Patents by Inventor Lajos Avar

Lajos Avar has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4876299
    Abstract: A compound of formula I ##STR1## in which R, R.sub.1, R.sub.10 and R.sub.11 are organic radicals. These compounds are suitable as U.V. absorbers.
    Type: Grant
    Filed: April 1, 1987
    Date of Patent: October 24, 1989
    Assignee: Sandoz Ltd.
    Inventor: Lajos Avar
  • Patent number: 4859725
    Abstract: A compound of formula I ##STR1## in which R to R.sub.5 are organic radicals, for use as a light stabilizer in polymeric systems.
    Type: Grant
    Filed: August 23, 1988
    Date of Patent: August 22, 1989
    Assignee: Sandoz Ltd.
    Inventor: Lajos Avar
  • Patent number: 4780492
    Abstract: A liquid concentrate comprising an oxamide and a 2,2,6,6-tetraalkylpiperidine compound dissolved in an organic solvent is useful for the UV-stabilization of hardenable liquid finishes, particularly automotive finishes.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: October 25, 1988
    Assignee: Sandoz Ltd.
    Inventor: Lajos Avar
  • Patent number: 4774332
    Abstract: A compopund containing one or more units of formula I ##STR1## in which R.sub.1 is --CH.sub.2 C.sub.1-4 alkyl or --CH.sub.3 or both groups R.sub.1 form --(CH.sub.2).sub.5 --;R.sub.2 is --CH.sub.2 C.sub.1-4 alkyl or --CH.sub.3 or both groups R.sub.2 form --(CH.sub.2).sub.5 --;R.sub.3 is furylmethyl, unsubstituted C.sub.1-18 alkyl; C.sub.1-4 alkyl monosubstituted by phenyl, the phenyl group of which is unsubstituted or substituted by 1 to 3 groups selected from --OH and C.sub.1-8 alkyl; C.sub.2-8 alkyl monosubstituted by C.sub.1-4 alkoxy; phenyl, unsubstituted or substituted by 1 to 3 groups selected from C.sub.1-8 alkyl and --OH; or cyclohexy, unsubstituted or monosubstituted by C.sub.1-8 alkyl or --OH.These compounds are useful as light stabilizers for polymeric material.
    Type: Grant
    Filed: July 11, 1986
    Date of Patent: September 27, 1988
    Assignee: Sandoz, Ltd.
    Inventor: Lajos Avar
  • Patent number: 4730017
    Abstract: A compound useful as a light-stabilizer for polymeric material of formula I ##STR1## in which R is hydrogen, oxygen, C.sub.1-8 alkyl or --CO--R.sub.5, where R.sub.5 is --C(R.sub.10).dbd.CH.sub.2, C.sub.1-6 alkyl, phenyl, --CO--O--C.sub.1-4 alkyl or --NR.sub.7 R.sub.8 and where R.sub.7 is hydrogen, C.sub.1-12 alkyl, C.sub.5-6 -cycloalkyl, phenyl, phenylC.sub.1-4 alkyl or C.sub.1-12 alkylphenyl and R.sub.8 is C.sub.1-12 alkyl or hydrogen;each R.sub.1, independently, is --CH.sub.3 or --CH.sub.2 (C.sub.1-4 alkyl) or both groups R.sub.1 form a group --(CH.sub.2).sub.5 --;each R.sub.2, independently, is --CH.sub.3 or --CH.sub.2 (C.sub.1-4 alkyl) or both groups R.sub.2 form a group --(CH.sub.2).sub.5);R.sub.10 is hydrogen or C.sub.1-4 alkyl; andR.sub.4 is an amide- or ester-forming group.
    Type: Grant
    Filed: September 12, 1986
    Date of Patent: March 8, 1988
    Assignee: Sandoz Ltd.
    Inventor: Lajos Avar
  • Patent number: 4716187
    Abstract: both R.sub.1 's and CH.sub.3 or together form --CH.sub.2).sub.5 ;both R.sub.2 's are CH.sub.3 or together form --CH.sub.2).sub.5 ;R.sub.3 has a significance of R, independently of R, except for oxygen;X is --O--, --NH-- or ##STR2## m is an integer from 1 to 4 inclusive; R.sub.4 is a saturated or unsaturated aliphatic group unsubstituted or substituted by one or two groups selected from --OH and C.sub.1-4 alkoxy and which can be interrupted by an oxygen or sulphur atom; or an aromatic group unsubstituted or substituted by one or two groups selected from --OH, C.sub.1-4 alkyl and C.sub.1-4 alkoxy are useful as U.V. light stabilizers in polymeric organic compounds.
    Type: Grant
    Filed: March 15, 1985
    Date of Patent: December 29, 1987
    Assignee: Sandoz Ltd.
