Abstract: Novel electrolytic capacitors are based on a composite liquid crystal electrolyte sandwiched between two electrodes where the electrolyte comprises a dispersion of a lyotropic liquid crystal in a dispersion media, and where the liquid crystal is a chromonic liquid crystal and the dispersion media is selected from a variety of materials ranging from liquids to solid polymers. Further the electrolyte optimally including a surfactant or surfactant system selected so as to influence the charge characteristics of the capacitor. The capacitors provide relatively high capacitance in a relatively thin device; are insensitive to reversal of polarity of an applied bias voltage; and can be produced at selected charging and discharging frequencies which in turn influences the characteristics of release of stored power. The invention further relates to methods of making the capacitors which utilize low cost materials and low cost fabrication techniques.

Abstract: A liquid crystal polymer dispersion is formed where liquid crystal encapsulation is produced by a process in which a reactive additive formulation is mixed and photo-polymerized. The polymerizable additive formulation includes monofunctional, multifunctional and photoinitiator compounds in specific composition. The polymerizable additive formulation enhances the control of deformed globule or droplet size, structure integrity, electro-optical properties, and prohibits flow of the liquid crystal as it is encapsulated. A simple process and a controllable system for encapsulating cholesteric materials that provides rugged low-power flexible passively-driven displays. Such displays offer the possibility of lower cost roll-to-roll manufacturing in addition to lighter weight, more rugged and conformable displays.

Abstract: This invention relates to a method of fabrication of liquid crystal light modulating devises having electrically tunable spectral wavelength and more particularly, to a cholesteric liquid crystal display with electrically switchable colors. The cholesteric light modulators may be fabricated by applying a plurality of layers to maximize the light modulation. It also features a polymer composite or polymer-network stabilized cholesteric liquid crystal with electrically switchable Bragg reflected wavelength within a predetermined range of spectral wavelength.

Abstract: The present invention provides liquid crystal devices comprised of a composite of an internal polymer network localized on the substrate surfaces and short-pitch dual-frequency switchable cholesteric liquid crystal that operate in two different modes including in-plane switching (amplitude modulation) and out-of-plane switching (phase modulation). The invention further provides a method of making a liquid crystal device demonstrating uniform lying helical axis where the device comprises a composite of an internal spatially ordered polymer network localized by in-situ photo-polymerization at the surface of the substrate. The invention can be used for flat panel displays, as well as spatial light modulators for applications such as optical waveguides, optical beam scanners, computer-generated holograms, and adaptive optics.

Abstract: A liquid crystal polymer dispersion is formed where liquid crystal encapsulation is produced by a process in which a reactive additive formulation is mixed and photo-polymerized. The polymerizable additive formulation includes monofunctional, multifunctional and photoinitiator compounds in specific composition. The polymerizable additive formulation enhances the control of deformed globule or droplet size, structure integrity, electro-optical properties, and prohibits flow of the liquid crystal as it is encapsulated. A simple process and a controllable system for encapsulating cholesteric materials that provides rugged low-power flexible passively-driven displays. Such displays offer the possibility of lower cost roll-to-roll manufacturing in addition to lighter weight, more rugged and conformable displays.

Abstract: The present invention relates to a display film that may be transferred by lamination or otherwise onto a substrate. The display film is formed of a stack of layers that can include different types, arrangements, and functionality within the stack depending upon factors including the characteristics of the substrate (e.g., upper or lower, transparent or opaque, substrates) and addressing of the display (e.g., active or passive matrix, electrical or optical addressing). The layers of the stacked display film include one or more electrode layers and one or more liquid crystal layers and, in addition, may include various combinations of an adhesive layer, preparation layer, casting layer, light absorbing layer, insulation layers, and protective layers. The liquid crystal layer can include cholesteric or other liquid crystal material. The liquid crystal layer can be a dispersion of liquid crystal in a polymer matrix formed by a variety of techniques.

Abstract: Methods for treating aligning substrates produces uniform alignment of liquid crystals in at least two modes. The method is based on the treatment of liquid crystal aligning substrates with a collimated or partially collimated plasma beam. In one embodiment, the method comprises a step of bombarding an aligning substrate with at least one plasma beam from a plasma beam source at a designated incident angle to align the atomic/molecular structure or the surface profile of the aligning substrate in at least one aligned direction.

