Abstract: Embodiments of the present invention relate to multilayer films and articles. In one aspect, a multilayer film comprises at least one outer layer comprising at least 50 wt % of a polyethylene composition comprising the reaction product of ethylene and optionally, one or more alpha-olefin comonomers, wherein the polyethylene composition is characterized by the following properties: a. a melt index, I2, of from 0.3 to 3.0 g/10 min; b. a density of from 0.950 to 0.965 g/cm3; c. a melt flow ratio, I10/I2, of from 6.3 to 7.5; and d. a molecular weight distribution (MWD) of from 2.2 to 3.5, wherein the multilayer film has a thickness of at least 2 mils, wherein the multilayer film comprises at least 50% by weight polyethylene, wherein the multilayer film exhibits a surface haze of 13.5% or less when measured according to ASTM 1003-07, and wherein the multilayer film exhibit a water vapor transmission rate of 0.7 g/mil/100 in2/day or less when measured according to ASTM F1249-06 at a temperature of 38° C.

Abstract: A coated article having recyclability properties including a combination of: (a) at least one polyolefin polymer article; and (b) a coating layer of a waterborne acrylic-based matte coating composition having a recyclability property, wherein the recyclability property of the waterborne acrylic-based matte coating composition is such that when the article with the waterborne acrylic-based matte coating composition is reprocessed, the article with the waterborne acrylic-based matte coating composition exhibits at least less than a 30% decreased change in performance compared to a control article without the waterborne acrylic-based matte coating composition; wherein both the control article and the article with the waterborne acrylic-based matte coating composition are both reprocessed the same way; a recyclable coated film structure including at least: (a) at least one first polymer film layer; and (b) at least one coating layer of the above recyclable waterborne acrylic-based matte coating composition; and a

Abstract: An article having recyclability properties including a combination of: (a) at least one polyolefin polymer; and (b) a waterborne adhesive composition having a recyclability property, wherein the recyclability property of the waterborne adhesive composition is such that when the article with the waterborne adhesive composition is reprocessed, the article with the waterborne adhesive composition exhibits less than a 40% decreased change in performance compared to a control article without the waterborne adhesive composition that is reprocessed the same way as the article with the waterborne adhesive composition; a recyclable laminate structure including (a) at least one first polymer film layer; and (?) at least one layer of the above waterborne laminating adhesive composition; and a process for manufacturing the above recyclable laminate structure.

Abstract: An article having recyclability properties including a combination of: (a) a polyolefin polymer; and (b) a solvent-borne adhesive composition having a recyclability property, wherein the recyclability property of the solvent-borne adhesive composition is such that when the article with the solvent-borne adhesive composition is reprocessed, the article with the solvent-borne adhesive composition exhibits less than a 40% decreased change in performance compared to a control article without the solvent-borne adhesive composition that is reprocessed the same way as the article with the solvent-borne adhesive composition; a recyclable laminate structure including at least: (a) at least a first polymer film layer; and (b) a layer of the above solvent-borne laminating adhesive composition; and a process for manufacturing the above recyclable laminate structure.

Abstract: Embodiments of the present invention relate to multilayer films and articles. In one aspect, a multilayer film comprises at least one outer layer comprising at least 50 wt % of a polyethylene composition comprising the reaction product of ethylene and optionally, one or more alpha-olefin comonomers, wherein the polyethylene composition is characterized by the following properties: a. a melt index, I2, of from 0.3 to 3.0 g/10 min; b. a density of from 0.950 to 0.965 g/cm3; c. a melt flow ratio, I10/I2, of from 6.3 to 7.5; and d. a molecular weight distribution (MWD) of from 2.2 to 3.5, wherein the multilayer film has a thickness of at least 2 mils, wherein the multilayer film comprises at least 50% by weight polyethylene, wherein the multilayer film exhibits a surface haze of 13.5% or less when measured according to ASTM 1003-07, and wherein the multilayer film exhibit a water vapor transmission rate of 0.7 g-mil/100 in2/day or less when measured according to ASTM F1249-06 at a temperature of 38° C.

Abstract: According to one embodiment described herein, the forces of a shrink film may be measured. The method of measuring the forces may include providing a shrink film processing unit and a testing vehicle moveable within the shrink film processing unit, positioning a shrink film around the testing vehicle, processing the wrapped testing vehicle by shrinking the shrink film around the testing vehicle as the testing vehicle moves through the shrink film processing unit, and measuring the forces applied by the shrink film on the testing vehicle with one or more force sensors at multiple separate sensor positions on the exterior of the testing vehicle during processing, after processing, or both.

Abstract: According to one embodiment described herein, the forces of a shrink film may be measured. The method of measuring the forces may include providing a shrink film processing unit and a testing vehicle moveable within the shrink film processing unit, positioning a shrink film around the testing vehicle, processing the wrapped testing vehicle by shrinking the shrink film around the testing vehicle as the testing vehicle moves through the shrink film processing unit, and measuring the forces applied by the shrink film on the testing vehicle with one or more force sensors at multiple separate sensor positions on the exterior of the testing vehicle during processing, after processing, or both.

Abstract: The present disclosure relates to a method of promoting optimal stretching of stretch film during a wrapping operation, which method comprises at least the following steps. First a resin suitable for making stretch films is selected. Then a dispersed agent is selected, preferably one which has a refractive index similar to the selected resin such that when a film is made comprising the resin and the dispersed agent, the film will appear somewhat clear. The dispersed agent is then mixed with the resin and a film is formed from the resin containing the dispersed agent. Finally, a load is manually wrapped using such film, wherein during wrapping, the film is stretched to a level where the film becomes more opaque.

