Abstract: On-line control of a process is achieved by feedforward computations of manipulated variable setpoints modified during each of frequent optimization cycles by feedback trim determined by actual versus predicted effects of setpoint changes on the process controlled variables. Process, economic, contractual and equipment parameter values are continuously polled and collected and used to compute the optimal setpoints for the manipulated variables before the feedback trim is applied. Drift factors are added to the feedback trim to provide on-line calibration of key measuring instruments. Drifts in process performance are updated on-line periodically through self-tuning routines computed as calibration factors for predictor and control equations based on rigorous process simulations and actual plant performance. The equations take the form of polynomials in which each term contains an adjustable coefficient and one or more variable process parameter.

Abstract: A modified polypropylene having a substantially isotactic homopolypropylene and a propylene/olefin random copolymer, the modified polypropylene including up to about 50 chain disruptors per 1000 propylene repeat units. The chain disruptors are racemic polypropylene diads and olefin, the olefin being incorporated into the high end of the molecular weight distribution of the modified polypropylene.