Patents by Inventor Li-Min Tau
Li-Min Tau has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20240150503Abstract: A propylene-ethylene copolymer includes propylene as a primary monomer, an ethylene content (ET) of 3.0% to 5% by weight, a melt flow rate of from 20 to 45 g/10 min, a xylene soluble fraction (XS) of from 2.0% to 7.0% by weight, and an XS/ET ratio of less than or equal to 1.51.Type: ApplicationFiled: December 5, 2023Publication date: May 9, 2024Applicant: W.R. GRACE & CO.-CONN.Inventors: Matthew Fedec, Jan Van Egmond, Manu Rego, John Kaarto, Li-Min Tau
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Patent number: 11873355Abstract: Propylene-ethylene copolymer compositions and production methods are provided. The copolymer compositions can be particularly advantageous for use in hot fill packaging of foodstuffs. The propylene-ethylene copolymers can be produced using a Ziegler-Natta catalyst and an alkoxysilane electron donor. The compositions can have propylene as a primary monomer with an ethylene content ranging from 2.0 to 6.0 percent by weight with a xylene soluble content of less than 7.0 percent by weight.Type: GrantFiled: June 7, 2019Date of Patent: January 16, 2024Assignee: W.R. Grace & Co.-Conn.Inventors: Matthew John Fedec, Jan Willem Van Egmond, Manu Rego, John Kalevi Kaarto, Li-Min Tau
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Patent number: 11254848Abstract: The present disclosure provides compositions, films and articles containing a random propylene/ethylene copolymer and a substituted phenylene aromatic diester. Polymerization with an improved catalyst system increases the amount of ethylene incorporated into the random propylene/ethylene copolymer backbone which results in improved thermal properties, improved optical properties, and improved heat seal properties.Type: GrantFiled: July 27, 2012Date of Patent: February 22, 2022Assignee: W.R. GRACE & CO.-CONN.Inventors: Li-Min Tau, Chai-Jing Chou, John Kaarto, Peter S. Martin, William G. Sheard
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Publication number: 20210253755Abstract: Propylene-ethylene copolymer compositions and production methods are provided. The copolymer compositions can be particularly advantageous for use in hot fill packaging of foodstuffs. The propylene-ethylene copolymers can be produced using a Ziegler-Natta catalyst and an alkoxysilane electron donor. The compositions can have propylene as a primary monomer with an ethylene content ranging from 2.0 to 6.0 percent by weight with a xylene soluble content of less than 7.0 percent by weight.Type: ApplicationFiled: June 7, 2019Publication date: August 19, 2021Inventors: Matthew John FEDEC, Jan Willem VAN EGMOND, Manu REGO, John Kalevi KAARTO, Li-Min TAU
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Patent number: 9683096Abstract: A polypropylene impact copolymer is disclosed. The propylene impact copolymer composition comprises from 60 to 90 percent by weight of the impact copolymer composition of a matrix phase, which can be a homopolymer polypropylene or random polypropylene copolymer having from 0.1 to 7 mol percent of units derived from ethylene or C4-C10 alpha olefins. The propylene impact copolymer composition also comprises from 10 to 40 percent by weight of the impact copolymer composition of a dispersed phase, which comprises a propylene/alpha-olefin copolymer having from 6 to 40 mol percent of units derived from ethylene or C4-C10 alpha olefins, wherein the dispersed phase has a comonomer content which is greater than the comonomer content in the matrix phase. The propylene impact copolymer composition is further characterized by having the ratio of the dispersed phase intrinsic viscosity (IV) to the matrix phase IV being 0.95 or less.Type: GrantFiled: August 19, 2010Date of Patent: June 20, 2017Assignee: Braskem America, Inc.Inventors: John Kaarto, Alechia Crown, Li-Min Tau, Gert J. Claasen
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Patent number: 9109106Abstract: The present invention relates to polymer compositions comprising a propylene impact copolymer and a processing aid, as well as corrugated boards made from such compositions. The impact copolymer has a melt flow range of from 1.5 to 3.5 g/10 min and a dispersed phase content of from 5 to 30% by weight. The dispersed phase of the impact copolymer has an ethylene content of from 30- to 70% by weight of the dispersed phase. The matrix phase of the impact copolymer is a propylene homopolymer or a random copolymer comprising units derived from propylene and a second copolymer selected from either ethylene or 1-butene wherein the units derived from the second copolymer comprise from 0 to 5% by weight of the dispersed phase.Type: GrantFiled: May 25, 2011Date of Patent: August 18, 2015Assignee: Braskem America, Inc.Inventors: Peter S. Dias, Li-Min Tau, John Kaarto
