Patents by Inventor Leroy J. Kloeppner
Leroy J. Kloeppner has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20250020966Abstract: A variable transmission device forms a surface area including a plurality of electro-optic elements and first and second electrodes electrically connecting with a power supply circuit. An electro-optic medium is disposed between the first and second electrodes. A plurality of third electrodes is disposed between the first and second electrodes. A control circuit is electrically connected to one of the at least one first electrode and the at least one second electrode and configured to supply control signals to the electro-optic elements.Type: ApplicationFiled: October 2, 2024Publication date: January 16, 2025Applicant: Gentex CorporationInventors: Robert R. Turnbull, David A. Blaker, Xiaoxu Niu, Leroy J. Kloeppner, Bradley R. Hamlin, Michael J. Burns
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Patent number: 12111556Abstract: An electro-optic device includes a first electrode electrically connecting with power supply circuitry. A second electrode is spaced from the first electrode and electrically connecting with the power supply circuitry. An electro-optic medium is disposed between the first electrode and the second electrode. At least one third electrode is disposed between the first electrode and the second electrode and electrically connecting with one of the first electrode and the second electrode via switching circuitry. The switching circuitry is operable to control an electrical current through the first electrode, the electro-optic medium, and the second electrode.Type: GrantFiled: April 6, 2023Date of Patent: October 8, 2024Assignee: GENTEX CORPORATIONInventors: Robert R. Turnbull, David A. Blaker, Xiaoxu Niu, Leroy J. Kloeppner, Bradley R. Hamlin, Michael J. Burns
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Patent number: 12054671Abstract: An electro-optic element having enhanced durability by the addition of an additive. The additive may enhance the durability of the electro-optic element by reducing or eliminating the effects of water on species with the electro-optic element, such as the electrolyte. Specifically, the additive may operate to reduce or eliminate the formation and/or accumulation of hydrogen fluoride within the electro-optic element by interaction of the electrolyte with water or alcohol molecules. In some embodiments, the additive may be an organosilicon species, such as (3-cyanopropyl) dimethylfluorosilane.Type: GrantFiled: December 1, 2021Date of Patent: August 6, 2024Assignee: GENTEX CORPORATIONInventors: William L. Tonar, Leroy J. Kloeppner
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Publication number: 20230324758Abstract: An electro-optic device includes a first electrode electrically connecting with power supply circuitry. A second electrode is spaced from the first electrode and electrically connecting with the power supply circuitry. An electro-optic medium is disposed between the first electrode and the second electrode. At least one third electrode is disposed between the first electrode and the second electrode and electrically connecting with one of the first electrode and the second electrode via switching circuitry. The switching circuitry is operable to control an electrical current through the first electrode, the electro-optic medium, and the second electrode.Type: ApplicationFiled: April 6, 2023Publication date: October 12, 2023Applicant: Gentex CorporationInventors: Robert R. Turnbull, David A. Blaker, Xiaoxu Niu, Leroy J. Kloeppner, Bradley R. Hamlin, Michael J. Burns
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Publication number: 20230305352Abstract: An electro-optic device includes a first electro-optic element and a second electro-optic element in series with the first electro-optic element via a common node conductively connecting the first electro-optic element to the second electro-optic element. A power supply circuitry includes a first node and a second node. The first node connects the power supply circuitry to the first electro-optic element, and the second node connects the power supply circuitry to the second electro-optic element.Type: ApplicationFiled: March 22, 2023Publication date: September 28, 2023Applicant: Gentex CorporationInventors: Mario F. Saenger Nayver, Ryan B. Balili, Patrick Kreun, Robert R. Turnbull, Donald L. Bareman, Winston D. Carston, Stephen F. Richlich, Leroy J. Kloeppner
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Publication number: 20230266631Abstract: An electro-optic assembly includes a first substrate and a second substrate that is disposed in a substantially parallel spaced apart relationship with the first substrate. A first conductive layer is disposed on the first substrate, and a second conductive layer is disposed on the second substrate. A cathodic electro-optic film is in contact with the second conductive layer and includes a cathodic species. An anodic electro-optic film is in contact with the first conductive layer. The anodic electro-optic film includes a plurality of anodic species mixed at a molar ratio that is configured to generally maintain an a* value and a b* value of the electro-optic assembly both staying between ?8 and 8 between a high-end transmission state and a fully darkened state caused by an applied voltage range. An electrolyte medium is disposed between the cathodic and anodic electro-optic films.Type: ApplicationFiled: February 17, 2023Publication date: August 24, 2023Applicant: GENTEX CORPORATIONInventors: Garret C. DeNolf, Caleb Knust, Leroy J. Kloeppner, Punam Giri
