Patents by Inventor Larry Zhao

Larry Zhao has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20250044661
    Abstract: In various embodiments, a tunable optical surface includes a dielectric substrate layer with an array of elongated metal rails extending from the dielectric substrate parallel to one another and spaced from one another to form channels therebetween. The channels are etched deeper into the dielectric substrate to form extended-depth channels. The depth of each extended-depth channel is greater than the height of adjacent elongated metal rails. The dimensions of the elongated metal rails and the extended-depth channels therebetween may be subwavelength with respect to an operational bandwidth. A tunable dielectric material that has a tunable refractive index, such as liquid crystal, is positioned within the extended-depth channels between adjacent elongated metal rails.
    Type: Application
    Filed: February 26, 2024
    Publication date: February 6, 2025
    Inventors: Gleb M. Akselrod, Lie "Larry" Zhao, Erik Edward Josberger, Laura Maria Pulido Mancera, Linda Gail Conway, Prasad Padmanabha Iyer
  • Publication number: 20240353624
    Abstract: A device may include a dielectric substrate layer with an array of multicoated elongated metal rails extending from the dielectric substrate parallel to one another and spaced from one another to form channels therebetween. The dimensions of the multicoated elongated metal rails and the channels therebetween may be subwavelength with respect to an operational bandwidth. In some examples, each multicoated elongated metal rail is formed with a copper core coated with an optically reflective silver coating followed by a passivation coating. In various examples, a conductive barrier material separates each multicoated elongated metal rail from an underlying dielectric substrate layer. A tunable dielectric material that has a tunable refractive index, such as liquid crystal, is positioned within the channels between adjacent multicoated elongated metal rails.
    Type: Application
    Filed: April 24, 2023
    Publication date: October 24, 2024
    Inventors: Gleb M. Akselrod, Lie "Larry" Zhao, Erik Edward Josberger, Prasad Padmanabha Iyer
  • Patent number: 10262943
    Abstract: A substrate is provided having a dual damascene structure formed within a dielectric material over the substrate. The dual damascene structure includes a trench and an opening formed to extend from a bottom of the trench to an underlying conductive material, with the underlying conductive material exposed at a bottom of the opening. The dual damascene structure is exposed to a sealing process by which the exposed surfaces of the dielectric material in the opening are sealed without covering the underlying conductive material exposed at the bottom of the opening. The sealing process can be one or more of deposition of a flowable film, deposition of an amorphous carbon barrier layer, and formation of a self-assembled monolayer of an amino group. After the sealing process, an electroless deposition process is performed to fill the opening with a metallic material in a bottom-to-top manner up to the bottom of the trench.
    Type: Grant
    Filed: January 23, 2018
    Date of Patent: April 16, 2019
    Assignee: Lam Research Corporation
    Inventors: Artur Kolics, William T. Lee, Larry Zhao, Derek Wong, Praveen Nalla, Kaihan Ashtiani, Patrick A. Van Cleemput, Yezdi Dordi
  • Publication number: 20180151503
    Abstract: A substrate is provided having a dual damascene structure formed within a dielectric material over the substrate. The dual damascene structure includes a trench and an opening formed to extend from a bottom of the trench to an underlying conductive material, with the underlying conductive material exposed at a bottom of the opening. The dual damascene structure is exposed to a sealing process by which the exposed surfaces of the dielectric material in the opening are sealed without covering the underlying conductive material exposed at the bottom of the opening. The sealing process can be one or more of deposition of a flowable film, deposition of an amorphous carbon barrier layer, and formation of a self-assembled monolayer of an amino group. After the sealing process, an electroless deposition process is performed to fill the opening with a metallic material in a bottom-to-top manner up to the bottom of the trench.
    Type: Application
    Filed: January 23, 2018
    Publication date: May 31, 2018
    Inventors: Artur Kolics, William T. Lee, Larry Zhao, Derek Wong, Praveen Nalla, Kaihan Ashtiani, Patrick A. Van Cleemput, Yezdi Dordi
  • Patent number: 9875968
    Abstract: A substrate is provided having a dual damascene structure formed within a dielectric material over the substrate. The dual damascene structure includes a trench and an opening formed to extend from a bottom of the trench to an underlying conductive material, with the underlying conductive material exposed at a bottom of the opening. The dual damascene structure is exposed to a sealing process by which the exposed surfaces of the dielectric material in the opening are sealed without covering the underlying conductive material exposed at the bottom of the opening. The sealing process can be one or more of deposition of a flowable film, deposition of an amorphous carbon barrier layer, and formation of a self-assembled monolayer of an amino group. After the sealing process, an electroless deposition process is performed to fill the opening with a metallic material in a bottom-to-top manner up to the bottom of the trench.