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Patent number: 9085682Abstract: The present invention relates to polymer compositions comprising a propylene impact copolymer and a processing aid, as well as corrugated boards made from such compositions. The impact copolymer has a melt flow range of from 1.5 to 3.5 g/10 min and a dispersed phase content of from 5 to 30% by weight. The dispersed phase of the impact copolymer has an ethylene content of from 30- to 70% by weight of the dispersed phase. The matrix phase of the impact copolymer is a propylene homopolymer or a random copolymer comprising units derived from propylene and a second copolymer selected from either ethylene or 1-butene wherein the units derived from the second copolymer comprise from 0 to 5% by weight of the dispersed phase.Type: GrantFiled: May 25, 2011Date of Patent: July 21, 2015Assignee: Braskem America, Inc.Inventors: Peter S. Dias, Li-Min Tau, John Kaarto
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Patent number: 8748539Abstract: Propylene impact copolymers (ICPs) are provided which comprise: (a) a matrix phase which comprises from 60 to 95 weight % of a polypropylene polymer containing from 0 to 6 mole % of units derived from one or more alpha-olefins other than propylene, and (b) a dispersed phase which comprises from 5 to 40 weight % of a copolymer derived from a first comonomer which can be either propylene or ethylene together with a second alpha-olefin comonomer. The ICP is further characterized by having a beta/alpha ratio less than or equal to 1.1. The ICPs of the present invention are particularly well suited for applications requiring clear, tough polymers such as thin walled injection molded articles for frozen food packaging applications.Type: GrantFiled: May 24, 2011Date of Patent: June 10, 2014Assignee: Braskem America, Inc.Inventors: Peter S. Martin, Peter S. Dias, Jason C. Brodil, Li-Min Tau, Debra R. Wilson, Jeffrey D. Goad, Matthew J. Fedec
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Publication number: 20140124405Abstract: The present disclosure provides compositions, films and articles containing a random propylene/ethylene copolymer and a substituted phenylene aromatic diester. Polymerization with an improved catalyst system increases the amount of ethylene incorporated into the random propylene/ethylene copolymer backbone which results in improved thermal properties, improved optical properties, and improved heat seal properties.Type: ApplicationFiled: July 27, 2012Publication date: May 8, 2014Applicant: Dow Global Technologies LLCInventors: Li-Min Tau, Chai-Jing Chou, John Kaarto, Peter S. Martin, William G. Sheard
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Publication number: 20130237111Abstract: Fabricated articles are disclosed which comprise a polypropylene impact copolymer. The propylene impact copolymer composition comprises from 60 to 90 percent by weight of the impact copolymer composition of a matrix phase, which can be a homopolymer polypropylene or random polypropylene copolymer having from 0.1 to 7 mol percent of units derived from ethylene or C4-C10 alpha olefins. The propylene impact copolymer composition also comprises from 10 to 40 percent by weight of the impact copolymer composition of a dispersed phase, which comprises a propylene/alpha-olefin copolymer having from 6 to 40 mol percent of units derived from ethylene or C4-C10 alpha olefins, wherein the dispersed phase has a comonomer content which is greater than the comonomer content in the matrix phase. The propylene impact copolymer composition is further characterized by having the ratio of the matrix MFR to the dispersed phase MFR being 1.2 or less.Type: ApplicationFiled: July 19, 2011Publication date: September 12, 2013Applicant: BRASKEM AMERICA, INC.Inventors: Alechia Crown, Gert Claasen, Jacquelyn Degroot, Thor Gudmundsson, Charles Crosby, Li-Min Tau, John Kaarto
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Publication number: 20120302701Abstract: Propylene impact copolymers (ICPs) are provided which comprise: (a) a matrix phase which comprises from 60 to 95 weight % of a polypropylene polymer containing from 0 to 6 mole % of units derived from one or more alpha-olefins other than propylene, and (b) a dispersed phase which comprises from 5 to 40 weight % of a copolymer derived from a first comonomer which can be either propylene or ethylene together with a second alpha-olefin comonomer. The ICP is further characterized by having a beta/alpha ratio less than or equal to 1.1. The ICPs of the present invention are particularly well suited for applications requiring clear, tough polymers such as thin walled injection molded articles for frozen food packaging applications.Type: ApplicationFiled: May 24, 2011Publication date: November 29, 2012Applicant: Dow Global Technologies LLCInventors: Peter S. Martin, Peter S. Dias, Jason C. Brodil, Li-Min Tau, Debra R. Wilson, Jeffrey D. Goad, Matthew J. Fedec
