Patents by Inventor Lawrence D. Vail
Lawrence D. Vail has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5192727Abstract: Zeolite LZ-202 and other zeolites synthesized in the absence of organic templating agents and having a crystal structure isotypic with the mineral mazzite are subjected to a three-step treatment to greatly increase their surface area, catalytic activity and adsorptive capacity for adsorbates having molecular dimensions as large as the SF.sub.6 molecule. The treatment steps involve an initial conventional NH.sub.4.sup.+ ion-exchange, steaming at temperatures in excess of 300.degree. C. and a low-pH NH.sub.4.sup.+ ion-exchange at pH values below 4.0.Type: GrantFiled: August 19, 1991Date of Patent: March 9, 1993Assignee: UOPInventors: Vinayan Nair, Donald F. Best, Lawrence D. Vail
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Patent number: 5146035Abstract: An improved process is disclosed for the isomerization of butenes, using a catalyst comprising a non-zeolitic molecular sieve to increase the proportion of isobutene or of 1-butene in the product with low formation of undesirable by-products.Type: GrantFiled: December 24, 1990Date of Patent: September 8, 1992Assignee: UOPInventors: Benjamin C. Spehlmann, Gail L. Gray, Lawrence D. Vail, Gregory J. Gajda
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Patent number: 5013337Abstract: This invention relates to a process for separating a mixture of molecular species based on the molecular size (kinetic diameter) or on the degree of polarity of the molecular species using a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2.+-.0.2 :zH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. A composition having the empirical formula expressed in molar ratios: xR:M.sub.1-y M'.sub.y A.sub.2.+-.0.2 :zH.sub.2 O, where M' is a metal such as cobalt, zinc, manganese, iron, nickel, copper, cadmium and gallium may also be used in the process.Type: GrantFiled: April 12, 1990Date of Patent: May 7, 1991Assignee: UOPInventors: Robert L. Bedard, Lawrence D. Vail, Stephen T. Wilson, Edith M. Flanigen
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Patent number: 4985151Abstract: Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of elements(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.Type: GrantFiled: September 19, 1989Date of Patent: January 15, 1991Assignee: UOPInventors: Brent M. T. Lok, Bonita K. Marcus, Lawrence D. Vail, Edith M. Flanigen, Robert L. Patton, Stephen T. Wilson
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Patent number: 4973785Abstract: Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.Type: GrantFiled: April 18, 1988Date of Patent: November 27, 1990Assignee: UOPInventors: Brent M. T. Lok, Bonita K. Marcus, Lawrence D. Vail, Edith M. Flanigen, Robert L. Patton, Stephen T. Wilson
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Patent number: 4935216Abstract: Crystalline molecular sieves having three-dimentional microporous framework structures of ZnO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Zn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Zn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of zinc, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.Type: GrantFiled: April 13, 1984Date of Patent: June 19, 1990Assignee: UOPInventors: Brent M. T. Lok, Lawrence D. Vail, Edith M. Flanigen
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Patent number: 4933068Abstract: This invention relates to a hydrocarbon conversion process using a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2+0.2 :ZH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. This invention also relates to a composition having the empirical formula expressed in molar ratios: XR:M.sub.1-y M.sup.'y A.sub.2+0.2 :ZH.sub.2 O where M' is a metal such as cobalt, zinc, manganese, iron, nickel, cooper, cadmium and gallium.Type: GrantFiled: October 2, 1989Date of Patent: June 12, 1990Assignee: UOPInventors: Robert L. Bedard, Lawrence D. Vail, Stephen T. Wilson, Edith M. Flanigen
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Patent number: 4882038Abstract: Crystalline molecular sieves having a three-dimensional microporous framework structures of MgO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of magnesium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed.Type: GrantFiled: February 16, 1988Date of Patent: November 21, 1989Assignee: UOPInventors: Brent M. T. Lok, Lawrence D. Vail, Edith M. Flanigen
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Patent number: 4880761Abstract: This invention relates to a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2.+-.0.2 :zH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. This invention also relates to a composition having the empirical formula expressed in molar ratios: xR:M.sub.1-y M'.sub.y A.sub.2.+-.0.2 :zH.sub.2 O, where M' is a metal such as cobalt, zinc, manganese, iron, nickel, copper, cadmium and gallium. This invention further relates to a method of preparing the crystalline composition.Type: GrantFiled: December 6, 1988Date of Patent: November 14, 1989Assignee: UOPInventors: Robert L. Bedard, Lawrence D. Vail, Stephen T. Wilson, Edith M. Flanigen
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Patent number: 4822478Abstract: An novel class of iron-aluminum-phosphorus-silicon-oxide molecular sieves is disclosed which contain as framework constituents FeO.sub.2.sup.-, and/or FeO.sub.2.sup.-2, AlO.sub.2.sup.-, PO.sub.2.sup.+ and SiO.sub.2 tetrahedral oxide units. These compositions are prepared hydrothermally, preferably using organic templating agents and are suitably employed as adsorbents and catalysts.Type: GrantFiled: May 6, 1987Date of Patent: April 18, 1989Assignee: UOPInventors: Brent M. T. Lok, Lawrence D. Vail, Edith M. Flanigen
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Patent number: 4793984Abstract: Crystalline molecular sieves having three-dimensional microporous framework structures of ELO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 framework oxide units are disclosed. The molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (EL.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system: "m" represents the molar amount of "R" present per mole of (El.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; "EL" represents at least one element capable of forming a framework oxide unit; and "w", "x", "y" and "z" represent the mole fractions of element(s) "EL", aluminum, phosphorus and silicon, respectively, present as framework oxides. Their use as adsorbents, catalysts, etc. is also disclosed.Type: GrantFiled: April 13, 1984Date of Patent: December 27, 1988Assignee: Union Carbide CorporationInventors: Brent M. Lok, Bonita K. Marcus, Lawrence D. Vail, Edith M. Flanigen, Robert L. Patton, Stephen T. Wilson
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Patent number: 4758419Abstract: Crystalline molecular sieves having a three-dimensional microporous framework structures of MgO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of magnesium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed.Type: GrantFiled: April 13, 1984Date of Patent: July 19, 1988Assignee: Union Carbide CorporationInventors: Brent M. Lok, Lawrence D. Vail, Edith M. Flanigen
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Patent number: 4683217Abstract: A novel class of iron-aluminum-phosphorus-silicon-oxide molecular sieves is disclosed which contain as framework constituents FeO.sub.2.sup.-, and/or FeO.sub.2.sup.-2, AlO.sub.2.sup.-, PO.sub.2.sup.+ and SiO.sub.2 tetrahedral oxide units. These compositions are prepared hydrothermally, preferably using organic templating agents and are suitably employed as adsorbents and catalysts.Type: GrantFiled: April 13, 1984Date of Patent: July 28, 1987Assignee: Union Carbide CorporationInventors: Brent M. Lok, Lawrence D. Vail, Edith M. Flanigen