Abstract: A process is disclosed for the production of refinery transportation fuel or components for refinery blending of transportation fuels having a reduced amount of sulfur and/or nitrogen-containing impurities. The process involves contacting a hydrocarbon feedstock containing the above impurities with an immiscible phase containing hydrogen peroxide and acetic acid in an oxidation zone to selectively oxidize the impurities. After a gravity phase separation, the hydrocarbon phase containing any remaining oxidized impurities, is passed to an extraction zone wherein aqueous acetic acid is used to extract a portion of any remaining oxidized impurities. A hydrocarbon stream having reduced impurities can then be recovered. The acetic acid phase effluents from the oxidation and the extraction zones can then be passed to a common separation zone for recovery of the acetic acid and for optional recycle back to the oxidation and extraction zones.

Abstract: A process is disclosed for the production of refinery transportation fuel or components for refinery blending of transportation fuels having a reduced amount of sulfur and/or nitrogen-containing impurities. The process involves contacting a hydrocarbon feedstock containing the above impurities with an immiscible phase containing hydrogen peroxide and acetic acid in an oxidation zone to selectively oxidize the impurities. After a gravity phase separation, the hydrocarbon phase containing any remaining oxidized impurities, is passed to an extraction zone wherein aqueous acetic acid is used to extract a portion of any remaining oxidized impurities. A hydrocarbon stream having reduced impurities can then be recovered. The acetic acid phase effluents from the oxidation and the extraction zones can then be passed to a common separation zone for recovery of the acetic acid and for optional recycle back to the oxidation and extraction zones.

Abstract: A process is disclosed for the ultradeep desulfurization of a sulfur-containing distillate feedstock.

Abstract: Economical processes are disclosed for the production of components for refinery blending of transportation fuels by selective hydrogenation of sulfur-containing and/or nitrogen-containing organic compounds contained in mixtures of hydrocarbons which are liquid at ambient conditions. Integrated hydrotreating processes of this invention advantageously provide their own source of high-boiling hydrogenation feedstock derived, for example, by fractionation of hydrotreated petroleum distillates. The high-boiling hydrogenation feedstock consisting essentially of material boiling between about 200° C. and about 425° C.

Abstract: A catalytic cracking process is provided for cost effectively separating and stripping hydrocarbon from catalyst while limiting the occurrence of undesired catalytic overcracking and thermal cracking reactions. The process includes the steps of contacting feed with catalyst, grossly separating the larger coked catalyst particles from the hydrocarbon, disengaging the smaller coked catalyst fines from the hydrocarbon, removing volatile hydrocarbon from the grossly separated and disengaged catalyst, and recycling the volatile hydrocarbon back to the gross separating step. The disengager step includes the steps of dampening the flow of grossly separated hydrocarbon and internally cyclone separating the smaller catalyst fines from the hydrocarbon product.

Abstract: A catalytic cracking apparatus is provided for cost-effectively separating and stripping hydrocarbon from catalyst while limiting the occurrence of undesired catalytic overcracking and thermal cracking reactions. The apparatus includes a reactor, a combined gross separator and catalyst stripping vessel, and a disengaging vessel. The combined vessel is positioned to quickly separate catalyst from reactor products, reduce catalytic overcracking and strip volatile hydrocarbon from coked catalyst in one unitary vessel. The disengager is designed to dampen the flow of grossly separated hydrocarbon, substantially separate catalyst fines from the grossly separated hydrocarbon, and convey the catalyst fines to the combined gross separation and catalyst stripping vessel.

Abstract: Effective quenching is provided in a catalytic cracking unit to increase product yield and decrease thermal cracking. Advantageously, the quench is injected at special locations. In the illustrated embodiment, the quench is injected into the oil product immediately downstream of the oil product exit of an internal gross cut separator in a disengaging vessel.

Abstract: A paraffin isomerization zone is described wherein an improvement to the process comprises using a preflash tower in connection with stabilizer and de-isohexanizer towers to efficiently separate the isomerization zone effluent into valuable components having higher octane values and a recycle material which can be reintroduced along with a fresh feed into the isomerization zone reactor.

Abstract: Substantial energy savings are realized in an aromatic extraction process wherein a vapor sidestream is removed from the solvent stripper, compressed and used to provide the heat necesary for distillation in the solvent stripper.