    Type: Grant
    Filed: February 24, 2017
    Date of Patent: January 23, 2018
    Assignee: Lam Research Corporation
    Inventors: Artur Kolics, William T. Lee, Larry Zhao, Derek Wong, Praveen Nalla, Kaihan Ashtiani, Patrick A. Van Cleemput, Yezdi Dordi
  • Publication number: 20170162512
    Abstract: A substrate is provided having a dual damascene structure formed within a dielectric material over the substrate. The dual damascene structure includes a trench and an opening formed to extend from a bottom of the trench to an underlying conductive material, with the underlying conductive material exposed at a bottom of the opening. The dual damascene structure is exposed to a sealing process by which the exposed surfaces of the dielectric material in the opening are sealed without covering the underlying conductive material exposed at the bottom of the opening. The sealing process can be one or more of deposition of a flowable film, deposition of an amorphous carbon barrier layer, and formation of a self-assembled monolayer of an amino group. After the sealing process, an electroless deposition process is performed to fill the opening with a metallic material in a bottom-to-top manner up to the bottom of the trench.
    Type: Application
    Filed: February 24, 2017
    Publication date: June 8, 2017
    Inventors: Artur Kolics, William T. Lee, Larry Zhao, Derek Wong, Praveen Nalla, Kaihan Ashtiani, Patrick A. Van Cleemput, Yezdi Dordi
  • Patent number: 9666524
    Abstract: A method of forming a barrier on both the sidewalls and bottom of a via and the resulting device are provided. Embodiments include forming a metal line in a substrate; forming a Si-based insulating layer over the metal line and the substrate; forming a via in the Si-based insulating layer down to the metal line; forming a dual-layer Mn/MnN on sidewalls and a bottom surface of the via; and filling the via with metal.
    Type: Grant
    Filed: April 14, 2016
    Date of Patent: May 30, 2017
    Assignee: GLOBALFOUNDRIES INC.
    Inventors: Moosung Chae, Larry Zhao
  • Patent number: 9583386
    Abstract: A substrate is provided having a dual damascene structure formed within a dielectric material over the substrate. The dual damascene structure includes a trench and an opening formed to extend from a bottom of the trench to an underlying conductive material, with the underlying conductive material exposed at a bottom of the opening. The dual damascene structure is exposed to a sealing process by which the exposed surfaces of the dielectric material in the opening are sealed without covering the underlying conductive material exposed at the bottom of the opening. The sealing process can be one or more of deposition of a flowable film, deposition of an amorphous carbon barrier layer, and formation of a self-assembled monolayer of an amino group. After the sealing process, an electroless deposition process is performed to fill the opening with a metallic material in a bottom-to-top manner up to the bottom of the trench.
    Type: Grant
    Filed: October 2, 2015
    Date of Patent: February 28, 2017
    Assignee: Lam Research Corporation
    Inventors: Artur Kolics, William T. Lee, Larry Zhao, Derek Wong, Praveen Nalla, Kaihan Ashtiani, Patrick A. Van Cleemput, Yezdi Dordi
  • Patent number: 9484252
    Abstract: Integrated circuits and methods for fabricating integrated circuits are provided. In one example, a method for fabricating an integrated circuit includes selectively depositing a metal capping layer on first sidewalls of a copper line while leaving exposed portions of a dielectric layer that are laterally adjacent to the copper line exposed. An ILD layer is deposited overlying the metal capping layer and the exposed portions of the dielectric layer.
    Type: Grant
    Filed: January 8, 2014
    Date of Patent: November 1, 2016
    Assignee: GLOBALFOUNDRIES, INC.
    Inventors: Moosung Chae, Larry Zhao
  • Patent number: 9431294
    Abstract: Integrated circuits and methods for producing the same are provided. A method for producing an integrated circuit includes forming an interconnect trench in a dielectric layer, and forming a conformal barrier layer overlying the dielectric layer and within the interconnect trench. A barrier spacer is formed by removing the conformal barrier layer from an interconnect trench bottom, and an interconnect is formed within the interconnect trench after forming the barrier spacer. An air gap trench is formed in the dielectric layer adjacent to the barrier spacer, and a top cap is formed overlying the interconnect and the air gap trench, where the top cap bridges the air gap trench to produce an air gap in the air gap trench.
