Patents by Inventor Larry W. Gatlin

Larry W. Gatlin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7211665
    Abstract: 1,3,5-(2H2,4H2,6H2) tripropanediamine N,N,N?,N?,N?,N? hexamethyl is used to scavenge sulfur compounds from hydrocarbons. A novel method of making the triazine comprises autocondensing (CH3)2NCH2CH2CH2N?CH2.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: May 1, 2007
    Assignee: Clearwater International, L.L.C.
    Inventor: Larry W. Gatlin
  • Patent number: 7140433
    Abstract: A new class of sulfur scavenging or converting compositions is disclosed comprising diamine terminated, amine-aldehyde adducts, where the adducts are substantially bimolecular amine-aldehyde adducts and the composition is substantially free of trimer and/or triazines. Methods for making and using the new class of sulfur scavenging or converting composition are also disclosed.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: November 28, 2006
    Assignee: Clearwater International, LLC
    Inventors: Larry W. Gatlin, Daniel R. Dostie, Timothy Eric Gatlin
  • Patent number: 7060198
    Abstract: Carboxylate salts of amines are used as components of heat exchange fluids. The amines may have a ratio of N to C of 1:0 to 1:12 and the carboxylate anion may be derived from an acid of the formula H(CH2)0-3COOH. A preferred monoamine heat exchange fluid utilizes triethanolamine formate. Lower carboxylate salts of diamines and triamines having the formula R2[N[(CH2)mNR]1-2]R where each R is independently selected from moieties of the formula —CnH2n+1 and moieties of the formula H[O(CH2)1-4]—, each m is independently a number from 1 to 6, and each n is a number from 1 to 4, are disclosed as compounds.
    Type: Grant
    Filed: May 8, 2002
    Date of Patent: June 13, 2006
    Assignee: Clearwater International, L.L.C.
    Inventors: Kevin W. Smith, Larry W. Gatlin, John H. Hallman
  • Patent number: 6806234
    Abstract: Compounds of the formula H(CH2)zCOO—[C2H4O]xCyH2y+1 where z is 0-2, x is an integer from 1 to 5 and y is an integer from 4-9 are used as emulsion breakers and defoamers in formation treatment fluids in the recovery of hydrocarbons from subterranean formations. A preferred material has the formula HCOO—[C2H4O]3C6H7.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: October 19, 2004
    Assignee: Clearwater International, LLC
    Inventors: Kevin W. Smith, Joseph Miller, Larry W. Gatlin
  • Publication number: 20030209689
    Abstract: Carboxylate salts of amines are used as components of heat exchange fluids. The amines may have a ratio of N to C of 1:0 to 1:12 and the carboxylate anion may be derived from an acid of the formula H(CH2)0-3COOH. A preferred monoamine heat exchange fluid utilizes triethanolamine formate. Lower carboxylate salts of diamines and triamines having the formula R2[N[(CH2)mNR]1-2]R where each R is independently selected from moieties of the formula —CnH2n+1 and moieties of the formula H[O(CH2)1-4]—, each m is independently a number from 1 to 6, and each n is a number from 1 to 4, are disclosed as compounds.
    Type: Application
    Filed: May 8, 2002
    Publication date: November 13, 2003
    Applicant: Clearwater, Inc.
    Inventors: Kevin W. Smith, Larry W. Gatlin, John H. Hallman
  • Publication number: 20030089641
    Abstract: 1,3,5 (2H2,4H2,6H2) tripropanediamine N,N,N′,N′,N″,N″ hexamethyl is used to scavenge sulfur compounds from hydrocarbons. A novel method of making the triazine comprises autocondensing (CH3)2N CHCH2CH2N═CH2.
    Type: Application
    Filed: November 8, 2002
    Publication date: May 15, 2003
    Applicant: Clearwater International LLC.
    Inventor: Larry W. Gatlin
  • Publication number: 20030092580
    Abstract: An invert emulsion, in which the aqueous phase includes a low concentration of potassium formate, is used in well drilling. The low concentration of potassium formate may be maintained by monitoring the potassium level in the circulating drilling fluid and/or by intermittently measuring the water activity of the drilling fluid. As an emulsifier, a reaction product of tall oil and a fatty alkanolamide may be used, optionally with an additional reaction product of tall oil with an aminoethylpiperazine.
    Type: Application
    Filed: October 9, 2002
    Publication date: May 15, 2003
    Applicant: Clearwater, Inc.
    Inventors: Rusty R. Mackey, Larry W. Gatlin
  • Publication number: 20030036571
    Abstract: Compounds of the formula H(CH2)ZCOO—[C2H4O]XCYH2Y+1 where z is 0-2, x is an integer from 1 to 5 and y is an integer from 4-9 are used as emulsion breakers and defoamers in formation treatment fluids in the recovery of hydrocarbons from subterranean formations. A preferred material has the formula HCOO—[C2H4O]3C6H7.
