Abstract: A novel, inexpensive sensor and method for detecting volatile compounds in the gas phase at concentrations of less than about 500 ppm in ambient air are provided. The sensor comprises (a) a dielectric substrate having a major surface; (b) a pair of electrically conductive electrodes disposed on the major surface of the substrate; and (c) a conductive polymer covering the pair of electrically conductive electrodes, with the conductive polymer doped with appropriate dopants in measurable excess of that stoichiometrically required to change the conductive polymer from a neutral state to a charged state to provide requisite conductivity. A method for making the sensor is provided, as is a method of use of the sensor which relates to its use in a monitoring system comprising a means for measuring the conductivity of the sensor connected to a warning means for providing an indication when the conductivity reaches a predetermined level.

Abstract: Apparatus for positioning a golf ball on a tee and for retrieving golf balls and tees. A hand-operated apparatus for setting golf balls on tees without requiring the golfer to bend is described. The device may also be used for retrieving golf balls and tees, and may itself be retrieved if dropped by using the handle of a golf club. The apparatus comprises a hollow outer shaft having a fixed handle at one end and a base for pivotably holding two golf ball encircling jaws at the other. An inner shaft, slidably disposed within the outer shaft and connected to a movable handle at one end, and jaw-actuating wires at the other permits a user to operate the jaws with one hand. A coil spring located between the fixed and movable handles provides a force therebetween, keeping the jaws closed in their normal position.

Abstract: A substrate (20) is treated prior to use to induce a near-perpendicular orientation of a liquid crystal director (26) relative to the substrate. A layer of silica (98) is deposited upon the substrate (20) by in-line magnetron sputtering as the substrate ( 20) is moved past the sputtering target (78), and the silica-coated substrate (20) is thereafter treated with a long-chain alcohol. The alcohol-treated substrate (20) is covered with a layer of liquid crystal (22), the director (26) of the liquid crystal (22) assuming a field-off state tilted about 1-3 degrees from the perpendicular toward an azimuthal direction (30) parallel to the direction of movement of the substrate (20) during deposition.

Abstract: A novel, inexpensive sensor (10) for detecting volatile hydrocarbons and other solvent vapors detects leaks in the fittings and valves of petroleum refineries and chemical manufacturing and processing plants. The sensor comprises (a) a dielectric substrate (12) having a major surface; (b) a pair of interdigitated, electrically conductive electrodes (14a, 14b) disposed on the major surface of the substrate; and (c) a composite coating (16) covering the interdigitated electrodes and comprising (1) a conductive polymer, and (2) a dielectric polymer with an affinity for the solvent vapors to be detected.

Abstract: A method is provided for preparing the surface of a cured cyanate ester resin or composite for metal plating. The composite may comprise graphite fibers embedded in a cured cyanate ester resin matrix The surface is treated with a preheated solution containing an alkali metal salt of an alkoxide. Preferred alkoxides are methoxide, ethoxide, propoxide, isopropoxide, butoxide, tert-butoxide, sec-tutoxide, 2- methyl-2-butoxide, pentoxide and hexoxide. The method of the invention operates to improve adhesion between the treated surface and a subsequently plated metal, such that the resulting cured cyanate ester resin or composite may replace certain metallic components in such applications as aircraft, spacecraft, and automobiles given its highly conductive metallic coating.

Abstract: Contaminant levels in a fluid such as air or water are reduced by producing a pulsed electron beam having an average primary electron energy of from about 90 to about 110 thousand electron volts (corresponding to an average injected electron energy of from about 45 to about 55 thousand electron volts in a preferred case) and directing the electron beam through the fluid. The contaminant compounds may include organic compounds and certain inorganic compounds such as NO.sub.x and SO.sub.x. The fluid is preferably contained in a contaminant reduction cell that is separated from an electron beam source by an electron-transparent window.

Abstract: A substrate is treated prior to use to induce a near-parallel orientation of a liquid crystal director relative to the substrate. A layer of silica is deposited on the substrate by in-line magnetron sputtering as the substrate is moved past the sputtering target, and the silica-coated substrate is thereafter treated with an alcohol that is selected from one of two classes of alcohols: (1) alcohols having an aromatic ring structure on one end of an aliphatic chain and a hydroxy group on the other end, with or without at least one ether group in the chain, and (2) an aliphatic chain having a hydroxy group at one end and at least one ether linkage in the chain. An example is 2-phenylethanol. The alcohol-treated substrate is covered with a layer of the liquid crystal. The process of the invention induces a tilt to the director of the liquid crystal. The tilt is about 0.5.degree. to 4.degree., as measured parallel to the surface of the substrate.