    Type: Grant
    Filed: October 28, 2014
    Date of Patent: August 30, 2016
    Assignee: GLOBALFOUNDRIES, INC.
    Inventors: Ming He, Errol Todd Ryan, Roderick Alan Augur, Craig Child, Larry Zhao
  • Publication number: 20160225712
    Abstract: A method of forming a barrier on both the sidewalls and bottom of a via and the resulting device are provided. Embodiments include forming a metal line in a substrate; forming a Si-based insulating layer over the metal line and the substrate; forming a via in the Si-based insulating layer down to the metal line; forming a dual-layer Mn/MnN on sidewalls and a bottom surface of the via; and filling the via with metal.
    Type: Application
    Filed: April 14, 2016
    Publication date: August 4, 2016
    Inventors: Moosung CHAE, Larry ZHAO
  • Patent number: 9362228
    Abstract: A method of forming a barrier on both the sidewalls and bottom of a via and the resulting device are provided. Embodiments include forming a metal line in a substrate; forming a Si-based insulating layer over the metal line and the substrate; forming a via in the Si-based insulating layer down to the metal line; forming a dual-layer Mn/MnN on sidewalls and a bottom surface of the via; and filling the via with metal.
    Type: Grant
    Filed: October 22, 2013
    Date of Patent: June 7, 2016
    Assignee: GLOBALFOUNDRIES INC.
    Inventors: Moosung Chae, Larry Zhao
  • Publication number: 20160118292
    Abstract: Integrated circuits and methods for producing the same are provided. A method for producing an integrated circuit includes forming an interconnect trench in a dielectric layer, and forming a conformal barrier layer overlying the dielectric layer and within the interconnect trench. A barrier spacer is formed by removing the conformal barrier layer from an interconnect trench bottom, and an interconnect is formed within the interconnect trench after forming the barrier spacer. An air gap trench is formed in the dielectric layer adjacent to the barrier spacer, and a top cap is formed overlying the interconnect and the air gap trench, where the top cap bridges the air gap trench to produce an air gap in the air gap trench.
    Type: Application
    Filed: October 28, 2014
    Publication date: April 28, 2016
    Inventors: Ming He, Errol Todd Ryan, Roderick Alan Augur, Craig Child, Larry Zhao
  • Publication number: 20160118296
    Abstract: A substrate is provided having a dual damascene structure formed within a dielectric material over the substrate. The dual damascene structure includes a trench and an opening formed to extend from a bottom of the trench to an underlying conductive material, with the underlying conductive material exposed at a bottom of the opening. The dual damascene structure is exposed to a sealing process by which the exposed surfaces of the dielectric material in the opening are sealed without covering the underlying conductive material exposed at the bottom of the opening. The sealing process can be one or more of deposition of a flowable film, deposition of an amorphous carbon barrier layer, and formation of a self-assembled monolayer of an amino group. After the sealing process, an electroless deposition process is performed to fill the opening with a metallic material in a bottom-to-top manner up to the bottom of the trench.
    Type: Application
    Filed: October 2, 2015
    Publication date: April 28, 2016
    Inventors: Artur Kolics, William T. Lee, Larry Zhao, Derek Wong, Praveen Nalla, Kaihan Ashtiani, Patrick A. Van Cleemput, Yezdi Dordi
  • Patent number: 9318436
    Abstract: One illustrative method disclosed herein includes forming a trench/via in a layer of insulating material, forming a barrier layer in the trench/via, forming a copper-based seed layer on the barrier layer, converting at least a portion of the copper-based seed layer into a copper-based nitride layer, depositing a bulk copper-based material on the copper-based nitride layer so as to overfill the trench/via and performing at least one chemical mechanical polishing process to remove excess materials positioned outside of the trench/via to thereby define a copper-based conductive structure. A device disclosed herein includes a layer of insulating material, a copper-based conductive structure positioned in a trench/via within the layer of insulating material and a copper-based silicon or germanium nitride layer positioned between the copper-based conductive structure and the layer of insulating material.
    Type: Grant
    Filed: August 27, 2014
    Date of Patent: April 19, 2016
    Assignee: GLOBALFOUNDRIES Inc.