Abstract: In a preparation method, a chiral or cholesteric liquid crystal, a photoreactive monomer, and a photoinitiator are disposed in a liquid crystal cell. A principal surface of the liquid crystal cell is illuminated with ultraviolet light selected to have a non-uniform ultraviolet light intensity profile in the liquid crystal cell. The illuminating cooperates with the photoinitiator to polymerize at least a portion of the photoreactive monomer near the principal surface to generate a polymer network having a density corresponding to the non-uniform ultraviolet light intensity profile. The polymer network biases the liquid crystal toward a selected helical alignment direction. In some embodiments, the illuminating includes illuminating with first and second ultraviolet light intensity profiles to produce surface and volume polymer network components.

Abstract: The present invention provides a method of preparation of optical compensation films using a polymer stabilization technique so as to enable continuous roll-to-roll production. The films can be applied for reflective liquid crystal displays. They are prepared by photo-polymerizing a mixture comprising a reactive monomer (or mixture of monomers), a small amount of photoinitiator and liquid crystal. The concentration of the reactive monomer (mesogenic or non-mesogenic) in the reactive mixtures can be as low as 5% or as high as 99% by weight. The materials that can function as the optical compensation films in the present invention include, but are not limited to, mixtures of liquid crystal and reactive mesogenic monomers (rod-like, bent-shaped, and disc-like mesogenic monomers) containing polymerizable groups (monofunctionaly or multifunctional) selected from acrylate, methacrylate, vinyls, butadiene, vinyl ethers, or epoxide.

Abstract: An electro-optic device includes a liquid crystal cell (10, 10?) and at least one electrode (40, 42, 40?, 42?) arranged to selectively electrically bias the liquid crystal cell (10, 10?). A chiral or cholesteric liquid crystal (30, 30?) is disposed in the liquid crystal cell (10, 10?). The liquid crystal (10, 10?) has an optic axis substantially along a selected optic axis direction in the absence of an electrical bias. A polymeric network (32, 32?, 72) is disposed at an inside surface of the liquid crystal cell (10, 10?). The polymeric network (32, 32?, 72) extends partway into the liquid crystal cell (10, 10?) leaving at least a portion of the liquid crystal cell (10, 10?) substantially free of the polymeric network (32, 32?, 72).

Abstract: The present invention relates to a display film that may be transferred by lamination or otherwise onto a substrate. The display film is formed of a stack of layers that can include different types, arrangements, and functionality within the stack depending upon factors including the characteristics of the substrate (e.g., upper or lower, transparent or opaque, substrates) and addressing of the display (e.g., active or passive matrix, electrical or optical addressing). The layers of the stacked display film include one or more electrode layers and one or more liquid crystal layers and, in addition, may include various combinations of an adhesive layer, preparation layer, casting layer, light absorbing layer, insulation layers, and protective layers. The liquid crystal layer can include cholesteric or other liquid crystal material. The liquid crystal layer can be a dispersion of liquid crystal in a polymer matrix formed by a variety of techniques.

Abstract: A method for simultaneously fabricating a phase separated organic film and microstructures with liquid crystal having desired alignment is disclosed. The method includes the step of preparing a mixture of liquid crystal material, prepolymer, and polarization-sensitive material. The mixture is disposed on a substrate and a combination of UV or visible light or heat treatment is applied while simultaneously inducing phase separation so as to form a layer or microstructure of appropriately aligned liquid crystal material adjacent the substrate.

Abstract: A liquid crystal device comprising tilted smectic phases of banana-shaped liquid crystal molecules is disclosed. A method for fabricating a light modulating device is also disclosed. The method comprises the steps of providing a pair of substrates with a cell gap therebetween and permanently disposing at least one banana-shaped liquid crystal material into said cell gap. The present invention also provides a method of generating an image, comprising providing a pair of substrates with a cell gap therebetween, providing transparent electrodes on each of the substrates adjacent to the cell gap, disposing at least one banana-shaped liquid crystal material into the cell gap; and applying an electric field across the electrodes. The tilted smectic phases of banana-shaped liquid crystal may be in either a racemic or a chiral state.