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Publication number: 20120301682Abstract: The present invention relates to polymer compositions comprising a propylene impact copolymer and a processing aid, as well as corrugated boards made from such compositions. The impact copolymer has a melt flow range of from 1.5 to 3.5 g/10 min and a dispersed phase content of from 5 to 30% by weight. The dispersed phase of the impact copolymer has an ethylene content of from 30-to 70% by weight of the dispersed phase. The matrix phase of the impact copolymer is a propylene homopolymer or a random copolymer comprising units derived from propylene and a second copolymer selected from either ethylene or 1-butene wherein the units derived from the second copolymer comprise from 0 to 5% by weight of the dispersed phase.Type: ApplicationFiled: May 25, 2011Publication date: November 29, 2012Applicant: Dow Global Technologies LLCInventors: Peter S. Dias, Li-Min Tau, John Kaarto
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Publication number: 20120046400Abstract: A polypropylene impact copolymer is disclosed. The propylene impact copolymer composition comprises from 60 to 90 percent by weight of the impact copolymer composition of a matrix phase, which can be a homopolymer polypropylene or random polypropylene copolymer having from 0.1 to 7 mol percent of units derived from ethylene or C4-C10 alpha olefins. The propylene impact copolymer composition also comprises from 10 to 40 percent by weight of the impact copolymer composition of a dispersed phase, which comprises a propylene/alpha-olefin copolymer having from 6 to 40 mol percent of units derived from ethylene or C4-C10 alpha olefins, wherein the dispersed phase has a comonomer content which is greater than the comonomer content in the matrix phase. The propylene impact copolymer composition is further characterized by having the ratio of the matrix MFR to the dispersed phase MFR being 1.2 or less.Type: ApplicationFiled: August 19, 2010Publication date: February 23, 2012Applicant: Dow Global Technologies Inc.Inventors: John Kaarto, Alechia Crown, Li-Min Tau, Gert J. Claasen
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Publication number: 20120045956Abstract: Fabricated articles are disclosed which comprise a polypropylene impact copolymer. The propylene impact copolymer composition comprises from 60 to 90 percent by weight of the impact copolymer composition of a matrix phase, which can be a homopolymer polypropylene or random polypropylene copolymer having from 0.1 to 7 mol percent of units derived from ethylene or C4-C10 alpha olefins. The propylene impact copolymer composition also comprises from 10 to 40 percent by weight of the impact copolymer composition of a dispersed phase, which comprises a propylene/alpha-olefin copolymer having from 6 to 40 mol percent of units derived from ethylene or C4-C10 alpha olefins, wherein the dispersed phase has a comonomer content which is greater than the comonomer content in the matrix phase. The propylene impact copolymer composition is further characterized by having the ratio of the matrix MFR to the dispersed phase MFR being 1.2 or less.Type: ApplicationFiled: August 19, 2010Publication date: February 23, 2012Applicant: Dow Global Technologies Inc.Inventors: Li-Min Tau, Gert J. Claasen, Charles R. Crosby, III, Alechia Crown, John Kaarto
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Patent number: 7981967Abstract: The invention is directed to a composition suitable for high gloss air quenched blown films. The films are comprised of from 2 to 15 percent by weight of a substantially isotactic propylene-based copolymer having a melt flow rate of at least 5 g/10 minutes and having from 8 to 21 mole percent units derived from an alpha olefin; and from 85 to 98 percent by weight of an ethylene-based copolymer having a melt index of from 0.1 to 9 g/10 minutes. An air quenched blown film made from the inventive composition exhibits a value for gloss greater than the value for gloss exhibited by an air quenched blown film made solely from the ethylene-based copolymer.Type: GrantFiled: April 13, 2006Date of Patent: July 19, 2011Assignee: Dow Global Technologies LLCInventors: Li-Min Tau, Shaun Parkinson, Jesus Nieto
