Patents by Inventor Laurent Vallier
Laurent Vallier has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11380543Abstract: A substrate is provided with a monocrystalline silicon-germanium layer with a first surface covered by a protective oxide obtained by wet process and having a degradation temperature. The protective oxide is transformed into fluorinated salt which is then eliminated. The substrate is placed in a processing chamber at a lower temperature than the degradation temperature and is subjected to a temperature ramp up to a higher temperature than the degradation temperature. The first surface is annealed in a hydrogen atmosphere devoid of silicon, germanium and precursors of the materials forming the target layer. When the temperature ramp is applied, a silicon precursor is inserted in the processing chamber between a loading temperature and the degradation temperature to deposit a monocrystalline buffer layer. A mono-crystalline target layer is deposited by chemical vapour deposition.Type: GrantFiled: December 17, 2019Date of Patent: July 5, 2022Assignees: COMMISSARIAT À L'ÉNERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, UNIVERSITÉ GRENOBLE ALPES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Pierre-Edouard Raynal, Pascal Besson, Jean-Michel Hartmann, Virginie Loup, Laurent Vallier
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Publication number: 20200194259Abstract: A substrate is provided with a monocrystalline silicon-germanium layer with a first surface covered by a protective oxide obtained by wet process and having a degradation temperature. The protective oxide is transformed into fluorinated salt which is then eliminated. The substrate is placed in a processing chamber at a lower temperature than the degradation temperature and is subjected to a temperature ramp up to a higher temperature than the degradation temperature. The first surface is annealed in a hydrogen atmosphere devoid of silicon, germanium and precursors of the materials forming the target layer. When the temperature ramp is applied, a silicon precursor is inserted in the processing chamber between a loading temperature and the degradation temperature to deposit a monocrystalline buffer layer. A mono-crystalline target layer is deposited by chemical vapour deposition.Type: ApplicationFiled: December 17, 2019Publication date: June 18, 2020Applicants: COMMISSARIAT À L'ÉNERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, UNIVERSITÉ GRENOBLE ALPES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEInventors: Pierre-Edouard RAYNAL, Pascal BESSON, Jean-Michel HARTMANN, Virginie LOUP, Laurent VALLIER
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Patent number: 10062602Abstract: The invention relates to a method of etching a layer of porous dielectric material, characterized in that the etching is performed in a plasma formed from at least one silicon-based gas mixed with oxygen (O2) and/or nitrogen (N2) so as to grow a passivation layer all along said etching, at least on flanks of the layer of porous dielectric material and wherein the silicon-based gas is taken from all the compounds of the type SixHy for which the ratio x/y is equal or greater than 0.3 or is taken from all the compounds of the following types: SixFy and SixCly, where x is the proportion of silicon (Si) in the gas and y is the proportion of fluorine (F) or chlorine (Cl) or hydrogen (H) in the gas.Type: GrantFiled: December 27, 2013Date of Patent: August 28, 2018Assignees: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CNRS—Centre National de la Recherche Scientifique, APPLIED MATERIALS, IncInventors: Nicolas Posseme, Sebastien Barnola, Olivier Joubert, Srinivas Nemani, Laurent Vallier
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Patent number: 9583339Abstract: A method is provided for forming spacers for a gate of a field effect transistor, the gate being situated above a layer of semiconductor material, including forming a layer of nitride covering the gate; modifying the layer by plasma implantation of light ions, having an atomic number equal or less than 10, in the layer in order to form a modified layer of nitride, the modifying being performed so as not to modify the layer of nitride over its entire thickness at flanks of the gate; and removing the modified layer of nitride by a selective wet or dry etching, of the modified layer relative to said layer of semiconductor material and relative to the non-modified layer at the flanks of the gate, without etching the layer of semiconductor material, wherein an entire length of the non-modified layer at the flanks remains after the selective wet or dry etching.Type: GrantFiled: April 6, 2016Date of Patent: February 28, 2017Assignees: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CNRS-Centre National de la Recherche Scientifique, APPLIED MATERIALS, Inc.Inventors: Nicolas Posseme, Thibaut David, Olivier Joubert, Thorsten Lill, Srinivas Nemani, Laurent Vallier
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Patent number: 9570317Abstract: A microelectronic method for etching a layer to be etched, including: modifying the layer to be etched from a surface of the layer to be etched and over a depth corresponding to at least a portion of thickness of the layer to be etched to form a film, with the modifying including implanting light ions into the layer to be etched; and removing the film includes a selective etching of the film relative to at least one layer underlying the film.Type: GrantFiled: December 20, 2013Date of Patent: February 14, 2017Assignees: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE JOSEPH FOURIERInventors: Nicolas Posseme, Olivier Joubert, Laurent Vallier