Abstract: An electro-optic device includes a liquid crystal cell (10, 10?) and at least one electrode (40, 42, 40?, 42?) arranged to selectively electrically bias the liquid crystal cell (10, 10?). A chiral or cholesteric liquid crystal (30, 30?) is disposed in the liquid crystal cell (10, 10?). The liquid crystal (10, 10?) has an optic axis substantially along a selected optic axis direction in the absence of an electrical bias. A polymeric network (32, 32?, 72) is disposed at an inside surface of the liquid crystal cell (10, 10?). The polymeric network (32, 32?, 72) extends partway into the liquid crystal cell (10, 10?) leaving at least a portion of the liquid crystal cell (10, 10?) substantially free of the polymeric network (32, 32?, 72).

Abstract: An optical compensation film for a liquid crystal display is provided wherein the film is a polymer that is capable of producing light induced anisotropy. The film is irradiated with light to form an optical axis or axes.

Abstract: The present invention provides a method of preparation of optical compensation films using a polymer stabilization technique so as to enable continuous roll-to-roll production. The films can be applied for reflective liquid crystal displays. They are prepared by photo-polymerizing a mixture comprising a reactive monomer (or mixture of monomers), a small amount of photoinitiator and liquid crystal. The concentration of the reactive monomer (mesogenic or non-mesogenic) in the reactive mixtures can be as low as 5% or as high as 99% by weight. The materials that can function as the optical compensation films in the present invention include, but are not limited to, mixtures of liquid crystal and reactive mesogenic monomers (rod-like, bent-shaped, and disc-like mesogenic monomers) containing polymerizable groups (monofunctionaly or multifunctional) selected from acrylate, methacrylate, vinyls, butadiene, vinyl ethers, or epoxide.

Abstract: A liquid crystal device comprising tilted smectic phases of banana-shaped liquid crystal molecules is disclosed. A method for fabricating a light modulating device is also disclosed. The method comprises the steps of providing a pair of substrates with a cell gap therebetween and permanently disposing at least one banana-shaped liquid crystal material into said cell gap. The present invention also provides a method of generating an image, comprising providing a pair of substrates with a cell gap therebetween, providing transparent electrodes on each of the substrates adjacent to the cell gap, disposing at least one banana-shaped liquid crystal material into the cell gap; and applying an electric field across the electrodes. The tilted smectic phases of banana-shaped liquid crystal may be in either a racemic or a chiral state.

Abstract: A polymerizable liquid crystalline monomer is described comprising a polymerizable first terminal group, a central portion, and a second terminal group, wherein the monomer is capable of filament formation. Filaments can form as a result of an isotropic to smectic phase transition and can subsequently be polymerized by photoinitiation, for example.

Abstract: A method is provided to align liquid crystals in liquid crystal displays by using photo-crosslinkable low molecular weight materials. The material contains a polymerizable group and a photosensitive group. The material is dissolved in a solvent and is disposed onto a substrate and the solvent is removed. The resulting film is then cured with UV light to cross-link and induce anisotropy in the material. Also, a liquid crystal display that contains an alignment layer that is the is the photo-reaction product of a photo-crosslinkable material that contains at least one polymerizable group and at least one photosensitive group.

Abstract: A new liquid crystalline light modulating cell and material are characterized by liquid crystalline light modulating material of liquid crystal and polymer, the liquid crystal being a chiral nematic liquid crystal having positive dielectric anisotropy and including chiral material in an amount effective to form focal conic and twisted planar textures, the polymer being distributed in phase separated domains in the liquid crystal cell in an amount that permits the liquid crystal to change textures upon the application of a field and ruggedizes the structure. In still another embodiment, the material exhibits stability at zero field in a colored, light reflecting state, a light scattering state and multiple stable reflecting state therebetween, as well as being optically clear in the presence of a field. In yet another embodiment, the application of mechanical force to the cell changes the material from an optically clear state to a light reflecting state.