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Patent number: 11624962Abstract: An electro-optic element includes a first electroactive compartment including an electroactive film having a first electroactive component and a second electroactive compartment including an electroactive solution or gel having a second electroactive component. An ion selective material is disposed between the first and second electroactive compartments and is configured to inhibit diffusion of the second electroactive component in an activated state from the second electroactive compartment to the first electroactive compartment. At least one of the first and second electroactive components is electrochromic such that the electro-optic element is configured to reversibly attenuate transmittance of light having a wavelength within a predetermined wavelength range when an electrical potential is applied to the electro-optic element.Type: GrantFiled: September 29, 2020Date of Patent: April 11, 2023Assignee: GENTEX CORPORATIONInventor: Leroy J. Kloeppner
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Publication number: 20230068233Abstract: An electro-optic device may comprise a first substrate having a first surface and a second surface; a second substrate having a third surface and a fourth surface, the second substrate disposed in a spaced-apart relationship relative to the first substrate such that the second and third surfaces are generally parallel to and face one another; a first electrode associated with the second surface; a second electrode associated with the third surface; a styrene-ethylene-butylene-styrene (SEBS) anionic exchange membrane disposed between the first and second electrodes; a first compartment defined by the SEBS anionic exchange membrane and the first substrate; a second compartment defined by the SEBS anionic exchange membrane and the second substrate; a cathodic species disposed in the first compartment; and an anodic species disposed in the second compartment.Type: ApplicationFiled: August 26, 2022Publication date: March 2, 2023Applicant: GENTEX CORPORATIONInventors: Leroy J. Kloeppner, Joshua P. McClure, Wenhan He
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Patent number: 11414594Abstract: A low dimerizing electrochromic compound for use in electrochromic mediums and electro-optic elements incorporating said electrochromic mediums is provided. The low dimerizing electrochromic compound is represented by Formula (I): wherein each R1 is individually an alkyl, a hydroxyalkyl, or an alkyl substituted with at least one polymerizable functional group; each R2 is a hydrogen; each R3 is individually a hydrogen or an alkyl; and each R4 is individually a hydrogen, an alkyl, or a hydroxyalkyl; and X? is an anion.Type: GrantFiled: April 7, 2020Date of Patent: August 16, 2022Assignee: GENTEX CORPORATIONInventors: Leroy J. Kloeppner, Zachary B. Erno, Henry A. Luten
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Publication number: 20220171245Abstract: An electro-optic element having enhanced durability by the addition of an additive. The additive may enhance the durability of the electro-optic element by reducing or eliminating the effects of water on species with the electro-optic element, such as the electrolyte. Specifically, the additive may operate to reduce or eliminate the formation and/or accumulation of hydrogen fluoride within the electro-optic element by interaction of the electrolyte with water or alcohol molecules. In some embodiments, the additive may be an organosilicon species, such as (3-cyanopropyl) dimethylfluorosilane.Type: ApplicationFiled: December 1, 2021Publication date: June 2, 2022Applicant: GENTEX CORPORATIONInventors: William L. Tonar, Leroy J. Kloeppner
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Patent number: 11231632Abstract: An electrochromic medium for use in an electro-optic device comprises a solvent comprising at least one low-volatile organic electrolyte solvent based on a cyclic carbonate ester; an anodic electroactive material; and a cathodic electroactive material; and at least one of the anodic and cathodic electroactive materials is electrochromic.Type: GrantFiled: December 13, 2018Date of Patent: January 25, 2022Assignee: GENTEX CORPORATIONInventors: Leroy J. Kloeppner, Zachary B. Erno, Steven D. Looman, Michael T. Stephenson, Michelle M. Carroll
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Patent number: 11092867Abstract: An optical assembly is provided that includes an electro-optic element that is configured to transition between a substantially clear state and a substantially darkened state. The electro-optic element can include an electrochromic polymer or network film that is substantially aligned with light having a predetermined polarization such that the electro-optic element is variably transmissive to the polarized light.Type: GrantFiled: December 28, 2018Date of Patent: August 17, 2021Assignee: GENTEX CORPORATIONInventors: Leroy J. Kloeppner, Henry A. Luten, William L. Tonar, Zachary B. Erno
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Patent number: 11067867Abstract: The electrochromic device includes a first substantially transparent substrate coupled to a first transparent electrode, a second substrate coupled to a second electrode, and an electrochromic medium. The electrochromic medium includes at least one solvent and/or an electrolyte gel, at least one cathodic material, and at least one anodic material. The cathodic material can be a cathodic organic framework electroactive material and/or the anodic material can be an anodic organic framework electroactive material. At least one of the anodic and cathodic organic framework electroactive materials is electrochromic.Type: GrantFiled: May 4, 2018Date of Patent: July 20, 2021Assignee: GENTEX CORPORATIONInventors: Zachary B. Erno, Sue F. Franz, Leroy J. Kloeppner, Steven D. Looman
