Abstract: Organosilicon compounds are prepared by the addition reaction of a gaseous unsaturated hydrocarbon with a silane or siloxane containing at least one silicon-bonded hydrogen atom in the presence of a hydrosilylation catalyst in a liquid reaction medium. In this process the unsaturated hydrocarbon and optionally the silane or siloxane is dispersed into the liquid reaction medium by a jet eductor (also known as a venturi pump) device and the resultant gas-in-liquid dispersion is introduced into a bubble reactor.

Abstract: Organosilicon compounds are prepared by the addition reaction of a gaseous unsaturated hydrocarbon with a silane or siloxane containing at least one silicon-bonded hydrogen atom in the presence of a hydrosilylation catalyst in a liquid reaction medium. In this process the unsaturated hydrocarbon and optionally the silane or siloxane is dispersed into the liquid reaction medium by a jet eductor (also known as a venturi pump) device and the resultant gas-in-liquid dispersion is introduced into a bubble reactor.

Abstract: A process for the preparation of organoalkoxysilanes containing one or more organic functional groups derived from organic acids or hydrogen cyanates, by a continuous or batch process utilizing a solid guanidinium salt as a phase transfer catalyst for the reaction between a liquid phase haloalkylalkoxysilane and a solid phase alkali or alkaline earth metal salt or ammonium salt of an organic acid or a metal cyanate.

Abstract: A process for the preparation of organoalkoxysilanes containing one or more organic functional groups derived from organic acids or hydrogen cyanates, by a continuous or batch process utilizing a solid guanidinium salt as a phase transfer catalyst for the reaction between a liquid phase haloalkylalkoxysilane and a solid phase alkali or alkaline earth metal salt or ammonium salt of an organic acid or a metal cyanate.

Abstract: Diol derived blocked mercaptofunctional silane compositions in which the silanes comprise cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and processes for their preparation are provided. Also provided are rubber compositions comprising the cyclic diol-derived blocked mercaptofunctional silanes, processes for their preparation and articles of manufacture comprising the rubber compositions, in particular, automotive tires and components thereof.

Abstract: Diol derived blocked mercaptofunctional silane compositions in which the silanes comprise cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and processes for their preparation are provided. Also provided are rubber compositions comprising the cyclic diol-derived blocked mercaptofunctional silanes, processes for their preparation and articles of manufacture comprising the rubber compositions, in particular, automotive tires and components thereof.

Abstract: Silicon fines which have been recovered from an organochlorosilane reactor are treated with HCl or elemental chlorine at an elevated temperature to salvage chlorosilane and metal salt values. Passivation is also achieved.

Abstract: An improved process for producing powdered uranium dioxide from a solution of uranyl nitrate which is suitable for the manufacture of fuel for nuclear reactors. The process is continuous and comprises an incremental precipitation of soluble uranyl nitrate with ammonium hydroxide which is interrupted with an intermediate aging period. The precipitate of ammonium uranate solids is dried and thermally converted to a powdered oxide of uranium.

Abstract: Process for recovering compounds of enriched nuclear fuel from scrap materials is disclosed. The process yields an acid solution with the nuclear fuel dissolved therein. Except for spent filter media, the scrap materials are calcined to produce an oxidized material, which is reduced to a particulate material and leached in an acid bath that contains some recycled acid to yield an acid solution of the nuclear fuel material. The scrap materials comprised of spent filter media are mulched and contacted with the acid solution. The insoluble materials are separated from the acid solution, and at least a portion of the acid solution is recycled to the leaching step, while the remainder of the acid solution is collected for subsequent treatment to recover the dissolved nuclear fuel material. Apparatus for performing the foregoing process is also disclosed.

Abstract: A process for recovering compounds of enriched nuclear fuel from scrap materials is disclosed. The process yields an acid solution with the nuclear fuel dissolved therein. Except for spent filter media, the scrap materials are calcined to produce an oxidized material, which is reduced to a particulate material and leached in an acid bath that contains some recycled acid to yield an acid solution of the nuclear fuel material. The scrap materials comprised of spent filter media are mulched and contacted with the acid solution. The insoluble materials are separated from the acid solution, and at least a portion of the acid solution is recycled to the leaching step, while the remainder of the acid solution is collected for subsequent treatment to recover the dissolved nuclear fuel material. Apparatus for performing the foregoing process is also disclosed.