Abstract: A substrate is treated prior to use to induce a near-parallel orientation of a liquid crystal director relative to the substrate. A layer of silica is deposited on the substrate by in-line magnetron sputtering as the substrate is moved past the sputtering target, and the silica-coated substrate is thereafter treated with an alcohol that is selected from one of two classes of alcohols: (1) alcohols having an aromatic ring structure on one end of an aliphatic chain and a hydroxy group on the other end, with or without at least one ether group in the chain, and (2) an aliphatic chain having a hydroxy group at one end and at least one ether linkage in the chain. An example is 2-phenylethanol. The alcohol-treated substrate is covered with a layer of the liquid crystal. The process of the invention induces a tilt to the director of the liquid crystal. The tilt is about 0.5.degree. to 4.degree., as measured parallel to the surface of the substrate.

Abstract: A novel, inexpensive sensor (10) for detecting volatile hydrocarbons and other solvent vapors detects leaks in the fittings and valves of petroleum refineries and chemical manufacturing and processing plants. The sensor comprises (a) a dielectric substrate (12) having a major surface; (b) a pair of interdigitated, electrically conductive electrodes (14a, 14b) disposed on the major surface of the substrate; and (c) a composite coating (16) covering the interdigitated electrodes and comprising (1) a conductive polymer, and (2) a dielectric polymer with an affinity for the solvent vapors to be detected.

Abstract: A photopolymerizable composition includes a water-insoluble olefinic compound that is polymerizable with free-radical initiators, an oil-soluble phenothiazine dye that is soluble in water-immiscible organic solvents, and a reducing agent operable to react with the dye to form reactive free radicals only when the dye is in an excited state induced by exposure to light. The reducing agent and the dye are reacted together under the influence of light, and particularly red light. The resulting reactive free radicals cause the olefinic compound to polymerize to a polymer that is substantially unaffected by the presence of moisture.

Abstract: A grating (22) of narrow parallel ridges (24) is formed in the surface (26) of a substrate (20) made of a hard material such as silicon dioxide. Metal (40) is deposited onto the grating (22) perpendicular to the ridges (24) at an angle of approximately 45.degree. to the surface (26) of the grating such that the metal (40) is deposited onto the top (24a) and one of the sides (24b) of the each of the ridges (24) to form generally L-shaped metal strips (12') thereon. The metal strips (12') are cut at periodic intervals along the ridges (24) to produce anisometric metal needles (12). The substrate (20) is immersed in a dielectric fluid (14), and ultrasonic energy is applied to cause the needles (12) to release from the substrate (20) into suspension in the fluid (14). The L-shape of the needles (12) makes them resistant to bending. The suspension (10) has birefringent properties similar to liquid crystals, but may be electrically switched at much higher speed.

Abstract: A substrate (20) is treated prior to use to induce a near-perpendicular orientation of a liquid crystal director (26) relative to the substrate. A layer of silica (38) is deposited upon the substrate (20) by in-line magnetron sputtering as the substrate (20) is moved past the sputtering target (78), and the silica-coated substrate (20) is thereafter treated with a long-chain alcohol. The alcohol-treated substrate (20) is covered with a layer of liquid crystal (22), the director (26) of the liquid crystal (22) assuming a field-off state tilted about 1-3 degrees from the perpendicular toward an azimuthal direction (30) parallel to the direction of movement of the substrate (20) during deposition.

Abstract: A sensor for monitoring the water content and the acid content in the presence of water in nonaqueous media can be incorporated into a monitoring system for monitoring the quality of nonaqueous fluids in equipment or vehicles. The sensor comprises an insulating substrate; electrodes formed on the substrate in an interdigitated pattern; and a conductive polymer deposited over the interdigitated electrodes which bridges between adjacent digits of the electrodes. The monitoring system incorporating the sensor comprises a control module for measuring the conductivity of the sensor. The control module is preprogrammed to compare the measured conductivity to a predetermined level indicative of an unacceptable level of degradation. The sensor is made by depositing electrodes on an insulating substrate; depositing a conductive polymer over the electrodes in an amount sufficient to bridge between the electrodes; and neutralizing the conductive polymer to an insulating form.

