Abstract: A sloped tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The reactor can include a downwardly sloped tubular member, a flow divider disposed in the tubular member, and one or more internal trays disposed in the tubular member. The flow divider divides flow of the reaction medium among the trays and the bottom of the tubular member.

Abstract: A reactor system operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The reactor system includes a heat exchanger for heating the reaction medium and a disengagement vessel for disengaging vapor from the heated reaction medium.

Abstract: A multi-level tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The tubular reactor can include a plurality of horizontally elongated and vertically spaced reactor segments coupled to and extending outwardly from a common header. One or more of the reactor segments can contain a tray that divides the internal volume of the reactor segment into upper and lower chambers. The reaction medium can flow away from the header in the upper chambers and back to the header in the lower chambers.

Abstract: A sloped tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The reactor can include a plurality of spaced apart internal trays disposed at different elevations in a downwardly sloping elongated tubular member.

Abstract: A multi-level tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The tubular reactor can include a plurality of horizontally elongated and vertically spaced tubular members coupled to and extending between a pair of horizontally spaced and vertically elongated headers.

Abstract: A horizontal trayed reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The reactor can include a plurality of vertically spaced trays disposed within the horizontally elongated vessel shell. The reaction medium can flow in generally opposite directions on vertically adjacent trays so that the reaction medium flows generally back-and-forth through the reactor.

Abstract: A multi-level tubular reactor operable to facilitate a chemical reaction in a reaction medium flowing therethrough. The tubular reactor can include a horizontally elongated reactor segment containing a tray that divides the internal volume of the reactor segment into upper and lower chambers. The reaction medium can flow through the upper and lower in generally opposite directions.

Abstract: The present invention provides an assembly for use in vertical, gravity flow driven polymerization reactors for combinations of high viscosity, high throughput, and shallow polymer depths. The baffle assembly module of the invention includes a support structure having a plurality of side openings. The side openings allow the escape of vapor liberated from the polymeric melt. The assembly further includes a feed splitter followed by two or more vertically arranged rows of baffle plates with the feed splitter and baffles sequentially positioned in the support structure. The plurality of parallel baffles in a row are angled such that when a polymeric melt contacts a given baffle the polymeric melt moves in a downward direction under the force of gravity. The arrangement of the rows is such that each row (except the lowest row) transfers the polymeric melt to a lower vertically adjacent row until reaching the last row of baffles in the module.

Abstract: The present invention provides an assembly for use in vertical, gravity flow driven polymerization reactors for combinations of high viscosity, high throughput, and shallow polymer depths. The baffle assembly module of the invention includes a support structure having a plurality of side openings. The side openings allow the escape of vapor liberated from the polymeric melt. The assembly further includes a feed splitter followed by two or more vertically arranged rows of baffle plates with the feed splitter and baffles sequentially positioned in the support structure. The plurality of parallel baffles in a row are angled such that when a polymeric melt contacts a given baffle the polymeric melt moves in a downward direction under the force of gravity. The arrangement of the rows is such that each row (except the lowest row) transfers the polymeric melt to a lower vertically adjacent row until reaching the last row of baffles in the module.

Abstract: A process for thermally crystallizing a polyester polymer by introducing pellets into a liquid medium having a temperature of at least 140° C. within a liquid medium zone and crystallizing the submerged pellets at or above the vapor pressure of the liquid medium without increasing the molecular weight of the pellets, and while the pressure on at least a portion of the pellets is equal to or greater than the vapor pressure of the liquid medium, separating at least a portion of said pellets and at least a portion of the liquid medium from each other. The crystallization is desirably conducted in the liquid medium zone without mechanically induced agitation. Optionally, the pellets are formed by an underfluid pelletizer.

Abstract: A process to produce polyester product from alkylene oxide and carboxylic acid. More specifically this process relates to a process to produce polyethylene terephthalate where terephthalic acid and ethylene oxide are reacted to form a partially esterified terephthalic acid product and then the partially esterified product is further reacted with ethylene glycol to produce polyethylene terephthalate.

Abstract: A process for thermally crystallizing a polyester polymer by introducing pellets into a liquid medium having a temperature of at least 140° C. within a liquid medium zone and crystallizing the submerged pellets at or above the vapor pressure of the liquid medium without increasing the molecular weight of the pellets, and while the pressure on at least a portion of the pellets is equal to or greater than the vapor pressure of the liquid medium, separating at least a portion of said pellets and at least a portion of the liquid medium from each other. The crystallization is desirably conducted in the liquid medium zone without mechanically induced agitation. Optionally, the pellets are formed by an underfluid pelletizer.

Abstract: A process for crystallizing a polyester polymer by introducing a molten polyester polymer, such as a polyethylene terephthalate polymer, into a liquid medium at a liquid medium temperature greater than the Tg of the polyester polymer, such as at a temperature ranging from 100° C. to 190° C., and allowing the molten polyester polymer to reside in the liquid medium for a time sufficient to crystallize the polymer under a pressure equal to or greater than the vapor pressure of the liquid medium. A process flow, underwater cutting process, crystallization in a pipe, and a separator are also described.

Abstract: The invention is directed to a method for making copolyesters of terephthalic acid and a diol component including ethylene glycol and includes the steps of adding terephthalic acid and diol to a first esterification reactor and then late addition of supplemental ethylene glycol subsequent to the first esterification reactor but prior to a point where the ethylene glycol partial pressure is reduced below about 300 torr.

Abstract: A process and apparatus for distributing molten thermoplastic material supplied directly from melt polymerization to a plurality of molding machines operating in timed sequence is disclosed. The invention is particularly applicable to transferring molten polyester (normally polyethylene terephthalate or a copolymer thereof) directly from a melt polymerization reactor to injection molding machines for producing molded plastic articles.