Abstract: A process and apparatus for the manufacture of silicon blocks having a columnar structure comprising monocrystalline crystal zones having a crystallographic preferred orientation. In a casting process, each mold filled with molten silicon is transferred, before the silicon has solidified completely, to a separate crystallization station where the silicon can then crystallize completely. During this process, the exposed surface of the silicon is maintained in a molten state until the end of the solidification process has almost been reached. The process allows the various, necessary steps to be carried out simultaneously and yields high-quality solar cell base material.

Abstract: The invention relates to a process and apparatus for manufacturing silicon astings or moldings, having a columnar structure of single-crystal regions of crystal with a preferential crystallographic orientation, and which can be manufactured cheaply and in large numbers in a semi-continuous mode of production. Liquid silicon is cast in a casting station, under an inert gas and preferably under reduced pressure, preferably in graphite molds which are exposed to a temperature gradient of 200.degree. to 1,000.degree. C. After cooling, the silicon is withdrawn automatically via a transport chamber connected to the casting station into special cooling stations, while the casting station is reloaded with an empty mold for repeating the process. The silicon blocks which have preferably been produced by this procedure are use as basic material for inexpensive solar cells having efficiencies of more than 10%, after they have been sawn into individual small wafers and have been doped and lead-bonded.