Abstract: Optoelectronic devices are derived from polymers that include structural units of formula wherein R1a and R2a are independently C10-20 alkenyl, C3-20 alkynyl, C3-20 substituted alkenyl, C3-20 substituted alkynyl, or a combination thereof; and R1b is alkyl, substituted alkyl, or a combination thereof.

Abstract: The invention provides an organic electronic device comprising: (i) a multilayer cathode comprising: (a) a conductive layer that is electrically connected as a bus, (b) a layer comprising at least one source of alkali metal ions, alkaline earth metal ions, or lanthanide ions and (c) a conductive metal layer comprising at least one conductive metal species; (ii) at least one electro-active organic layer; and (iii) an anode that is electrically connected to the conductive metal layer.

Abstract: Disclosed is an opto-electroactive device comprising a metallocene of the formula wherein M is zirconium or hafnium; X is halogen and R1–R5 are each independently hydrogen, aryl, alkyl, halogen or —Si(R6)3; or wherein at least two adjacent R substituents on at least one ring are joined to form a fused ring, which may be unsubstituted or substituted with aryl, alkyl, halogen or —Si(R6)3; or wherein the R1 substituents on each ring are joined to link the rings in an ansa bridge, and wherein R6 is an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group. Also disclosed is a method for making an opto-electroactive device comprising a metallocene.

Abstract: A method for making alkylhalosilanes is provided comprising reacting an alkyl halide and silicon in the presence of a copper catalyst comprising copper powder, particulated copper, copper flake, or combinations thereof and at least one co-catalyst.

Abstract: A method for making alkylhalosilanes is provided comprising reacting an alkyl halide and silicon in the presence of a copper catalyst comprising copper powder, particulated copper, copper flake, or combinations thereof and at least one co-catalyst.

Abstract: A method of preparing a contact mass is provided comprising reacting silicon and a cuprous chloride to form a concentrated, catalytic contact mass. Furthermore, a method for making an alkylhalosilane using the aforementioned contact mass is provided comprising effecting reaction between an alkyl halide and silicon in the presence of said concentrated contact mass to produce alkylhalosilane.

Abstract: A silicone composition that includes at least one functionalized polydiorganosiloxane, at least one cure catalyst, at least one reactive diluant, and at least one thermally conductive filler is provided in the present invention. Further embodiments of the present invention include a method for substantially increasing the thermal conductivity of a silicone composition and a thermal interface material containing the aforementioned silicone composition.

Abstract: Unexpected corrosion of downstream sections of a dialkyl carbonate manufacturing apparatus has been traced to alkyl chloroformate impurities, which slowly decompose to yield hydrochloric acid. An improved process and apparatus for dialkyl carbonate synthesis reduce corrosion by physically removing or chemically decomposing the alkyl chloroformate impurities within the corrosion-resistant upstream sections of the apparatus. The alkyl chloroformate may be decomposed by passing it through a passageway at a temperature of about 30° C. to about 130° C. for a time of about 0.5 hour to about 10 hours. The passageway may include one or more holding vessels or a tubular section that promotes plug flow.

Abstract: A polydiorganosiloxane with a polar radical with a dipole moment greater than 2 debye provides a polydiorganosiloxane with an initial viscosity in a range between about 100 centipoise and about 50,000 centipoise. Further embodiments of the present invention include a silicone composition, a method for substantially increasing the thermal conductivity of a silicone composition, and a thermal interface material containing a silicone composition wherein the silicone composition includes the aforementioned polydiorganosiloxane.

Abstract: A silicone composition that includes at least one functionalized polydiorganosiloxane, at least one cure catalyst, at least one reactive diluant, and at least one thermally conductive filler is provided in the present invention. Further embodiments of the present invention include a method for substantially increasing the thermal conductivity of a silicone composition and a thermal interface material containing the aforementioned silicone composition.

Abstract: Unexpected corrosion of downstream sections of a dialkyl carbonate manufacturing apparatus has been traced to alkyl chloroformate impurities, which slowly decompose to yield hydrochloric acid. An improved process and apparatus for dialkyl carbonate synthesis reduce corrosion by physically removing or chemically decomposing the alkyl chloroformate impurities within the corrosion-resistant upstream sections of the apparatus.