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Publication number: 20160300709Abstract: A method is provided for forming spacers for a gate of a field effect transistor, the gate being situated above a layer of semiconductor material, including forming a layer of nitride covering the gate; modifying the layer by plasma implantation of light ions, having an atomic number equal or less than 10, in the layer in order to form a modified layer of nitride, the modifying being performed so as not to modify the layer of nitride over its entire thickness at flanks of the gate; and removing the modified layer of nitride by a selective wet or dry etching, of the modified layer relative to said layer of semiconductor material and relative to the non-modified layer at the flanks of the gate, without etching the layer of semiconductor material, wherein an entire length of the non-modified layer at the flanks remains after the selective wet or dry etching.Type: ApplicationFiled: April 6, 2016Publication date: October 13, 2016Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CNRS Centre National de la Recherche Scientifique, APPLIED MATERIALS, Inc.Inventors: Nicolas POSSEME, Thibaut David, Olivier Joubert, Thorsten Lill, Srinivas Nemani, Laurent Vallier
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Publication number: 20160035581Abstract: A microelectronic method for etching a layer to be etched, including: modifying the layer to be etched from a surface of the layer to be etched and over a depth corresponding to at least a portion of thickness of the layer to be etched to form a film, with the modifying including implanting light ions into the layer to be etched; and removing the film includes a selective etching of the film relative to at least one layer underlying the film.Type: ApplicationFiled: December 20, 2013Publication date: February 4, 2016Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE JOSEPH FOURIERInventors: Nicolas POSSEME, Olivier JOUBERT, Laurent VALLIER
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Patent number: 9048011Abstract: The invention relates to the field of production in thin coatings of electronic devices and/or MEMS and relates to an improved method for forming a pattern in a thin SiARC anti-reflective coating, comprising the doping by deposition of such SiARC coating covered with a resist pattern through a protective coating of the resist pattern, then etching the doped zones of the SiARC coating (FIG. 3c).Type: GrantFiled: December 27, 2013Date of Patent: June 2, 2015Assignees: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, CNRS—CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE JOSEPH FOURIERInventors: Nicolas Posseme, Olivier Joubert, Laurent Vallier
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Patent number: 8956886Abstract: In some embodiments, a method of controlling a photoresist trimming process in a semiconductor manufacturing process may include forming a photoresist layer atop a first surface of a substrate, wherein the photoresist layer comprises a lower layer having a first pattern to be etched into the first surface of the substrate, and an upper layer having a second pattern that is not etched into the first surface of the substrate; trimming the photoresist layer in a direction parallel to the first surface of the substrate; measuring a trim rate of the second pattern using an optical measuring tool during the trimming process; and correlating the trim rate of the second pattern to a trim rate of the first pattern to control the trim rate of the first pattern during the trimming process.Type: GrantFiled: March 11, 2014Date of Patent: February 17, 2015Assignee: Applied Materials, Inc.Inventors: Samer Banna, Olivier Joubert, Lei Lian, Maxime Darnon, Nicolas Posseme, Laurent Vallier
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Publication number: 20140273297Abstract: In some embodiments, a method of controlling a photoresist trimming process in a semiconductor manufacturing process may include forming a photoresist layer atop a first surface of a substrate, wherein the photoresist layer comprises a lower layer having a first pattern to be etched into the first surface of the substrate, and an upper layer having a second pattern that is not etched into the first surface of the substrate; trimming the photoresist layer in a direction parallel to the first surface of the substrate; measuring a trim rate of the second pattern using an optical measuring tool during the trimming process; and correlating the trim rate of the second pattern to a trim rate of the first pattern to control the trim rate of the first pattern during the trimming process.Type: ApplicationFiled: March 11, 2014Publication date: September 18, 2014Applicant: APPLIED MATERIALS, INC.Inventors: SAMER BANNA, OLIVIER JOUBERT, LEI LIAN, MAXIME DARNON, NICOLAS POSSEME, LAURENT VALLIER
