Abstract: Shear-thinning ethylene/?-olefin and ethylene/?-olefin/diene monomer interpolymers that do not include a traditional branch-inducing monomer such as norbornadiene are prepared at an elevated temperature in an atmosphere that has little or no hydrogen using a constrained geometry complex catalyst and an activating cocatalyst.

Abstract: This invention relates to a polyolefin copolymer composition produced with a catalyst having a metallocene complex in a single reactor in a process for the polymerization of an &agr;olefin monomer with one or more olefin comonomers, and a molecular weight maximum which occurs in that 50 percent by weight of the composition which has the highest weight percent comonomer content. Preferably, the composition has a comonomer partitioning factor C pf which is equal to or greater than 1.10 or molecular weight partitioning factor M pf which is equal to or greater than 1.15. Preferred composition also have at least 0.01 long chain branches per 1000 carbon atoms along the polymer backbone. These compositions with reverse molecular engineering have superior properties and are easily processable due to the simultaneous presence of the association of high molecular weight with high comonomer content and of long chain branching.

Abstract: The invention relates to a polyolefin copolymer composition produced with a catalyst having a metallocene, complex in a single reactor for the polymer of an &agr;-olefin monomer with one or more olefin comonomers, and a molecule weight maximum which occurs in that 50 percent by weight of the composition which has the highest weight percent comonomer content. Preferably, the composition has a comonomer partitioning fact Cpf which is equal to or greater than 1.10 or molecule weight partitioning fact Mpf which is equal to or greater than 1.15. Preferred composition also have at least 0.01 long chain branches per 1000 carbon atoms along the polymer backbone. These compositions with reverse molecular engineering have. superior properties and are easily processable due to the simultaneous presence of the association of high molecular weight with high comonomer content and of long chain branching.

Abstract: Medium modulus, polyethylene films and bags with improved tear performance are made for heavy-duty packaging applications and hot-fill uses. Film compositions contain high molecular weight linear polyethylene and linear ethylene/.alpha.-olefin interpolymer. The film is at least about 1.25 mils (31 microns) thick and is characterized as having a calculated film density in the range of about 0.923 to about 0.95 grams/cubic centimeter (g/cc) and typically has a tear strength or impact resistance at least 30 percent greater than current industrial polyethylene film. The novel film has superior dimensional stability and strength properties which allow significant down-gauging relative to industrial films used as heavy-duty overwraps, sleeves and bags.