic material, e.g. plastics, against degradation under the influence of U.V. radiation.Type: GrantFiled: May 16, 1975Date of Patent: June 14, 1977Assignee: Sandoz Ltd.Inventors: Lajos Avar, Kurt Hofer
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Patent number: 4008200Abstract: The present invention concerns a novel method of stabilizing organic material susceptible to degradation under the effect of heat, oxidation or ultra-violet light which comprises treating said material with a compound of the formula: ##STR1## WHEREIN R.sub.1, R.sub.2 and R.sub.3 are substituents, e.g. alkyl and Me is hydrogen or a metal cation.Type: GrantFiled: April 11, 1975Date of Patent: February 15, 1977Assignee: Sandoz Ltd.Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
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Patent number: 3976658Abstract: New ultraviolet light-absorbing compounds of the formula ##SPC1##In whichR.sub.1 is a substituent, e.g. alkyl,R.sub.2 is a substituent, e.g. alkyl,R.sub.3 is hydrogen or a substituents, e.g. alkyl,n is 1, 2 or 3, andR is an n-valent, optionally substituted benzene radical, or a 1- or 2-valent naphthalene or heterocyclic radical,Which are producible by known processes.Such compounds are useful as stabilizers of organic materials, particularly plastics materials, against the degrading action of ultraviolet light and can be either applied as a coating on the organic material, or incorporated therein.Type: GrantFiled: July 8, 1974Date of Patent: August 24, 1976Assignee: Sandoz Ltd.Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
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Patent number: 3975382Abstract: The present invention concerns novel pyrazole (5) pyrazolone (5) metal complexes of the formula ##SPC1##Wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are substituents and Me is a transition metal,Useful in stabilizing sensitive organic material against the degradative effect of U.V. light.Type: GrantFiled: March 14, 1975Date of Patent: August 17, 1976Assignee: Sandoz Ltd.Inventors: Lajos Avar, Kurt Hofer