Patents by Inventor Lawrence R. Wallace

Lawrence R. Wallace has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6770715
    Abstract: A high molecular weight, medium density polyethylene (HMW, MDPE) is disclosed. The polyethylene comprises from about 85 to about 98 wt % of recurring units of ethylene and about 2 to about 15 wt % of a C3-C10 &agr;-olefin. It has a density from about 0.92 to about 0.944 g/cc, a melt index MI2 from about 0.01 to about 0.5 dg/min, and a melt flow ratio MFR from about 50 to about 300. It has a multimodal molecular weight distribution comprising a high molecular weight component and a low molecular weight component. The low molecular weight component has an MI2 from about 50 to about 600 dg/min and a density from about 0.94 to about 0.97 g/cc. A process for making the medium density polyethylene is also disclosed. The process uses a Ziegler catalyst and applies multiple reaction zones.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: August 3, 2004
    Assignee: Equistar Chemicals, LP
    Inventors: Philip J. Garrison, Lawrence R. Wallace, Danny L. Wise, James H. Meas, Leonard V. Cribbs, Jean A. Merrick-Mack, Paula L. Nygard
  • Publication number: 20030040588
    Abstract: A high molecular weight, medium density polyethylene (HMW, MDPE) is disclosed. The polyethylene comprises from about 85 to about 98 wt % of recurring units of ethylene and about 2 to about 15 wt % of a C3-C10 &agr;-olefin. It has a density from about 0.92 to about 0.944 g/cc, a melt index MI2 from about 0.01 to about 0.5 dg/min, and a melt flow ratio MFR from about 50 to about 300. It has a multimodal molecular weight distribution comprising a high molecular weight component and a low molecular weight component. The low molecular weight component has an MI2 from about 50 to about 600 dg/min and a density from about 0.94 to about 0.97 g/cc. A process for making the medium density polyethylene is also disclosed. The process uses a Ziegler catalyst and applies multiple reaction zones.
    Type: Application
    Filed: September 12, 2002
    Publication date: February 27, 2003
    Applicant: Equistar Chemicals, LP
    Inventors: Philip J. Garrison, Lawrence R. Wallace, Danny L. Wise, James H. Meas, Leonard V. Cribbs, Jean A. Merrick-Mack, Paula L. Nygard
  • Patent number: 6486270
    Abstract: A high molecular weight, medium density polyethylene (HMW, MDPE) is disclosed. The polyethylene comprises from about 85 to about 98 wt % of recurring units of ethylene and about 2 to about 15 wt % of a C3-C10 &agr;-olefin. It has a density from about 0.92 to about 0.944 g/cc, a melt index MI2 from about 0.01 to about 0.5 dg/min, and a melt flow ratio MFR from about 50 to about 300. It has a multimodal molecular weight distribution comprising a high molecular weight component and a low molecular weight component. The low molecular weight component has an MI2 from about 50 to about 600 dg/min and a density from about 0.94 to about 0.97 g/cc. A process for making the medium density polyethylene is also disclosed. The process uses a Ziegler catalyst and applies multiple reaction zones.
    Type: Grant
    Filed: August 25, 2000
    Date of Patent: November 26, 2002
    Assignee: Equistar Chemicals, LP
    Inventors: Philip J. Garrison, Lawrence R. Wallace, Danny L. Wise, James H. Meas, Jr., Leonard V. Cribbs, Jean A. Merrick-Mack, Paula L. Nygard
  • Patent number: 6147167
    Abstract: A process for producing a polyethylene film composition, comprising melt extruding a linear copolymer of ethylene and at least one other olefin having from 3 to 8 carbon atoms, said linear copolymer having a bimodal distribution comprising a high molecular weight fraction having a weight average molecular weight of at least 600,000 and a low molecular weight fraction having a weight average molecular weight of less than 20,000 at a temperature of from 195 to 285.degree. C. in the presence of oxygen in an amount of from about 0.5 to about 6% by volume to improve bubble stability without any significant reduction in tear strength of film produced from said melt extruded linear copolymer.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: November 14, 2000
    Assignee: Equistar Chemicals, LP
    Inventors: Mark P. Mack, James H. Meas, Jr., Paula L. Nygard, Lawrence R. Wallace, Philip J. Garrison
  • Patent number: 5962598
    Abstract: A polyethylene film composition characterized as having a broad molecular weight distribution, Mw/Mm 15, a density of 0.920 to 0.970 g/cc, a melt flow index (190.degree. C./2.16 kg) of 0.01 to 0.2 g/10 min., the polyethylene film composition being produced by melt extruding a linear copolymer at a temperature of at least 180.degree. C. in the presence of an amount of a free radical initiator sufficient to improve bubble stability without any significant reduction in the tear strength of film produced from the composition as compared with film produced from the linear copolymer that has not been treated with the free radical initiator.
