Abstract: The present invention provides a reactor and gasification process for the continuous controlled production of hydrogen (H2) and a by-product synthesis gas (mixture of CO+H2+CO2), such a process called a hydrogen priority poly-generation process (HPPP). The reactor uses a circulating molten iron process, which is capable of gasifying a variety of carbonaceous materials including low rank coals and biomass. The process employs an iron steam oxidation-reduction cycle in a multi-chamber reactor including a multi-vessel reactor system, where in one compartment or vessel hydrogen is produced by steam oxidation of molten iron; and in a second compartment or vessel the iron is regenerated by carbon reduction of molten iron oxide thereby producing a by-product synthesis gas (CO+H2+CO2), and excess heat which can be used to produce steam, and in a third step the iron is purified before being returned to the steam oxidation step in the process.

Abstract: The present invention provides a reactor and gasification process for the continuous controlled production of hydrogen (H2) and a by-product synthesis gas (mixture of CO+H2+CO2), such a process called a hydrogen priority poly-generation process (HPPP). The reactor uses a circulating molten iron process, which is capable of gasifying a variety of carbonaceous materials including low rank coals and biomass. The process employs an iron steam oxidation-reduction cycle in a multi-chamber reactor including a multi-vessel reactor system, where in one compartment or vessel hydrogen is produced by steam oxidation of molten iron; and in a second compartment or vessel the iron is regenerated by carbon reduction of molten iron oxide thereby producing a by-product synthesis gas (CO+H2+CO2), and excess heat which can be used to produce steam, and in a third step the iron is purified before being returned to the steam oxidation step in the process.