Abstract: A grating (22) of narrow parallel ridges (24) is formed in the surface (26) of a substrate (20) made of a hard material such as silicon dioxide. Metal (40) is deposited onto the grating (22) perpendicular to the ridges (24) at an angle of approximately 45.degree. to the surface (26) of the grating such that the metal (40) is deposited onto the top (24a) and one of the sides (24b) of the each of the ridges (24) to form generally L-shaped metal strips (12') thereon. The metal strips (12') are cut at periodic intervals along the ridges (24) to produce anisometric metal needles (12). The substrate (20) is immersed in a dielectric fluid (14), and ultrasonic energy is applied to cause the needles (12) to release from the substrate (20) into suspension in the fluid (14). The L-shape of the needles (12) makes them resistant to bending. The suspension ( 10) has birefringent properties similar to liquid crystals, but may be electrically switched at much higher speed.

Abstract: A liquid crystal is used as the phase modulating medium in a microwave phase modulating cell (20). Applied electric and/or magnetic fields transverse to the direction of wave propagation create a birefringence that changes the velocity of wave propagation and the index of refraction of the medium. The phase modulating cell (20) is used singly or in arrays to direct microwave beams.

Abstract: A composite material (20) has electrically conducting, elongated particles (22) dispersed in a liquid crystal (24). The index of refraction to microwaves is controllable by the application of a transverse electric field that aligns the liquid crystal material (24) and the particles (22). A phase modulating cell (31) is formed by placing the composite material (20) inside a microwave wave guide (32), with transverse electrodes (36) built into the sides of the wave guide (32). Another set of transverse electrodes or magnet pole pieces (30) can be provided to align the liquid crystal material (24) and the particles (22) in another direction, thereby switching the index of refraction of the cell (31). The particles (22) may be made of a ferromagnetic material, to permit magentic as well as electrical switching.

Abstract: A grating (22) of narrow parallel ridges (24) is formed in the surface (26) of a substrate (20) made of a hard material such as silicon dioxide. Metal (40) is deposited onto the grating (22) perpendicular to the ridges (24) at an angle of approximately 45.degree. to the surface (26) of the grating such that the metal (40) is deposited onto the top (24a) and one of the sides (24b) of the each of the ridges (24) to form generally L-shaped metal strips (12') thereon. The metal strips (12') are cut at periodic intervals along the ridges (24) to produce anisometric metal needles (12). The substrate (20) is immersed in a dielectric fluid (14), and ultrasonic energy is applied to cause the needles (12) to release from the substrate (20) into suspension in the fluid (14). The L-shape of the needles (12) makes them resistant to bending. The suspension ( 10) has birefringent properties similar to liquid crystals, but may be electrically switched at much higher speed.

Abstract: Liquid crystals are induced to assume a uniform tilted alignment in the absence of an applied field by treating the surface of a substrate to provide a desired tilted surface microstructure and free hydroxyl groups. A long chain alcohol having the formula ROH, where R is a carbon chain having at least about 6 carbon atoms therein, is chemically reacted with the tilted surface microstructure and the alkoxy groups derived therefrom are chemically bonded to the microstructure. Subsequently introduced liquid crystals assume a tilted-perpendicular alignment at a tilt angle of about 0.5.degree. to about 6.degree.. The liquid crystals exhibit a significantly greater photostability than has previously been achieved. The microstructure is preferably obtained by depositing sequential layers of SiO.sub.x at medium and shallow grazing angles, where x is from 1 to 2, with the substrate rotated 90.degree. between depositions.

Abstract: A composite material includes droplets of a liquid crystal material dispersed within a matrix of a photopolymerized polymer. The material is prepared by forming a solution of the liquid crystal material and a monomer, and then polymerizing the monomer with light. The solubility of the liquid crystal material in the polymer is less than in the monomer. As polymerization progresses, a portion of the liquid crystal material separates as a second phase in the polymer matrix. The liquid crystal can be any suitable such material that is soluble in the monomer and less so in the polymer, and the monomer is a polymerizable acrylate or methacrylate. Liquid crystal devices are prepared by forming the composite material between two electrically conducting substrates.

Abstract: A composite material having droplets of a liquid crystal material in a matrix of a coploymer of a multifunctional acrylate, or a mixture of different multifunctional acrylates, and a multifunctional mercaptan is prepared by photopolymerization. The liquid crystal material is initially mixed with a multifunctional acrylate monomer, a multifunctional mercaptan, and a photoinitiator to form a solution. The solution is exposed to ultraviolet light, whereupon the multifunctional acrylate monomer and multifunctional mercaptan copolymerize in a step reaction, and the liquid crystal separates from the copolymer as droplets dispersed throughout the copolymer matrix. The resulting material is placed between transparent, electrically conducting plates to form an electro-optic display device.