Abstract: An optical waveguide sensor using an intermediate layer between the preformed optical core and the optical cladding material. This intermediate layer comprises a material that is doped with a sensor material to respond to an analyte of interest by luminescing or by developing optical absorption in the transmission region of the core fiber and that has a refractive index greater than the preformed core. Two configurations provide sensors for ionizing radiation capable of measuring the dose rate and the integrated deposited dose.

Abstract: A process for treating metal surfaces to obtain improved susceptibility to bonding with adhesive compositions is disclosed. A metal surface is oxidized with a halogen to form a monolayer of halide ions on the surface. The halide ions are then exchanged with azide ions to form an azide monolayer on the metal surface. Upon contact of the treated surface with an adhesive composition, the azide layer may be thermally or photochemically decomposed to form active nitrene species, which react to bond the adhesive composition to the metal surface.

Abstract: In a radiation or high energy particle responsive system useful as a scintillator, and comprising,a first component which interacts with said radiation or high energy particle to emit photons in a certain first wavelength range; andat least one additional solute component which absorbs the photons in said first wavelength range and thereupon emits photons in another wavelength range higher than said first range;an improvement is provided wherein at least one of said components absorbs substantially no photons in said wavelength range in which it emits photons, due to a large Stokes shift caused by an excited state intramolecular rearrangement.

Abstract: New polysilane copolymers comprise recurring units of --Si(X)(Y)-- and Si(A)(B)--, Si(X)(Y) being different from Si(A)(B),whereinX and Y together have 1-13 carbon atoms, and X and Y each independently is hydrogen, alkyl, cycloalkyl, phenyl, alkylphenyl, or phenylalkyl, with the proviso that only one of X and Y contains a phenyl moiety, or together X and Y are an alkylene group forming a ring with the adjoining Si atom,and whereinA and B together have 3-13 carbon atoms, and A and B each independently is alkyl or cycloalkyl, with the proviso (a) that when one of A and B is ethyl, the other is not methyl or ethyl, and (b) that when one of A and B is n-propyl and the other is methyl, X and Y are not both methyl.Corresponding homopolysilanes are also provided.Upon ultraviolet irradiation, they photodepolymerize to form volatile products. As a result, they represent a new class of photoresists which enable direct formation of a positive image eliminating the heretofore required development step.

Abstract: New polysilane copolymers comprise recurring units of --Si(X)(Y)-- and Si(A)(B)--, Si(X)(Y) being different from Si(A)(B), whereinX and Y together have 1-13 carbon atoms, and X and Y each independently is hydrogen, alkyl, cycloalkyl, phenyl, alkylphenyl, or phenylalkyl, with the proviso that only one of X and Y contains a phenyl moiety, or together X and Y are an alkylene group forming a ring with the adjoining Si atom, and whereinA and B together have 3-13 carbon atoms, and A and B each independently is alkyl or cycloalkyl, with the proviso (a) that when one of A and B is ethyl, the other is not methyl or ethyl, and (b) that when one of A ad B is n-propyl and the other is methyl, X and Y are not both methyl.Corresponding homopolysilanes are also provided.Upon ultraviolet irradiation, they photodepolymerize to form volatile products. As a result, they represent a new class of photoresists which enable direct formation of a positive image eliminating the heretofore required development step.

Abstract: A combination moisture and hydrogen getter comprises(a) a moisture getter comprising a readily oxidizable metal; and(b) a hydrogen getter comprising (i) a solid acetylenic compound and (ii) a hydrogenation catalyst. A method of scavenging moisture from a closed container uses the combination moisture and hydrogen getter to irreversibly chemically reduce the moisture and chemically bind the resultant hydrogen.

Abstract: The invention relates to the gettering of hydrogen and its isotopes, the gettering materials being painted or coated onto, or otherwise disposed in an area or volume from which hydrogen is to be removed.