Patents by Inventor Leonardo Dalloro

Leonardo Dalloro has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8247622
    Abstract: A process is described for the preparation of phenol by the hydrodeoxygenation of polyhydroxylated benzene derivatives or by the selective hydroxylation of benzene under depletive conditions, characterized in that the above-mentioned reactions are carried out in the presence of a catalyst based on multi component metal oxides comprising at least one metal selected from the groups VB, VIB, VIII, IB, IIB, IVA, VA.
    Type: Grant
    Filed: October 20, 2010
    Date of Patent: August 21, 2012
    Assignee: Polimeri Europa S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Fausto Genoni, Guido Spano, Franco Rivetti
  • Publication number: 20110092746
    Abstract: A process is described for the preparation of phenol by the hydrodeoxygenation of polyhydroxylated benzene derivatives or by the selective hydroxylation of benzene under depletive conditions, characterized in that the above-mentioned reactions are carried out in the presence of a catalyst based on multi component metal oxides comprising at least one metal selected from the groups VB, VIB, VIII, IB, IIB, IVA, VA.
    Type: Application
    Filed: October 20, 2010
    Publication date: April 21, 2011
    Applicant: POLIMERI EUROPA S.p.A.
    Inventors: Leonardo DALLORO, Alberto Cesana, Roberto Buzzoni, Fausto Genoni, Guido Spano, Franco Rivetti
  • Patent number: 7868210
    Abstract: A process is described for the preparation of phenol by the hydrodeoxygenation of polyhydroxylated benzene derivatives or by the selective hydroxylation of benzene under depletive conditions, characterized in that the above-mentioned reactions are carried out in the presence of a catalyst based on multi component metal oxides comprising at least one metal selected from the groups VB, VIB, VIII, IB, IIB, IVA, VA.
    Type: Grant
    Filed: January 10, 2006
    Date of Patent: January 11, 2011
    Assignee: Polimeri Europa S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Fausto Genoni, Guido Spano′, Franco Rivetti
  • Patent number: 7547778
    Abstract: The present invention relates to a process for the preparation of zeolitic catalysts of the MFI type in spheroidal form. The process consists in emulsifying and consolidating in paraffinic hydrocarbons, in the presence of a non-ionic surface-active agent or a suitable combination of a non-ionic surface-active agent and a cationic surface-active agent, a dispersion of particles of zeolitic material of the MFI type in a silica sol.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: June 16, 2009
    Assignee: Polimeri Europa S.p.A.
    Inventors: Luigi Balducci, Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni
  • Publication number: 20080132735
    Abstract: A process is described for the preparation of phenol by the hydrodeoxygenation of polyhydroxylated benzene derivatives or by the selective hydroxylation of benzene under depletive conditions, characterized in that the above-mentioned reactions are carried out in the presence of a catalyst based on multi component metal oxides comprising at least one metal selected from the groups VB, VIB, VIII, IB, IIB, IVA, VA.
    Type: Application
    Filed: January 10, 2006
    Publication date: June 5, 2008
    Applicant: POLIMERI EUROPA S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Fausto Genoni, Guido Spano, Franco Rivetti
  • Publication number: 20070267324
    Abstract: The invention relates to a process for the production of linear alkanes, containing less than 6? carbon atoms, from a mix comprising one or more hydrocarbons containing at least 6 carbon atoms. The process uses a catalytic composition comprising particular combinations of a Y-type zeolite, at least one element selected from Zn, Mo, Cu, Ga, In, W, Ta, Zr, Ti, metals of Group VIII and optionally one or more lanthanides.
    Type: Application
    Filed: February 4, 2005
    Publication date: November 22, 2007
    Applicant: Polimeri Europa S. p. A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti
  • Publication number: 20070173644
    Abstract: The present invention relates to a process for the preparation of zeolitic catalysts of the MFI type in spheroidal form. The process consists in emulsifying and consolidating in paraffinic hydrocarbons, in the presence of a non-ionic surface-active agent or a suitable combination of a non-ionic surface-active agent and a cationic surface-active agent, a dispersion of particles of zeolitic material of the MFI type in a silica sol.
    Type: Application
    Filed: March 29, 2007
    Publication date: July 26, 2007
    Applicant: POLIMERI EUROPA S.p.A.
    Inventors: Luigi Balducci, Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni
  • Patent number: 7214637
    Abstract: The present invention relates to a process for the preparation of zeolitic catalysts of the MFI type in spheroidal form. The process consists in emulsifying and consolidating in paraffinic hydrocarbons, in the presence of a non-ionic surface-active agent or a suitable combination of a non-ionic surface-active agent and a cationic surface-active agent, a dispersion of particles of zeolitic material of the MFI type in a silica sol.