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Patent number: 11048138Abstract: An electrochromic device and an electrode assembly for forming an electrochromic device includes a substrate, a conductive layer disposed over the substrate, and a resistive layer disposed over the conductive layer. The resistive layer includes conductive particles disposed in a polymer binder. The conductive particles include at least one doped metal oxide.Type: GrantFiled: February 21, 2019Date of Patent: June 29, 2021Assignee: GENTEX CORPORATIONInventors: Zachary J. Petroelje, William L. Tonar, Leroy J. Kloeppner
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Publication number: 20210103194Abstract: An electro-optic element includes a first electroactive compartment including an electroactive film having a first electroactive component and a second electroactive compartment including an electroactive solution or gel having a second electroactive component. An ion selective material is disposed between the first and second electroactive compartments and is configured to inhibit diffusion of the second electroactive component in an activated state from the second electroactive compartment to the first electroactive compartment. At least one of the first and second electroactive components is electrochromic such that the electro-optic element is configured to reversibly attenuate transmittance of light having a wavelength within a predetermined wavelength range when an electrical potential is applied to the electro-optic element.Type: ApplicationFiled: September 29, 2020Publication date: April 8, 2021Inventor: Leroy J. Kloeppner
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Patent number: 10971718Abstract: An energy storage device includes a cathodic material in an activated state; and an anodic material in an activated state; wherein: the cathodic material is covalently attached to, or confined within, a first polymer matrix, the first polymer matrix is configured to prevent or minimize substantial diffusion of the cathodic material in the activated state; and the anodic material is a phenazine, a phenothiazine, a triphenodithiazine, a carbazole, a indolocarbazole, a biscarbazole, or a ferrocene covalently attached to, or confined within, a second polymer matrix, the second polymer matrix is configured to prevent or minimize substantial diffusion of the anodic material in the activated state.Type: GrantFiled: October 7, 2019Date of Patent: April 6, 2021Assignee: GENTEX CORPORATIONInventors: David A Theiste, Leroy J. Kloeppner, Sue F. Franz, Punam Giri, Rongguang Lin
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Publication number: 20200393731Abstract: An electrochromic device includes a first substrate having a first conductive surface, a second substrate having a second conductive surface, and a sealing member joining the first conductive surface of the first substrate to the second conductive surface of the second substrate. The electrochromic device also includes a first busbar spaced apart from a second busbar and both in electrical communication with the first conductive surface of the first substrate, and a third busbar spaced apart from a fourth busbar and both in electrical communication with the second conductive surface of the second substrate. The first substrate, the second substrate, and the sealing member define a chamber. The first busbar is electrically connected with the third busbar to define a first zone. The second busbar is electrically connected with the fourth busbar to define a second zone.Type: ApplicationFiled: June 11, 2020Publication date: December 17, 2020Applicant: GENTEX CORPORATIONInventors: Kevin L. Ash, Leroy J. Kloeppner, Michelle M. Carroll, Michael T. Stephenson
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Publication number: 20200326602Abstract: A low dimerizing electrochromic compound for use in electrochromic mediums and electro-optic elements incorporating said electrochromic mediums is provided. The low dimerizing electrochromic compound is represented by Formula (I): wherein each R1 is individually an alkyl, a hydroxyalkyl, or an alkyl substituted with at least one polymerizable functional group; each R2 is a hydrogen; each R3 is individually a hydrogen or an alkyl; and each R4 is individually a hydrogen, an alkyl, or a hydroxyalkyl; and X? is an anion.Type: ApplicationFiled: April 7, 2020Publication date: October 15, 2020Inventors: Leroy J. Kloeppner, Zachary B. Erno, Henry A. Luten
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Patent number: 10774191Abstract: An electrochromic device includes a cathodic compartment including a cathodic material; an anodic compartment including an anodic material; and a transparent, ion-selective membrane displaced between the cathodic compartment and the anodic compartment wherein the transparent, ion-selective membrane is a cationic polymer.Type: GrantFiled: August 8, 2018Date of Patent: September 15, 2020Assignee: GENTEX CORPORATIONInventors: Zachary B. Erno, Leroy J. Kloeppner, Sue F. Franz, Joel C. Nemes, Garret C. Denolf, Nathan P. Boogaart
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Publication number: 20200192173Abstract: An electrochromic medium for use in an electro-optic device comprises a solvent comprising at least one low-volatile organic electrolyte solvent based on a cyclic carbonate ester; an anodic electroactive material; and a cathodic electroactive material; and at least one of the anodic and cathodic electroactive materials is electrochromic.Type: ApplicationFiled: December 13, 2018Publication date: June 18, 2020Applicant: GENTEX CORPORATIONInventors: Leroy J. Kloeppner, Zachary B. Erno, Steven D. Looman, Michael T. Stephenson, Michelle M. Carroll