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Publication number: 20140183159Abstract: The invention relates to the field of production in thin coatings of electronic devices and/or MEMS and relates to an improved method for forming a pattern in a thin SiARC anti-reflective coating, comprising the doping by deposition of such SiARC coating covered with a resist pattern through a protective coating of the resist pattern, then etching the doped zones of the SiARC coating (FIG. 3c).Type: ApplicationFiled: December 27, 2013Publication date: July 3, 2014Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENE ALT, Universite Joseph Fourier, CNRS-Centre National de la Recherche ScientifiqueInventors: Nicolas POSSEME, Olivier JOUBERT, Laurent VALLIER
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Publication number: 20140187035Abstract: The invention relates to a method of etching a layer of porous dielectric material, characterized in that the etching is performed in a plasma formed from at least one silicon-based gas mixed with oxygen (O2) and/or nitrogen (N2) so as to grow a passivation layer all along said etching, at least on flanks of the layer of porous dielectric material and wherein the silicon-based gas is taken from all the compounds of the type SixHy for which the ratio x/y is equal or greater than 0.3 or is taken from all the compounds of the following types: SixFy and SixCly, where x is the proportion of silicon (Si) in the gas and y is the proportion of fluorine (F) or chlorine (Cl) or hydrogen (H) in the gas.Type: ApplicationFiled: December 27, 2013Publication date: July 3, 2014Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENE ALT, APPLIED MATERIALS, Inc., CNRS Centre National de la Recherche ScientifiqueInventors: Nicolas POSSEME, Sebastien BARNOLA, Olivier JOUBERT, Srinivas NEMANI, Laurent VALLIER
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Publication number: 20140187046Abstract: The invention relates to a method for forming spacers for a gate of a field effect transistor, the gate being situated above a layer of semiconductor material, comprising a step of forming a layer of nitride covering the transistor gate, the method being characterized in that it comprises: after the step of forming the layer of nitride, at least one step of modifying the layer of nitride by implantation of light ions in the layer of nitride in order to form a modified layer of nitride, the step of modification being performed so as not to modify the layer of nitride over its entire thickness at flanks of the gate, the step of modifying the layer of nitride by implantation being performed using a plasma comprising the light ions; at least one step of removing the modified layer of nitride by means of a selective etching of the modified layer of nitride vis-à-vis said semiconductor material and vis-à-vis the non-modified layer of nitrideType: ApplicationFiled: December 27, 2013Publication date: July 3, 2014Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENE ALT, APPLIED MATERIALS, Inc., CNRS Centre National de la Recherche ScientifiqueInventors: Nicolas POSSEME, Thibaut DAVID, Olivier JOUBERT, Torsten LILL, Srinivas NEMANI, Laurent VALLIER
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Patent number: 6818488Abstract: The invention relates to a process for making a gate for a CMOS transistor structure, made from a stack realized on a face in a semi-conducting material of a substrate, said stack comprising a gate isolation layer, a gate material layer and a gate mask in sequence, the process comprising the following steps: a) anisotropic etching of the top part of the gate material layer not masked by the gate mask, this etching step leaving the bottom part of the gate material layer and leading to the formation of a deposit composed of etching products on the etching sides resulting from the anisotropic etching, b) treatment of the deposit composed of etching products, to make a protection layer reinforced against subsequent etching of the gate material, c) etching of the bottom part of the gate material layer as far as the gate isolation layer, this etching comprising isotropic etching of the gate material layer to make the gate shorter at the bottom than at the top.Type: GrantFiled: September 8, 2003Date of Patent: November 16, 2004Assignees: Commissariat a l'Energie Atomique, Centre National de la RechercheInventors: Olivier Joubert, Giles Cunge, Johann Foucher, David Fuard, Marceline Bonvalot, Laurent Vallier
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Publication number: 20040104411Abstract: The invention relates to a process for making a gate for a CMOS transistor structure, made from a stack realized on a face in a semi-conducting material of a substrate, said stack comprising a gate isolation layer, a gate material layer and a gate mask in sequence, the process comprising the following steps:Type: ApplicationFiled: September 8, 2003Publication date: June 3, 2004Inventors: Olivier Joubert, Giles Cunge, Johann Foucher, David Fuard, Marceline Bonvalot, Laurent Vallier
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Patent number: 6551698Abstract: Method for preparing a silicon substrate to form a thin electric insulating layer (24), characterized in that it comprises: a deoxidation step of at least one part of the silicon substrate (10), then a heat treatment step of the substrate at a temperature of 750° C. or less, the heat treatment being conducted in a NO-containing atmosphere at a pressure of 5.103 Pa (50 mBr) or less, in order to form a layer of silicon oxynitride (22) on the substrate. Use for the production of EPROM and DRAM memories.Type: GrantFiled: April 4, 2001Date of Patent: April 22, 2003Assignee: Commissariat a l'Energie AtomiqueInventors: François Martin, Daniel Bensahel, Caroline Hernandez, Laurent Vallier