Abstract: The instant invention provides a polyethylene blend composition suitable for blown film, method of producing the same, and films made therefrom. The polyethylene blend composition suitable for blown film according to the present invention comprises the melt blending product of: (a) less than or equal to 4 percent by weight of a low density polyethylene (LDPE) having a density in the range of from 0.915 to 0.935 g/cm3, and a melt index (I2) in the range of from greater than 0.8 to less than or equal to 5 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of from 6 to 10; (b) 90 percent or greater by weight of a heterogenous linear low density polyethylene (hLLDPE) having a density in the range of from 0.917 to 0.950 g/cm3, and a melt index (I2) in the range of from 0.1 to less than or equal to 5 g/10 minutes; (c) optionally a hydrotalcite based neutralizing agent; (d) optionally one or more nucleating agents; and (e) optionally one or more antioxidants.

Abstract: The instant invention provides a polyethylene composition suitable for stretch film applications and, method of producing the same, and cast film made therefrom. The linear low density polyethylene composition suitable for stretch film applications according to the present invention comprises: less than or equal to 100 percent by weight of the units derived from ethylene; and less than 35 percent by weight of units derived from one or more ?-olefin comonomers; wherein said linear low density polyethylene composition has a density in the range of from 0.900 to 0.930 g/cm3, a molecular weight distribution (Mw/Mn) in the range of from 2.5 to 4.5, a melt index (I2) in the range of from 0.3 to 10 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of from 2.2 to 3, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of said composition, and a zero shear viscosity ratio (ZSVR) in the range from 1 to 1.2.

Abstract: The instant invention provides an ethylene/alpha-olefin interpolymer suitable for use in shrinkage film applications, and articles made therefrom. The ethylene/alpha-olefin interpolymer according to the present invention has a CDBI of less than 60%, and comprises at least two fractions in crossfractionation of the ethylene/alpha-olefin interpolymer, eluting from 85° C. to 90° C. and from 90° C. to 95° C., comprising a weight fraction ratio of >0.68 and a molecular weight homogeneity index of greater than 0.65; wherein the weight fraction ratio is the ratio of the weight of polymer in each fraction divided by the weight of polymer eluting between 95° C. and 100° C. and the molecular weight homogeneity index is the ratio of the weight average molecular weight of the polymer in the fraction divided by the weight average molecular weight of the polymer eluting between 95° C. and 100° C., and wherein the ethylene/alpha-olefin interpolymer has a density in the range of 0.920 to 0.940 g/cm3.

Abstract: The instant invention provides a polyethylene blend composition suitable for blown film, method of producing the same, and films made therefrom. The polyethylene blend composition suitable for blown film according to the present invention comprises the melt blending product of: (a) less than or equal to 4 percent by weight of a low density polyethylene (LDPE) having a density in the range of from 0.915 to 0.935 g/cm3, and a melt index (I2) in the range of from greater than 0.8 to less than or equal to 5 g/10 minutes, and a molecular weight distribution (Mw/Mn) in the range of from 6 to 10; (b) 90 percent or greater by weight of a heterogenous linear low density polyethylene (hLLDPE) having a density in the range of from 0.917 to 0.950 g/cm3, and a melt index (I2) in the range of from 0.1 to less than or equal to 5 g/10 minutes; (c) optionally a hydrotalcite based neutralizing agent; (d) optionally one or more nucleating agents; and (e) optionally one or more antioxidants.

Abstract: A reactor blend polyethylene composition comprising: from 35 to 70 percent by weight of a first polyethylene component; and a second polyethylene component; wherein the polyethylene resin has a melt index I2 of less than 1 dg/min and greater than or equal to 0.25 dg/min and exhibits a V0.1/V100 of greater than or equal to 9; and wherein the first and second polyethylene components are produced in continuous dual solution polymerization reactors, wherein the second polyethylene component is produced in the presence of the first polyethylene component and wherein a Ziegler-Natta catalyst is present in each of the first and second polymerization reactors is provided. Also provided are methods for producing the polyethylene resin and films made therefrom.

Abstract: Chlorinated and chlorosulfonated polyethylenes are produced by chlorinating substantially linear olefin polymers having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .gtoreq.(I.sub.10 /I.sub.2)-4.63, a critical shear rate at onset of gross melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and Mw/Mn and at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5 and their method of manufacture are disclosed. The chlorosulfonated polyethylenes are produced by treating the chlorinated polyethylenes with a mixture of gaseous chlorine and sulfur dioxide.

Abstract: Chlorinated and chlorosulfonated polyethylenes are produced by chlorinating substantially linear olefin polymers having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63, a critical shear rate at onset of gross melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and M.sub.w /M.sub.n and at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5 and their method of manufacture are disclosed. The chlorosulfonated polyethylenes are produced by treating the chlorinated polyethylenes with a mixture of gaseous chlorine and sulfur dioxide.

Abstract: Chlorinated and chlorosulfonated polyethylenes are produced by chlorinating substantially linear olefin polymers having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63, a critical shear rate at onset of gross melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and Mw/Mn and at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5 and their method of manufacture are disclosed. The chlorosulfonated polyethylenes are produced by treating the chlorinated polyethylenes with a mixture of gaseous chlorine and sulfur dioxide.