    Inventor: Lajos Avar
  • Patent number: 4695600
    Abstract: These compounds are useful as light stabilizers in polymeric systems. ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are organic radicals.
    Type: Grant
    Filed: June 17, 1986
    Date of Patent: September 22, 1987
    Assignee: Sandoz Ltd.
    Inventor: Lajos Avar
  • Patent number: 4661595
    Abstract: A method for preparing a compound of formula I ##STR1## in which X is O or S;both groups R together with the two carbon atoms to which they are attached form a fused aromatic group;R.sub.1 is an organic radical; andn is 0, 1, 2 or 3comprising reacting a compound of formula II ##STR2## where R, R.sub.1 and n are defined above and where each R.sub.3, independently, is C.sub.1-12 alkoxy or one R.sub.3 is C.sub.1-12 alkoxy and the other R.sub.3 is halogen,with elemental sulphur in an alkaline medium, a metal sulphide or a metal hydrosulphide.Compounds of formula I and formula II are useful as photoinitiators.
    Type: Grant
    Filed: July 10, 1985
    Date of Patent: April 28, 1987
    Assignee: Sandoz Ltd.
    Inventor: Lajos Avar
  • Patent number: 4485034
    Abstract: Oxalanilides of formula I ##STR1## in which R is C.sub.6-22 alkyl or C.sub.6-22 alkoxyR.sub.1 and R.sub.2 are independently, hydrogen, C.sub.1-8 alkyl, C.sub.1-12 alkoxy, C.sub.1-12 alkylthio, phenoxy or phenylthio; provided that R.sub.1 and R.sub.2 may not both be selected from alkylthio, phenoxy and phenylthio;and R.sub.3 is hydrogen or C.sub.1-8 alkylcertain of which are novel, are useful as UV-stabilizers in organic polymers and organic polymer-containing coatings, particularly automotive finishes. The compounds have low volatility and excellent solubility in organic solvents such as are used in liquid finishes.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: November 27, 1984
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
  • Patent number: 4415687
    Abstract: 1,3-dihydroxy-4,6-bis-4'-(2',2',6',6',-tetramethylpiperidyl) benzene, its 1'-alkyl or 1'-(substituted alkyl) derivatives and monomeric or polymeric products derived from these compounds by substitution of 1- and 3-hydroxy groups and/or by the linking of hydroxy groups on adjacent units through a bridging groups, are useful as light and heat stabilizers for polymeric organic materials.Corresponding bis(3',4'-dehydro) unsaturated compounds are useful as intermediates.
    Type: Grant
    Filed: July 2, 1982
    Date of Patent: November 15, 1983
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
  • Patent number: 4412024
    Abstract: Oxalanilides of formula I ##STR1## in which R is C.sub.6-22 alkyl or C.sub.6-22 alkoxyR.sub.1 and R.sub.2 are independently, hydrogen, C.sub.1-8 alkyl, C.sub.1-12 alkoxy, C.sub.1-12 alkylthio, phenoxy or phenylthio; provided that R.sub.1 and R.sub.2 may not both be selected from alkylthio, phenoxy and phenylthio;andR.sub.3 is hydrogen or C.sub.1-8 alkylcertain of which are novel, are useful as UV-stabilizers in organic polymers and organic polymer-containing coatings, particularly automotive finishes. The compounds have low volatility and excellent solubility in organic solvents such as are used in liquid finishes.
    Type: Grant
    Filed: September 14, 1981
    Date of Patent: October 25, 1983
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
  • Patent number: 4324628
    Abstract: The present invention relates to a photopolymerization process comprising irradiating a photopolymerizable material with U.V. light of wave length 250 to 400 nm in the presence of a photosensitizing amount of a photoinitiator of formula I, ##STR1## in which R is hydrogen or halogenR.sub.1 is alkyl, cycloalkyl, benzyl, optionally substituted phenyl or (a) ##STR2## either R.sub.2 is optionally substituted alkyl, benzyl, C.sub.6 H.sub.5 --CH.dbd.CH--, 2-thienyl, 2-furyl, 2-(3-chloro)benzothienyl or optionally substituted phenyl, andR.sub.3 is hydrogen or R.sub.2 and R.sub.3 form a radical of formula (b) ##STR3## in which X is a direct bond, --O--, --S--, --CH.sub.2 --, ##STR4## and R.sub.4 and R' have one of the significances of R.sub.2 and R, respectively,with the proviso that when R.sub.1 is (a) R.sub.3 is hydrogen and R.sub.2 and R.sub.4 are free from halogen atoms.