    Type: Grant
    Filed: September 21, 2004
    Date of Patent: May 8, 2007
    Assignee: Polimeri Europa S.p.A.
    Inventors: Luigi Balducci, Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni
  • Patent number: 7157397
    Abstract: A process is described for the synthesis of mesitylene, characterized in that mesitylene is obtained starting exclusively from pseudocumene, without the use of any other chemical compound, operating in continuous, at a temperature ranging from 225 to 400° C., at a pressure ranging from 1 to 50 bar, at a weight space velocity ranging from 0.1 to 10 hours?1, and in the presence of a catalyst containing a zeolite selected from ZSM-5 zeolite having a crystal lattice based on silicon oxide and aluminum oxide, and ZSM-5 zeolite modified by the partial or total substitution of Si with a tetravalent element such as Ti or Ge and/or the partial or total substitution of Al with other trivalent elements, such as Fe, Ga or B.
    Type: Grant
    Filed: February 26, 2004
    Date of Patent: January 2, 2007
    Assignees: Polimeri Europa S.p.A., Enitecnologie S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Robert{dot over (o)} Buzzoni, Franco Rivetti, Giovanni Antonio Fois, Caterina Rizzo, Virginio Arrigoni
  • Patent number: 7038093
    Abstract: The invention relates to a process for the preparation of phenol comprising the following phases: 1) preparation in continuous of phenol by means of the direct oxidation of benzene with hydrogen peroxide operating with an H2O2/benzene ratio ranging from 10 to 70%, in a three-phase reaction system comprising a first liquid phase consisting of benzene and an organic solvent, a second liquid phase consisting of water, a solid phase consisting of an activated catalyst based on titanium silicalite TS-1; 2) separation of the phenol and non-reacted benzene from the reaction mixture of the oxidation section (1), by means of fractionated distillation; 3) separation of the solvent and by-products from the mixture coming from the distillation tail (2), by means of basic extraction; 4) transformation of the by-products obtain in section (3) to phenol by means of hydrodeoxygenation with hydrogen operating in continuous, in aqueous solution, at a temperature ranging from 250 to 500° C.
    Type: Grant
    Filed: November 20, 2003
    Date of Patent: May 2, 2006
    Assignee: Polimeri Europa S.p.A.
    Inventors: Daniele Bianchi, Rossella Bortolo, Roberto Buzzoni, Alberto Cesana, Leonardo Dalloro, Rino D'Aloisio
  • Patent number: 6949687
    Abstract: A process is described for the contemporaneous preparation of mesitylene and durene, characterized in that mesitylene and durene are obtained exclusively starting from pseudo-cumene without the use of any further chemical compound, operating in continuous, at a temperature ranging from 210 to 400° C., at a pressure ranging from 1 to 50 bar, with a weight space velocity ranging from 0.1 to 20 hours?1 and in the presence of a catalyst based on crystalline metal-silicates in acid form. After the recovery of mesitylene and durene from the reaction raw product, some of the remaining components of the raw product itself are recycled and fed to the reactor together with the pseudo-cumene.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: September 27, 2005
    Assignees: Polimeri Europa S.p.A., Enitecnologie S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti, Caterina Rizzo, Virginio Arrigoni, Carlo Perego
  • Patent number: 6936738
    Abstract: A process is described for the preparation of phenol characterized in that the phenol is obtained by means of the hydrodeoxygenation of benzene-diols with hydrogen, operating in continuous, in an aqueous solution, at temperatures ranging from 250 to 500° C., at pressures of 1-100 bar and in the presence of a catalyst based on elements of group VIB or group VIII of the periodic table.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: August 30, 2005
    Assignees: ENI S.p.A., Polimeri Europa S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti
  • Publication number: 20050032630
    Abstract: The present invention relates to a process for the preparation of zeolitic catalysts of the MFI type in spheroidal form. The process consists in emulsifying and consolidating in paraffinic hydrocarbons, in the presence of a non-ionic surface-active agent or a suitable combination of a non-ionic surface-active agent and a cationic surface-active agent, a dispersion of particles of zeolitic material of the MFI type in a silica sol.
    Type: Application
    Filed: September 21, 2004
    Publication date: February 10, 2005
    Applicant: POLIMERI EUROPA S.p.A.