    Type: Grant
    Filed: July 26, 1996
    Date of Patent: October 5, 1999
    Assignee: Equistar Chemicals, LP
    Inventors: Mark P. Mack, James H. Meas, Jr., Paula L. Nygard, Lawrence R. Wallace, Philip J. Garrison
  • Patent number: 5502099
    Abstract: This invention provides flexible compositions which have 20-90% by total weight of composition of a filler selected from the group consisting of barium sulfate, zinc oxide, zirconium oxide, zirconium silicate and mixtures thereof, and a thermoplastic resin, which when filled with 20-90% by total weight of composition of the filler, has a flexural strength of less than 7500 psi.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: March 26, 1996
    Assignee: General Electric Company
    Inventor: Lawrence R. Wallace
  • Patent number: 5399608
    Abstract: Compositions comprising a high molecular weight polyester resin derived from a cyclohexanedimethanol and a hexacarbocyclic dicarboxylic acid or mixture of such resins and, optionally, a second linear high molecular weight polyester, optionally further combined with an effective, impact strength-improving amount of a thermoplastic elastomer, such as a polyether ester or a polyetherimide ester, with relatively high loadings of fillers selected from zinc oxide, barium sulfate, zirconium oxide, zirconium silicate, strontium sulfate or a mixture of any of such fillers, provide highly dense thermoplastic molded articles with improved impact strength and properties suitable to replace ceramics and filled thermosets in many important applications.
    Type: Grant
    Filed: January 15, 1992
    Date of Patent: March 21, 1995
    Assignee: General Electric Company
    Inventors: Joel D. Allen, Dennis W. Champlain, Lawrence R. Wallace, Eileen B. Walsh
  • Patent number: 5395875
    Abstract: Compositions comprising copolyetherester resins, copolyetherimide ester resins, or mixtures thereof, in combination with a high molecular weight polyester resin or mixture of such resins, with relatively high loadings of fillers selected from zinc oxide, barium sulfate, zirconium oxide, zirconium silicate, strontium sulfate or a mixture of any of such fillers, provide highly dense thermoplastic molded articles with properties suitable to replace ceramics and filled thermosets in many important applications.
    Type: Grant
    Filed: February 16, 1993
    Date of Patent: March 7, 1995
    Assignee: General Electric Company
    Inventors: Joel D. Allen, Dennis W. Champlain, Richard J. Clark, Lawrence R. Wallace
  • Patent number: 5214088
    Abstract: Compositions comprising copolyetherester resins, copolyetherimide ester resins, or mixtures thereof, in combination with a high molecular weight polyester resin or mixture of such resins, with relatively high loadings of fillers selected from zinc oxide, barium sulfate, zirconium oxide, zirconium silicate, strontium sulfate or a mixture of any of such fillers, provide highly dense thermoplastic molded articles with properties suitable to replace ceramics and filled thermosets in many important applications.
    Type: Grant
    Filed: October 15, 1990
    Date of Patent: May 25, 1993
    Assignee: General Electric Company
    Inventors: Joel D. Allen, Dennis W. Champlain, Richard J. Clark, Lawrence R. Wallace
  • Patent number: 5149734
    Abstract: A novel compositions is disclosed which comprises polybutylene terephthalate, polyethylene terephthalate, and 30-85% by total weight of barium sulfate of said molding composition.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: September 22, 1992
    Assignee: General Electric Company
    Inventors: Robert A. Fisher, Keith N. Gray, Lawrence R. Wallace
  • Patent number: 5132353
    Abstract: A novel molding composition is disclosed which comprises polybutylene terephthalate, polyethylene terephthalate, and 20-85% of zinc oxide by total weight of said molding composition.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: July 21, 1992
    Assignee: General Electric Company
    Inventor: Lawrence R. Wallace
  • Patent number: 4882375
    Abstract: The melt viscosity of polyesters is modified by adding thereto a minor amount of a sulfonated salt of a carboxylic acid.
    Type: Grant
    Filed: September 1, 1988
    Date of Patent: November 21, 1989
    Assignee: General Electric Company
    Inventors: John A. Tyrell, Lawrence R. Wallace
  • Patent number: 4680334
    Abstract: A synergistic effect in reducing the burning characteristics of polymers is obtained by the use of molybdenum based compounds in conjunction with an effective amount of a sulfur-containing polymer whether used alone or as an additive to other polymeric systems.
    Type: Grant
    Filed: September 26, 1985
    Date of Patent: July 14, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Lawrence R. Wallace
  • Patent number: 4556694
    Abstract: Low temperature impact properties of poly(vinyl chloride) are improved by adding to the poly(vinyl chloride) chlorosulfonated polyethylene and chlorinated polyethylene wherein the base polyethylene of each additive has a density of at least 0.94. The use of all three components provides a synergistic lowering of the brittleness temperature as compared to either chlorosulfonated polyethylene or chlorinated polyethylene when added to the poly(vinyl chloride).
    Type: Grant
    Filed: July 26, 1984
    Date of Patent: December 3, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Lawrence R. Wallace