    Type: Grant
    Filed: December 3, 1980
    Date of Patent: April 13, 1982
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Hans-Werner Finck, Evelyne Kalt
  • Patent number: 4165267
    Abstract: The present invention concerns novel photopolymerizable formulations which comprise a photopolymerizable system in association with a photosensitizing amount of the compound of formula ##STR1## WHEREIN R is an unsubstituted or substituted binuclear aromatic group, e.g. phenoxy phenyl,M is 0, 1 or 2 andHal is halogen.
    Type: Grant
    Filed: March 6, 1973
    Date of Patent: August 21, 1979
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Kurt Hofer
  • Patent number: 4146540
    Abstract: The present invention concerns certain novel compounds falling under the general formula: ##STR1## WHEREIN R.sub.1, R.sub.2 and R.sub.3 are substituents, e.g. alkyl and Me is hydrogen or a metal cation.The compounds are useful stabilizers of organic material against the degradative effect of heat, oxidation and U.V. light.
    Type: Grant
    Filed: October 21, 1977
    Date of Patent: March 27, 1979
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
  • Patent number: 4102857
    Abstract: New ultraviolet light-absorbing compounds of the formula ##STR1## IN WHICH R.sub.1 is a substituent, e.g. alkyl,R.sub.2 is a substituent, e.g. alkyl,R.sub.3 is hydrogen or a substituent, e.g. alkyl,N is 1, 2 or 3, andR is an n-valent, optionally substituted benzene radical, or a 1- or 2-valent naphthalene or heterocyclic radical, which are producible by known processes. Such compounds are useful as stabilizers of organic materials, particularly plastics materials, against the degrading action of ultraviolet light and can be either applied as a coating on the organic material, or incorporated therein.Such compounds are useful as stabilizers of organic materials, particularly plastics materials, against the degrading action of ultraviolet light and can be either applied as a coating on the organic material, or incorporated therein.
    Type: Grant
    Filed: August 20, 1976
    Date of Patent: July 25, 1978
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
  • Patent number: 4036812
    Abstract: The present invention concerns novel nickel complexes (I) possessing U.V. stabilizing properties characterized by bearing per molecule 2 monodentate nickel coordinated 1,3-hydrocarbyl-4-(greater than C.sub.1)-acyl-pyrazole-5-oxy ligands and one bidentate or two monodentate nickel coordinated primary or secondary amine ligands, and their use as U.V. stabilizers for e.g. plastics materials.
    Type: Grant
    Filed: December 17, 1975
    Date of Patent: July 19, 1977
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Kurt Hofer
  • Patent number: 4029684
    Abstract: The present invention concerns novel 2-hydroxybenzophenone derivatives and metal complexes thereof of the formula: ##STR1## wherein Z.sub.1, Z.sub.2, Y.sub.1 and Y.sub.2 are each, independently, hydrogen or a substituent, at least one of Y.sub.1 and Y.sub.2 being a group ##STR2## wherein, R.sub.1 is alkyl R.sub.2 is hydrogen or a substituent andA is oxygen, sulphur or ##STR3## The compounds are useful for stabilizing organic material, e.g. plastics, against degradation under the influence of U.V. radiation.
    Type: Grant
    Filed: May 16, 1975
    Date of Patent: June 14, 1977
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Kurt Hofer
  • Patent number: 4008200
    Abstract: The present invention concerns a novel method of stabilizing organic material susceptible to degradation under the effect of heat, oxidation or ultra-violet light which comprises treating said material with a compound of the formula: ##STR1## WHEREIN R.sub.1, R.sub.2 and R.sub.3 are substituents, e.g. alkyl and Me is hydrogen or a metal cation.
    Type: Grant
    Filed: April 11, 1975
    Date of Patent: February 15, 1977
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
  • Patent number: 3976658
    Abstract: New ultraviolet light-absorbing compounds of the formula ##SPC1##In whichR.sub.1 is a substituent, e.g. alkyl,R.sub.2 is a substituent, e.g. alkyl,R.sub.3 is hydrogen or a substituents, e.g. alkyl,n is 1, 2 or 3, andR is an n-valent, optionally substituted benzene radical, or a 1- or 2-valent naphthalene or heterocyclic radical,Which are producible by known processes.Such compounds are useful as stabilizers of organic materials, particularly plastics materials, against the degrading action of ultraviolet light and can be either applied as a coating on the organic material, or incorporated therein.
    Type: Grant
    Filed: July 8, 1974
    Date of Patent: August 24, 1976
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
  • Patent number: 3975382
    Abstract: The present invention concerns novel pyrazole (5) pyrazolone (5) metal complexes of the formula ##SPC1##Wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are substituents and Me is a transition metal,Useful in stabilizing sensitive organic material against the degradative effect of U.V. light.
    Type: Grant
    Filed: March 14, 1975
    Date of Patent: August 17, 1976
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Kurt Hofer