Abstract: A rigid non-isocyanate polyurethane foam and a preparation method therefor are provided. According to the present application, a rigid epoxide is firstly reacted with carbon dioxide to obtain rigid cyclic carbonate, then the product is reacted with diamine to obtain rigid non-isocyanate polyurethane, and the rigid non-isocyanate polyurethane is mixed with a foaming agent for foaming to obtain rigid non-isocyanate polyurethane foam. The present application improves the mechanical property of non-isocyanate polyurethane by optimizing the structures and groups of raw materials; according to the present application, mild reaction conditions such as atmospheric pressure and low temperature are used, and the amounts of reactants and foaming agents are adjusted, so that the reaction is significantly enhanced, and an excellent foaming effect is achieved.

Abstract: A non-metal catalyst for synthesizing polycarbonate by CO2 and a preparation method therefor are provided. The preparation method of the non-metal catalyst includes the following steps: dissolving a hydroxyl functionalized organic ammonium halide monomer, a quaternary phosphonium salt monomer, and a hydroxyl functionalized imidazole salt monomer in a solvent, and polymerizing the mixture under the action of an initiator to obtain the non-metal catalyst for synthesizing the polycarbonate by using CO2. The non-metal catalyst prepared by the present invention is used as a heterogeneous catalytic material, is applied to a system for preparing polycarbonate by a one-step copolymerization reaction of CO2 and an epoxy compound, has high catalytic activity, does not need an additional cocatalyst or a solvent, efficiently converts CO2 into the polycarbonate, has no impurities such as metal in the product, and has the advantages of easy separation, recycling, and the like.

Abstract: A method for simultaneously determining fat-soluble vitamins and carotenoids in serum, and belonging to the technical field of analytical chemistry, includes an ionic liquid (IL) or a binary mixed solvent composed of an IL and another solvent is adopted as an extractant; the biological samples are pre-treated by liquid-liquid extraction (LLE) and then detected by high-performance liquid chromatography (HPLC); retinyl acetate and trans-?-apo-8?-carotenal are adopted as the internal standards for fat-soluble vitamins and carotenoids, respectively; and the internal standard method is adopted to establish standard curves for quantification based on the retention time and the UV-Vis absorption spectrum. Compared with the existing methods, in the disclosure, the pretreatment process is simple and easy to be conducted, the sample can be prepared in a short time, and the toxic and harmful organic solvent is used at a reduced amount.

Abstract: A method for simultaneously determining fat-soluble vitamins and carotenoids in serum, and belonging to the technical field of analytical chemistry, includes an ionic liquid (IL) or a binary mixed solvent composed of an IL and another solvent is adopted as an extractant; the biological samples are pre-treated by liquid-liquid extraction (LLE) and then detected by high-performance liquid chromatography (HPLC); retinyl acetate and trans-?-apo-8?-carotenal are adopted as the internal standards for fat-soluble vitamins and carotenoids, respectively; and the internal standard method is adopted to establish standard curves for quantification based on the retention time and the UV-Vis absorption spectrum. Compared with the existing methods, in the disclosure, the pretreatment process is simple and easy to be conducted, the sample can be prepared in a short time, and the toxic and harmful organic solvent is used at a reduced amount.