Abstract: The present invention relates to a transparent lithium aluminosilicate (LAS) glass-ceramic containing a ?-quartz solid solution as the main crystalline phase, the composition of which, expressed in percentages by mass of oxides, contains 60 to 67.5% SiO2, 18 to 22% Al2O3, 2.5 to 3.3% Li2O, 0 to 1.5% MgO, 1 to 3.5% ZnO, 0 to 4% BaO, 0 to 4% SrO, 0 to 2% CaO, 3.1 to 5% TiO2, 0.4 to 1.3% ZrO2, 0 to 1% Na2O, 0 to 1% K2O, 0 to 5% P2O5, 0.02 to 0.1% CoO, 0.05 to 0.25% Fe2O3, with (0.74 MgO + 0.19 BaO + 0.29 SrO + 0.53 CaO + 0.48 Na2O + 0.32 K2O) / Li2O < 0.8, and optionally up to 2% of at least one refining agent, the composition being free of V2O5 with the exception of unavoidable traces. It also relates to an article, consisting at least in part of a glass-ceramic, chosen in particular from a cooking plate and a glazing. It also relates to a lithium aluminosilicate glass, precursor of the glass-ceramic, and the process for producing the article.

Abstract: Objects of the present invention are: a lead-free enamel composition comprising finely divided glass particles, finely divided pigment particles and an organic binder, characterised in that the glass of said particles is a lead-free mineral glass, essentially having the composition below, which is expressed in percentages by weight of oxides: SiO2 45-60 B2O3 ?0-10 Al2O3 ?6-17 Na2O 0-7 K2O 0-7 Li2O 0-7 CaO ?0-12 BaO 13-27 ZnO ?3-17 MgO 0-9 TiO2 0-2 ZrO2 0-7 with Na2O + K2O + Li2O >4 the enamel able to be obtained by firing of said composition; glass-ceramic articles, which are decorated with said enamel; and new lead-free mineral glasses.

Abstract: The present invention relates to a product, comprising a body which is delimited by a surface, of a lithium aluminosilicate-based glass-ceramic, as well as to its method of preparation. Characteristically, said glass-ceramic has, on at least one part of said surface, a surface layer the degree of crystallization of which is greater than that of said glass-ceramic within said body.

Abstract: The present invention relates to a product, comprising a body which is delimited by a surface, of a lithium aluminosilicate-based glass-ceramic, as well as to its method of preparation. Characteristically, said glass-ceramic has, on at least one part of said surface, a surface layer the degree of crystallization of which is greater than that of said glass-ceramic within said body.

Abstract: Objects of the present invention are: a lead-free enamel composition comprising finely divided glass particles, finely divided pigment particles and an organic binder, characterised in that the glass of said particles is a lead-free mineral glass, essentially having the composition below, which is expressed in percentages by weight of oxides: SiO2 45-60 CaO ?0-12 B2O3 ?0-10 BaO 13-27 Al2O3 ?6-17 ZnO ?3-17 Na2O 0- 7 MgO 0- 9 K2O 0-7 TiO2 0-2 Li2O 0- 7 ZrO2 0- 7 with Na2O + K2O + Li2O > 4 the enamel able to be obtained by firing of said composition; glass-ceramic articles, which are decorated with said enamel; and new lead-free mineral glasses.

Abstract: Objects of the present invention are: a lead-free enamel composition comprising finely divided glass particles, finely divided pigment particles and an organic binder, characterised in that the glass of said particles is a lead-free mineral glass, essentially having the composition below, which is expressed in percentages by weight of oxides: SiO2 45-60 CaO ?0-12 B2O3 ?0-10 BaO 13-27 Al2O3 ?6-17 ZnO ?3-17 Na2O 0-7 MgO 0-9 K2O 0-7 TiO2 0-2 Li2O 0-7 ZrO2 0-7 with Na2O + >4 K2O + Li2O the enamel able to be obtained by firing of said composition; glass-ceramic articles, which are decorated with said enamel; and new lead-free mineral glasses.

Abstract: Objects of the present invention are:

Abstract: The invention relates to a decorated glass-ceramic plate, suitable in particular as a cooktop, comprising a glass-ceramic plate having a low coefficient of thermal expansion between ±15×10−7 K−1 (20-700° C.) and a decoration on the surface of said plate. Characteristically, said decoration comprises a vitrified glass frit containing 10 to 35% by weight of pigments and said decorated glass-ceramic cooktop has a modulus of rupture of at least 120 MPa. The invention also relates to a method of decorating glass-ceramic plates and to an enamel which is useful in particular for implementing said method.