    Type: Application
    Filed: August 19, 2002
    Publication date: February 20, 2003
    Inventors: Kevin W. Smith, Joseph Miller, Larry W. Gatlin
  • Patent number: 6489272
    Abstract: A composition useful as a well lubricant, solvent, emulsifier, and performance extender for corrosion inhibitors in high velocity gas, oil or water drilling, production or gathering applications, that is preferably formed by the reaction and distillation of a tall oil fatty acid with a fatty alkanolamide, preferably in the presence of methyl ester of fatty acids, and most preferably when further reacted and distilled with an emulsifier such as coconut oil diethanolamide or distilled tall oil amide of aminoethylpiperazine. The fatty acids and oils useful in the invention can range from C8 to C24, with C12, C14, C16, C18 and C20 fatty acids and oils being most preferred. The presence of methyl ester is preferred because it functions as a foam suppressant, diluent and amine scavenger during distillation.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: December 3, 2002
    Inventor: Larry W. Gatlin
  • Publication number: 20020157989
    Abstract: Potassium formate is used together with a sulfide scavenger to remove and otherwise treat sulfhydryl compounds such as hydrogen sulfide present in hydrocarbons and aqueous substrates
    Type: Application
    Filed: April 23, 2002
    Publication date: October 31, 2002
    Applicant: Clearwater, Inc.
    Inventors: Larry W. Gatlin, Wayne Mueller
  • Publication number: 20010006935
    Abstract: A composition useful as a well lubricant, solvent and emulsifier that is preferably formed by the reaction and distillation of a tall oil fatty acid with a fatty alkanolamide, preferably in the presence of methyl ester of fatty acids, and most preferably when further reacted and distilled with an emulsifier such as coconut oil diethanolamide. The fatty acids and oils useful in the invention can range from C8 to C24, with C12, C14, C16, C18 and C20 fatty acids and oils being most preferred. The presence of methyl ester is preferred because it functions as a foam supressant, diluent and amine scavenger during distillation.
    Type: Application
    Filed: February 1, 2001
    Publication date: July 5, 2001
    Inventor: Larry W. Gatlin
  • Patent number: 6194361
    Abstract: A composition useful as a well lubricant, solvent and emulsifier that is preferably formed by the reaction and distillation of a tall oil fatty acid with a fatty alkanolamide, preferably in the presence of methyl ester of fatty acids, and most preferably when further reacted and distilled with an emulsifier such as coconut oil diethanolamide or distilled tall oil amide of AEP. The fatty acids and oils useful in the invention can range from C8 to C24, with C12, C14, C16, C18 and C20 fatty acids and oils being most preferred. The presence of methyl ester is preferred because it functions as a foam supressant, diluent and amine scavenger during distillation.
    Type: Grant
    Filed: May 14, 1998
    Date of Patent: February 27, 2001
    Inventor: Larry W. Gatlin
  • Patent number: 5498707
    Abstract: A composition adapted to convert hydrogen sulfide and organic sulfides to nontoxic polymers. The compositions comprise amine resin solutions made by reacting sterically hindered amines such as selected diamines, triamines, amino alcohols, and mixtures thereof, with aldehydes, aldehyde donors, or the reaction products of lower alkanolamines and lower aldehydes. The subject compositions are preferably made by reacting the sterically hindered amines and aldehyde components in about a 1:1 molar ratio at a temperature ranging from about 110.degree. to about 120.degree. F. (about 43.degree. to about 49.degree. C.), using enough of the sterically hindered amine to produce a reaction product having a pH ranging from about 10.5 to about 12. Streams containing hydrogen sulfide or organic sulfides are preferably treated by contacting such streams with from about 2 to about 4 ppm of the amine solution of the invention per ppm of sulfide.
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: March 12, 1996
    Inventor: Larry W. Gatlin
  • Patent number: 5488103
    Abstract: A composition adapted to convert hydrogen sulfide and organic sulfides to nontoxic polymers. The compositions comprise amine resin solutions made by reacting sterically hindered amines such as selected diamines, triamines, amino alcohols, and mixtures thereof, with aldehydes, aldehyde donors, or the reaction products of lower alkanolamines and lower aldehydes. The subject compositions are preferably made by reacting the sterically hindered amines and aldehyde components in about a 1:1 molar ratio at a temperature ranging from about 110.degree. to about 120.degree. F. (about 43.degree. to about 49.degree. C.), using enough of the sterically hindered amine to produce a reaction product having a pH ranging from about 10.5 to about 12. Streams containing hydrogen sulfide or organic sulfides are preferably treated by contacting such streams with from about 2 to about 4 ppm of the amine solution of the invention per ppm of sulfide.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: January 30, 1996
    Inventor: Larry W. Gatlin
  • Patent number: 5486605
    Abstract: A composition is disclosed that is adapted to convert hydrogen sulfide and organic sulfides to nontoxic polymers. The compositions comprise amine resin solutions made by reacting sterically hindered amines such as amine heads with aldoses selected from the group consisting of D-aldoses having from 3 to 6 carbon atoms. Streams containing hydrogen sulfide or organic sulfides are preferably treated by contacting such streams with from about 2 to about 4 ppm or more of the amine solution of the invention per ppm of sulfide.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: January 23, 1996
    Inventor: Larry W. Gatlin
  • Patent number: 5128049
    Abstract: A method for reducing the hydrogen sulfide content of hydrocarbon-containing fluids and aqueous solutions through a two-stage injection procedure whereby a dilute solution of a scavenging agent is injected into a hydrogen sulfide-containing fluid, followed by equilibration and a second injection of dilute solution of scavenging agent to further reduce the hydrogen sulfide content of the treated fluid.
    Type: Grant
    Filed: January 22, 1991
    Date of Patent: July 7, 1992
    Inventor: Larry W. Gatlin