Abstract: A process for enhancing biodegradability of polyolefinic materials is provided. The process includes providing a polyolefinic material, mixing the polyolefinic material with at least one fatty reagent, heating up the polyolefinic material mixed with the at least one fatty reagent to the melting temperature of the polyolefinic material to obtain a melted material, letting the melted material cool at room temperature for a time sufficient to obtain a solidified product, and incubating the solidified product with at least one fungal mycelium selected from fungal strains secreting Unspecific Peroxygenases (UPO), in presence of a fungal culture medium.