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Publication number: 20110031645Abstract: The present invention relates to polypropylene compositions having a broad molecular weight distribution with a relatively high amount of xylene soluble material. The compositions have an Mw/Mn of five or greater, but preferably greater than 5.5 and more preferably greater than 6.0. The compositions have xylene solubles from 5.0 to 8.0 percent by weight, preferably from 5.5 to 8.0 percent by weight, and more preferably 6.0 to 7.5 percent by weight. The polymers of the present invention are particularly well suited for biaxially oriented polypropylene applications.Type: ApplicationFiled: August 7, 2009Publication date: February 10, 2011Applicant: Dow Global Technologies Inc.Inventors: Beth A. Kuettel, Drew A. Davidock, Li-Min Tau, Thomas R. Cuthbert
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Patent number: 7579407Abstract: A unique thermoplastic olefin composition having: (a) at least 40 percent by weight of a propylene-alpha olefin copolymer based on the total weight of polymers in the composition, the propylene-alpha olefin copolymer having at least 60 percent by weight units derived from propylene, at least 6 percent by weight units derived from an alpha olefin, a molecular weight distribution less than 3.5, and a broad composition distribution; and (b) at least 20 percent by weight of a polypropylene based on the total weight of polymers in the composition, the polypropylene having at least 93 percent by weight units derived from propylene, a molecular weight distribution of greater than 3.5, a heat of fusion greater than the heat of fusion exhibited by the propylene-alpha olefin copolymer, and a melting point Tmax of at least 120° C.Type: GrantFiled: May 3, 2003Date of Patent: August 25, 2009Assignee: Dow Global Technologies Inc.Inventors: Li-Min Tau, Yunwa Wilson Cheung, Charles F. Diehl, Lonnie G. Hazlitt
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Patent number: 7459500Abstract: A unique thermoplastic olefin composition having: (a) at least 40 percent by weight of a propylene-alpha olefin copolymer based on the total weight of polymers in the composition, the propylene-alpha olefin copolymer having at least 60 percent by weight units derived from propylene, at least 6 percent by weight units derived from an alpha olefin, a molecular weight distribution less than 3.5, and a broad composition distribution; and (b) at least 20 percent by weight of a polypropylene based on the total weight of polymers in the composition, the polypropylene having at least 93 percent by weight units derived from propylene, a molecular weight distribution of greater than 3.5, a heat of fusion greater than the heat of fusion exhibited by the propylene-alpha olefin copolymer, and a melting point Tmax of at least 120° C.Type: GrantFiled: May 5, 2003Date of Patent: December 2, 2008Assignee: Dow Global Technologies Inc.Inventors: Li-Min Tau, Yunwa Wilson Cheung, Charles F. Diehl, Lonnie G. Hazlitt
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Publication number: 20080207836Abstract: The invention is directed to a composition suitable for high gloss air quenched blown films. The films are comprised of from 2 to 15 percent by weight of a substantially isotactic propylene-based copolymer having a melt flow rate of at least 5 g/10 minutes and having from 8 to 21 mole percent units derived from an alpha olefin; and from 85 to 98 percent by weight of an ethylene-based copolymer having a melt index of from 0.1 to 9 g/10 minutes. An air quenched blown film made from the inventive composition exhibits a value for gloss greater than the value for gloss exhibited by an air quenched blown film made solely from the ethylene-based copolymer.Type: ApplicationFiled: April 13, 2006Publication date: August 28, 2008Inventors: Li-Min Tau, Shaun Parkinson, Jesus Nieto
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Patent number: 7041765Abstract: Films with excellent machine direction (MD) tear properties comprise at least one layer made from a polymer comprising: (A) at least 50 weight percent (wt%) propylene; and (B) at least 5 wt % ethylene and/or one or more unsaturated comonomers. Representative of component (B) unsatuarated comonomers are the C4-20 ?-olefins, C4-20 dienes, styrenic compounds, and the like. Preferably, the film has at least one of a (i) haze value of less than about 10, (ii) 45 degree gloss of greater than about 65, and (iii) dart value of greater than about 100 g/mil. In one preferred embodiment, the layer comprises a compolymer characterized as having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content, i.e.Type: GrantFiled: November 5, 2002Date of Patent: May 9, 2006Assignee: Dow Global Technologies Inc.Inventors: Li-Min Tau, Pak-Wing S. Chum, Seema Karande, Clive Bosnyak