Abstract: Sulfate ester modified cellulose nanofibers having an average fiber diameter in the range of 1 nm to 500 nm, and having sulfate ester modified hydroxyl groups on surfaces of the cellulose nanofibers. A method of producing cellulose nanofibers that are nanosized, that have a high crystallinity degree, and that have large aspect ratios, the method being a chemical method that does not require any physical pulverization, that is energy-saving, and that can be performed under mild reaction conditions. A method of producing modified cellulose nanofibers including modifying the surfaces of the cellulose nanofibers through esterification or urethanization. A method of producing cellulose nanofibers includes impregnating cellulose with a fibrillation solution containing dimethylsulfoxide, at least one carboxylic acid anhydride selected from acetic anhydride and propionic anhydride, and sulfuric acid to fibrillate the cellulose.

Abstract: Sulfate ester modified cellulose nanofibers having an average fiber diameter in the range of 1 nm to 500 nm, and having sulfate ester modified hydroxyl groups on surfaces of the cellulose nanofibers. A method of producing cellulose nanofibers that are nanosized, that have a high crystallinity degree, and that have large aspect ratios, the method being a chemical method that does not require any physical pulverization, that is energy-saving, and that can be performed under mild reaction conditions. A method of producing modified cellulose nanofibers including modifying the surfaces of the cellulose nanofibers through esterification or urethanization. A method of producing cellulose nanofibers includes impregnating cellulose with a fibrillation solution containing dimethylsulfoxide, at least one carboxylic acid anhydride selected from acetic anhydride and propionic anhydride, and sulfuric acid to fibrillate the cellulose.

Abstract: Sulfate ester modified cellulose nanofibers having an average fiber diameter in the range of 1 nm to 500 nm, and having sulfate ester modified hydroxyl groups on surfaces of the cellulose nanofibers. A method of producing cellulose nanofibers that are nanosized, that have a high crystallinity degree, and that have large aspect ratios, the method being a chemical method that does not require any physical pulverization, that is energy-saving, and that can be performed under mild reaction conditions. A method of producing modified cellulose nanofibers including modifying the surfaces of the cellulose nanofibers through esterification or urethanization. A method of producing cellulose nanofibers includes impregnating cellulose with a fibrillation solution containing dimethylsulfoxide, at least one carboxylic acid anhydride selected from acetic anhydride and propionic anhydride, and sulfuric acid to fibrillate the cellulose.

Abstract: Provided is a method of producing fine cellulose fibers that are nanosized, that have a high crystallinity degree, and that are less vulnerable to fiber shape damage, the method including impregnating cellulose with a fibrillation solution to fibrillate the cellulose without mechanical crushing, and modifying the cellulose. The method of producing cellulose microfibrils of the present invention includes impregnating cellulose with a fibrillation solution containing a carboxylic acid vinyl ester or an aldehyde and an aprotic solvent having a donor number of 26 or more to fibrillate the cellulose. The aldehyde is at least one kind of aldehyde selected from the group consisting of an aldehyde represented by the following formula (1), paraformaldehyde, cinnamaldehyde, perillaldehyde, vanillin, and glyoxal: R1—CHO??(1) where R1 represents a hydrogen atom, an alkyl group having 1 to 16 carbon atoms, an alkenyl group, a cycloalkyl group, or an aryl group.

Abstract: Sulfate ester modified cellulose nanofibers having an average fiber diameter in the range of 1 nm to 500 nm, and having sulfate ester modified hydroxyl groups on surfaces of the cellulose nanofibers. A method of producing cellulose nanofibers that are nanosized, that have a high crystallinity degree, and that have large aspect ratios, the method being a chemical method that does not require any physical pulverization, that is energy-saving, and that can be performed under mild reaction conditions. A method of producing modified cellulose nanofibers including modifying the surfaces of the cellulose nanofibers through esterification or urethanization. A method of producing cellulose nanofibers includes impregnating cellulose with a fibrillation solution containing dimethylsulfoxide, at least one carboxylic acid anhydride selected from acetic anhydride and propionic anhydride, and sulfuric acid to fibrillate the cellulose.

Abstract: A method of producing cellulose fine fibers that are nanosized, that have a high crystallinity degree, and that are less vulnerable to fiber shape damage, the method including impregnating cellulose with a fibrillation solution containing formic acid to fibrillate the cellulose without vigorous mechanical crushing. The method of producing cellulose fine fibers including impregnating the cellulose with formic acid, a high-concentration formic acid aqueous solution, or a solution containing, in an aprotic solvent having a donor number of 26 or more, formic acid or a high-concentration formic acid aqueous solution serving as a fibrillation solution to fibrillate the cellulose. In addition, a method of producing surface-modified cellulose fine fibers including impregnating the cellulose with the fibrillation solution to modify the surfaces of cellulose fine fibers while fibrillating the cellulose.

