Abstract: Described herein are catalytic hydrogenation and the use of ruthenium complexes having a bidentate diphosphine ligand or two monodentate phosphine ligands, two carboxylate ligands, and optionally a diamine ligand in hydrogenation processes for the reduction of imines into the corresponding amines.

Abstract: Described herein is a process including isomerizing the ? position of a ?-trisubstituted C3-C70 carbonyl compound.

Abstract: Describes herein are methods of using ruthenium complexes in base-free hydrogenation processes for the reduction of imines into the corresponding amines.

Abstract: Described herein is a process including isomerizing the ? position of a ?-trisubstituted C3-C70 carbonyl compound.

Abstract: Described herein are catalytic hydrogenation and the use of ruthenium complexes having a bidentate diphosphine ligand or two monodentate phosphine ligands, two carboxylate ligands, and optionally a diamine ligand in hydrogenation processes for the reduction of imines into the corresponding amines.

Abstract: A method to confer, enhance, improve or modify the flavor properties of a flavoring composition or flavored article by adding to the composition or article the compound 3-mercaptoheptyl acetate or an optically active enantiomer thereof in an amount effective to provide a flavor base having top notes of the citrus-grapefruit, teas and/or peach type and/or red fruit. The compound is typically added to provide an amount of from 0.0001 to 500 ppm in the flavoring composition or flavored article. Also, the resultant flavored composition or flavored article.

Abstract: A composition of matter comprising a) at least one compound of formula in the form of any one of its isomers or a mixture thereof; wherein R1 represents a hydrogen atom or a C1-2 alkyl group; and R represents a group of formula —CH2C(Me)2OH; with R being, relative to position 1, a meta, a para substituent of the aromatic ring or a mixture thereof; and b) at least one compound of formula in the form of any one of its isomers or a mixture thereof; wherein R1 and R have the same meaning as defined in formula (I); their uses as perfuming ingredients as well as perfuming composition and consumer products including such a composition of matter and a process to prepare the composition.

Abstract: The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of Fe complexes with tridentate ligands, having one amino or imino coordinating group and two phosphino coordinating groups, in hydrogenation processes for the reduction of ketones or aldehydes, into the corresponding alcohol or diol, respectively.

Abstract: The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of Fe complexes with tridentate ligands, having one amino or imino coordinating group and two phosphino coordinating groups, in hydrogenation processes for the reduction of ketones or aldehydes, into the corresponding alcohol or diol, respectively.

Abstract: A composition of matter comprising a) at least one compound of formula in the form of any one of its isomers or a mixture thereof; wherein R1 represents a hydrogen atom or a C1-2 alkyl group; and R represents a group of formula —CH2C(Me)2OH; with R being, relative to position 1, a meta, a para substituent of the aromatic ring or a mixture thereof; and b) at least one compound of formula in the form of any one of its isomers or a mixture thereof; wherein R1 and R have the same meaning as defined in formula (I); their uses as perfuming ingredients as well as perfuming composition and consumer products including such a composition of matter and a process to prepare the composition.

Abstract: The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of Fe complexes with tridentate ligands, having one amino or imino coordinating group and two phosphino coordinating groups, in hydrogenation processes for the reduction of ketones or aldehydes, into the corresponding alcohol or diol, respectively.

Abstract: The present invention relates to certain iron complexes that have utility in the field of catalytic hydrogenation and, more particularly, to certain iron complexes of tridentate ligands having one amino or imino coordinating groups and two phosphino coordinating groups. These iron complexes can be used in hydrogenation processes for the reduction of ketones, aldehydes, esters or lactones into the corresponding alcohol or diol, respectively.

Abstract: The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of Fe complexes with tridentate ligands, having one amino or imino coordinating group and two phosphino coordinating groups, in hydrogenation processes for the reduction of ketones, aldehydes, esters or lactones into the corresponding alcohol or diol, respectively.

Abstract: The present invention concerns the use as perfuming ingredient of a composition of matter comprising at least 94% w/w of 4,6-dimethyl-3-octen-5-ol, and at most 1% w/w of 2-methylpent-2-en-1-ol and 3-ethyl-4-methylhexan-2-one.

Abstract: The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of Fe complexes with tridentate ligands, having one amino or imino coordinating group and two phosphino coordinating groups, in hydrogenation processes for the reduction of ketones or aldehydes, into the corresponding alcohol or diol, respectively.

Abstract: The present invention concerns the use as perfuming ingredient of a composition of matter comprising at least 94% w/w of 4,6-dimethyl-3-octen-5-ol, and at most 1% w/w of 2-methylpent-2-en-1-ol and 3-ethyl-4-methylhexan-2-one.

Abstract: A method to confer, enhance, improve or modify the flavor properties of a flavoring composition or flavored article by adding to the composition or article the compound 3-mercaptoheptyl acetate or an optically active enantiomer thereof in an amount effective to provide a flavor base having top notes of the citrus-grapefruit, teas and/or peach type and/or red fruit. The compound is typically added to provide an amount of from 0.0001 to 500 ppm in the flavoring composition or flavored article. Also, the resultant flavored composition or flavored article.

Abstract: The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of Fe complexes with tridentate ligands, having one amino or imino coordinating group and two phosphino coordinating groups, in hydrogenation processes for the reduction of ketones, aldehydes, esters or lactones into the corresponding alcohol or diol, respectively.

Abstract: The present invention relates to the field of catalytic hydrogenation and, more particularly, to a process for the reduction by hydrogenation, using molecular H2, of a C6-C20 conjugated dienal into the corresponding deconjugated enal, characterized in that said process is carried out in the presence of a catalytic system comprising at least a base and at least one complex in the form of a rhodium complex comprising a C34-C60 bidentate diphosphine ligand (L2) coordinating the rhodium.

Abstract: The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of Ru complexes with bidentate ligands, having one amino or imino coordinating group and one phosphino coordinating group, in hydrogenation processes for the reduction of esters or lactones into the corresponding alcohol or diol respectively.