Abstract: Unexpected corrosion of downstream sections of a dialkyl carbonate manufacturing apparatus has been traced to alkyl chloroformate impurities, which slowly decompose to yield hydrochloric acid. An improved process and apparatus for dialkyl carbonate synthesis reduce corrosion by physically removing or chemically decomposing the alkyl chloroformate impurities within the corrosion-resistant upstream sections of the apparatus.

Abstract: A method for making an alkylhalosilane is provided wherein the method comprises heat treating silicon and a form of copper at a temperature greater than about 500° C. to produce a contact mass and effecting reaction between an alkyl halide and silicon in the presence of the contact mass to produce alkylhalosilane.

Abstract: A polydiorganosiloxane with a polar radical with a dipole moment greater than 2 provides a polydiorganosiloxane with an initial viscosity in a range between about 100 centipoise and about 50,000 centipoise.

Abstract: A flame retardant polycarbonate composition includes (A) at least one polycarbonate and (B) a silsesquioxane flame retardant. The flame retardant polycarbonate composition can be made by providing a polycarbonate and incorporating a flame retardant amount of a silsesquioxane into the polycarbonate. An article can be molded from the composition.

Abstract: Dialkyldihalosilane formation during direct method alkylhalosilane production is promoted by effecting reaction between alkyl halide and powdered silicon in the presence of a catalyst comprising copper, zinc, and aluminum and further comprising an amount of phosphorus and tin wherein the amount of phosphorus and tin substantially enhances the selectivity of dialkyldihalosilane formation in comparison to the selectivity of dialkyldihalosilane formation in the presence of the catalyst comprising copper, zinc, aluminum and tin without phosphorus.

Abstract: A method for forming a dialkyldichlorosilane, comprising reacting elemental silicon with an alkyl chloride using copper as a catalyst together with promoters zinc, tin, and a special promoter. The special promoter is silver, a silver compound, gold, a gold compound, or combinations thereof. The alkyl may be methyl such that the dialkyldichlorosilane is dimethyldichlorosilane and the alkyl chloride is methyl chloride. The reacting generates the dialkyldichlorosilane in accordance with a first selectivity for the dialkyldichlorosilane that exceeds a second selectivity for the dialkyldichlorosilane. The second selectivity is a selectivity for the dialkyldichlorosilane that would have existed had the special promoter been absent.

Abstract: A current limiting device comprises at least two electrodes; an electrically conductive composite material between the electrodes; interfaces between the electrodes the said composite material; and an inhomogeneous resistance distribution structure at the interfaces. During a high current event, adiabatic resistive heating at the interfaces causes rapid thermal expansion and vaporization and at least a partial physical separation at the interfaces; so the resistance of the current limiting device increases. The composite material comprises at least one polymeric matrix material and at least one electrically conductive material, and the polymeric matrix material comprises at least one epoxy and at least one silicone.

Abstract: A current limiting device comprises at least two electrodes; an electrically conductive composite material between the electrodes; interfaces between the electrodes the said composite material; and an inhomogeneous resistance distribution structure at the interfaces. During a high current event, adiabatic resistive heating at the interfaces causes rapid thermal expansion and vaporization and at least a partial physical separation at the interfaces; so the resistance of the current limiting device increases. The composite material comprises at least one polymeric matrix material and at least one electrically conductive material, and the polymeric matrix material comprises at least one epoxy and at least one silicone.

Abstract: A current limiting device comprises at least two electrodes; an electrically conductive composite material between the electrodes; interfaces between the electrodes the said composite material; and an inhomogeneous resistance distribution structure at the interfaces. During a high current event, adiabatic resistive heating at the interfaces causes rapid thermal expansion and vaporization and at least a partial physical separation at the interfaces; so the resistance of the current limiting device increases. The composite material comprises at least one polymeric matrix material and at least one electrically conductive material, and the polymeric matrix material comprises at least one epoxy and at least one silicone.