    Inventors: Xunyuan Zhang, Larry Zhao, Ming He, Sean Lin, John Iacoponi, Errol Todd Ryan
  • Patent number: 9287183
    Abstract: A method for detecting contamination on a patterned substrate includes: performing a via etch operation on a substrate, wherein the via etch operation is configured to define a via feature on the substrate and expose an etch-stop layer at a bottom of the via feature; performing an etch-stop removal operation on the substrate, wherein the etch-stop removal operation is configured for removing the etch-stop layer at the bottom of the via feature to expose a metallic feature underlying the etch-stop layer; applying an electroless deposition solution to the substrate, the applied electroless deposition solution configured for selectively depositing a metallic material over the exposed metallic feature and on metallic contaminants on exposed surfaces of the substrate, the metallic contaminants being generated from the metallic feature during the etch-stop removal operation; performing an inspection operation on the substrate to identify the metallic contaminants that have been deposited with the metallic material.
    Type: Grant
    Filed: March 31, 2015
    Date of Patent: March 15, 2016
    Assignee: Lam Research Corporation
    Inventors: Larry Zhao, Artur Kolics, Praveen Nalla
  • Patent number: 9236299
    Abstract: One method includes forming a barrier layer in a trench/opening in an insulating material, forming a first region of a copper material above the barrier layer, forming a metal layer in the trench/opening on the first region of copper material, forming a second region of copper material on the metal layer, performing at least one CMP process to remove any materials positioned above a planarized upper surface of the layer of insulating material outside of the trench/opening so as to thereby define a structure comprised of the metal layer positioned between the first and second regions of copper material, forming a dielectric cap layer above the layer of insulating material and above the structure, and performing a metal diffusion anneal process to form a metal cap layer adjacent at least the upper surface of a conductive copper structure.
    Type: Grant
    Filed: March 7, 2014
    Date of Patent: January 12, 2016
    Assignee: GLOBALFOUNDRIES Inc.
    Inventors: Xunyuan Zhang, Hoon Kim, Christian Witt, Larry Zhao
  • Patent number: 9159610
    Abstract: A method for fabricating an integrated circuit includes providing a conductive material overlying a semiconductor substrate and a dielectric material overlying the conductive material, wherein an opening exposes a surface of the conductive material and sidewalls of the dielectric material and selectively depositing a first layer of a first barrier material on the surface of the conductive material with the sidewalls of the dielectric material remaining exposed, the first barrier material being such that, if annealed in an annealing process, the first barrier material would diffuse into the conductive material. The method further includes modifying the first barrier material on the exposed surface to form a second barrier material, the second barrier material being such that, during an annealing process, the second barrier material does not diffuse into the conductive material and depositing a second layer of the first barrier material along the sidewalls of the opening.
    Type: Grant
    Filed: October 23, 2013
    Date of Patent: October 13, 2015
    Assignee: GLOBALFOUNDIRES, INC.
    Inventors: Xunyuan Zhang, Moosung Chae, Larry Zhao
  • Patent number: RE47630
    Abstract: An approach for forming a semiconductor device is provided. In general, the device is formed by providing a metal layer, a cap layer over the metal layer, and an ultra low k layer over the cap layer. A via is then formed through the ultra low k layer and the cap layer. Once the via is formed, a barrier layer (e.g., cobalt (Co), tantalum (Ta), cobalt-tungsten-phosphide (CoWP), or other metal capable of acting as a copper (CU) diffusion barrier) is selectively applied to a bottom surface of the via. A liner layer (e.g., manganese (MN) or aluminum (AL)) is then applied to a set of sidewalls of the via. The via may then be filled with a subsequent metal layer (with or without a seed layer), and the device may the then be further processed (e.g., annealed).
    Type: Grant
    Filed: October 26, 2016
    Date of Patent: October 1, 2019
    Assignee: GLOBALFOUNDRIES INC.
    Inventors: Larry Zhao, Ming He, Xunyuan Zhang, Sean Xuan Lin
  • Patent number: RE49820
    Abstract: An approach for forming a semiconductor device is provided. In general, the device is formed by providing a metal layer, a cap layer over the metal layer, and an ultra low k layer over the cap layer. A via is then formed through the ultra low k layer and the cap layer. Once the via is formed, a barrier layer (e.g., cobalt (Co), tantalum (Ta), cobalt-tungsten-phosphide (CoWP), or other metal capable of acting as a copper (CU) diffusion barrier) is selectively applied to a bottom surface of the via. A liner layer (e.g., manganese (MN) or aluminum (AL)) is then applied to a set of sidewalls of the via. The via may then be filled with a subsequent metal layer (with or without a seed layer), and the device may the then be further processed (e.g., annealed).
    Type: Grant
    Filed: August 31, 2019
    Date of Patent: January 30, 2024
    Assignee: GlobalFoundries U.S. Inc.
    Inventors: Larry Zhao, Ming He, Xunyuan Zhang, Sean Xuan Lin