Abstract: Provided is a method of producing fine cellulose fibers that are nanosized, that have a high crystallinity degree, and that are less vulnerable to fiber shape damage, the method including impregnating cellulose with a fibrillation solution to fibrillate the cellulose without mechanical crushing, and modifying the cellulose. The method of producing cellulose microfibrils of the present invention includes impregnating cellulose with a fibrillation solution containing a carboxylic acid vinyl ester or an aldehyde and an aprotic solvent having a donor number of 26 or more to fibrillate the cellulose. The aldehyde is at least one kind of aldehyde selected from the group consisting of an aldehyde represented by the following formula (1), paraformaldehyde, cinnamaldehyde, perillaldehyde, vanillin, and glyoxal: R1—CHO??(1) where R1 represents a hydrogen atom, an alkyl group having 1 to 16 carbon atoms, an alkenyl group, a cycloalkyl group, or an aryl group.

Abstract: Modified fine cellulose fibers are produced by impregnating a cellulose with a reactive fibrillation solution or mixture containing a catalyst including a base catalyst or an organic acid catalyst, a monobasic carboxylic anhydride, and an aprotic solvent having a donor number of not less than 26 to esterify and chemically fibrillate the cellulose. This method provides a simple efficient process for producing modified fine cellulose fibers that have a diameter from several nano-meters to submicrometers, a large aspect ratio, a high degree of crystallinity, less damage in the shape or crystalline structure of the fine fibers, a large aspect ratio, and an excellent dispersibility in an organic solvent; The catalyst may contain a pyridine compound. The monobasic carboxylic anhydride may be a C2-4aliphatic monocarboxylic anhydride.

Abstract: There is provided a solvent that can uniformly dissolve a polysaccharide within a short time period regardless of the crystal form of the polysaccharide and without requiring any special pretreatment. The solvent includes a tetraalkylammonium acetate represented by the below-indicated formula; and an aprotic polar solvent. A content of the aprotic polar solvent is 35 wt % or more. In the formula, R1, R2, R3, and R4 each independently represent an alkyl group having 3 to 6 carbon atoms.

Abstract: Cellulose nanofibers include: a linear portion; and a curved portion, in which an average of a length of the linear portion and an average of a maximum diameter of the linear portion have a relationship that satisfies the following Equation (a): (The average of the length of the linear portion)/(The average of the maximum diameter of the linear portion)?10??Equation (a)

Abstract: Cellulose nanofibers have an average degree of polymerization of 600 or more to 30000 or less, an aspect ratio of 20 or more to 10000 or less, an average diameter of 1 nm or more to 800 nm or less, and an I?-type crystal peak in an X-ray diffraction pattern, in which a hydroxyl group is chemically modified by a modifying group.

Abstract: Cellulose nanofibers have an average degree of polymerization of 600 or more to 30000 or less, an aspect ratio of 20 or more to 10000 or less, an average diameter of 1 nm or more to 800 nm or less, and an I?-type crystal peak in an X-ray diffraction pattern, in which a hydroxyl group in the cellulose nanofibers is esterified and has a modification degree of 1.0 or more based on all of the hydroxyl groups.

Abstract: There is provided a solvent that can uniformly dissolve a polysaccharide within a short time period regardless of the crystal form of the polysaccharide and without requiring any special pretreatment. The solvent includes a tetraalkylammonium acetate represented by the below-indicated formula; and an aprotic polar solvent. A content of the aprotic polar solvent is 35 wt % or more. [Chem. 1] In the formula, R1, R2, R3, and R4 each independently represent an alkyl group having 3 to 6 carbon atoms.

Abstract: The present invention is cellulose nanofibers having an average polymerization degree of 600 to 30000, an aspect ratio of 20 to 10000, an average diameter of 1 nm to 800 nm, and an I?-type crystal peak in an X-ray diffraction pattern.

Abstract: It is to provide a silsesquioxane having ?,?-diol group, and to provide an organic-inorganic hybrid resin composition comprising silsesquioxane and hydroxyalkyl cellulose. A composition comprising a cage-type structure of silsesquioxane represented by general formula (A), and a partially cleaved cage-type structure of silsesquioxane represented by general formula (B); (RSiO3/2)l??(A) (RSiO3/2)m(RSiO2H)n??(B) [wherein in formulae (A) and (B), l and m represent an integer of 4 or more, n represents an integer of 1 or more, and n/(l+m) is 0.03 to 0.2; each R may be the same or different, and represents an alkoxy group with 1 to 10 carbons, etc.; wherein at least one R in one molecule is a group having ?,?-diol group, and when the number of groups having ?,?-diol is 2 or more, they may be the same or different].

Abstract: It is to provide a silsesquioxane having ?,?-diol group, and to provide an organic-inorganic hybrid resin composition comprising silsesquioxane and hydroxyalkyl cellulose. A composition comprising a cage-type structure of silsesquioxane represented by general formula (A), and a partially cleaved cage-type structure of silsesquioxane represented by general formula (B); (RSiO3/2)l??(A) (RSiO3/2)m(RSiO2H)n??(B) [wherein in formulae (A) and (B), l and m represent an integer of 4 or more, n represents an integer of 1 or more, and n/(l+m) is 0.03 to 0.2; each R may be the same or different, and represents an alkoxy group with 1 to 10 carbons, etc.; wherein at least one R in one molecule is a group having ?,?-diol group, and when the number of groups having ?,?-diol is 2 or more, they may be the same or different].