    Inventors: Luigi Balducci, Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni
  • Patent number: 6838406
    Abstract: The present invention relates to a process for the preparation of zeolitic catalysts of the MFI type in spheroidal form. The process consists in emulsifying and consolidating in paraffinic hydrocarbons, in the presence of a non-ionic surface-active agent or a suitable combination of a non-ionic surface-active agent and a cationic surface-active agent, a dispersion of particles of zeolitic material of the MFI type in a silica sol.
    Type: Grant
    Filed: November 18, 2002
    Date of Patent: January 4, 2005
    Assignee: Polimeri Europa S.p.A.
    Inventors: Luigi Balducci, Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni
  • Publication number: 20040225170
    Abstract: A process is described for the synthesis of mesitylene, characterized in that mesitylene is obtained starting exclusively from pseudocumene, without the use of any other chemical compound, operating in continuous, at a temperature ranging from 225 to 400° C., at a pressure ranging from 1 to 50 bar, at a weight space velocity ranging from 0.1 to 10 hours−1, and in the presence of a catalyst containing a zeolite selected from ZSM-5 zeolite having a crystal lattice based on silicon oxide and aluminum oxide, and ZSM-5 zeolite modified by the partial or total substitution of Si with a tetravalent element such as Ti or Ge and/or the partial or total substitution of Al with other trivalent elements, such as Fe, Ga or B.
    Type: Application
    Filed: February 26, 2004
    Publication date: November 11, 2004
    Applicants: POLIMERI EUROPA S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti, Giovanni Antonio Fois, Caterina Rizzo, Virginio Arrigoni
  • Publication number: 20040127762
    Abstract: A process is described for the contemporaneous preparation of mesitylene and durene, characterized in that mesitylene and durene are obtained exclusively starting from pseudo-cumene without the use of any further chemical compound, operating in continuous, at a temperature ranging from 210 to 400° C., at a pressure ranging from 1 to 50 bar, with a weight space velocity ranging from 0.1 to 20 hours−1 and in the presence of a catalyst based on crystalline metal-silicates in acid form. After the recovery of mesitylene and durene from the reaction raw product, some of the remaining components of the raw product itself are recycled and fed to the reactor together with the pseudo-cumene.
    Type: Application
    Filed: December 17, 2003
    Publication date: July 1, 2004
    Applicants: POLIMERI EUROPA S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti, Caterina Rizzo, Virginio Arrigoni, Carlo Perego
  • Publication number: 20040122264
    Abstract: The invention relates to a process for the preparation of phenol comprising the following phases:
    Type: Application
    Filed: November 20, 2003
    Publication date: June 24, 2004
    Applicant: POLIMERI EUROPA S.p.A.
    Inventors: Daniele Bianchi, Rossella Bortolo, Roberto Buzzoni, Alberto Cesana, Leonardo Dalloro, Rino D'Aloisio
  • Patent number: 6734323
    Abstract: The present invention relates to a process for the preparation of zeolitic catalysts comprising zeolite and oligomeric silica, which can be used in industrial reactors. The process consists in directly mixing the suspension, resulting from the synthesis of the zeolite, with an oligomeric silica sol, obtained from the hydrolysis of a tetra-alkyl ortho silicate in the presence of tetra-alkylammonium hydroxide, and in subjecting the mixture to rapid drying, by feeding to a spray-dry.
    Type: Grant
    Filed: November 29, 2000
    Date of Patent: May 11, 2004
    Assignees: Enichem S.P.A., Enitecnologie S.P.A.
    Inventors: Giuseppe Botti, Angela Carati, Leonardo Dalloro
  • Publication number: 20040077906
    Abstract: A process is described for the preparation of phenol characterized in that the phenol is obtained by means of the hydrodeoxygenation of benzene-diols with hydrogen, operating in continuous, in an aqueous solution, at temperatures ranging from 250 to 500° C., at pressures of 1-100 bar and in the presence of a catalyst based on elements of group VIB or group VIII of the periodic table.
    Type: Application
    Filed: October 14, 2003
    Publication date: April 22, 2004
    Applicants: ENI S.p.A., POLIMERI EUROPA S.p.A.
    Inventors: Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni, Franco Rivetti
  • Patent number: 6645899
    Abstract: The present invention relates to a method for the removal of the templating agent from synthetic zeolites in general and in particular from silicalite, titanium silicalite and from composite materials containing zeolites and for their activation as catalysts. The method consists in treating the above materials with solvents in vapor phase and at a low temperature.
    Type: Grant
    Filed: November 15, 2000
    Date of Patent: November 11, 2003
    Assignee: Enichem S.p.A.
    Inventors: Stefano Palmery, Fausto Genoni, Guido Spano′, Leonardo Dalloro, Alberto Cesana, Roberto Buzzoni