Abstract: Lithium ion batteries and electrolytes therefor are provided, which include electrolyte additives having dithioester functional group(s) that stabilize the SEI (solid-electrolyte interface) at the surfaces of the anode material particles, and/or stabilize the CEI (cathode electrolyte interface) at the surfaces of the cathode material particles, and/or act as oxygen scavengers to prevent cell degradation. The electrolyte additives having dithioester functional group(s) may function as polymerization controlling and/or chain transfer agents that regulate the level of polymerization of other electrolyte components, such as VC (vinyl carbonate) and improve the formation and operation of the batteries. The lithium ion batteries may have metalloid-based anodes—including mostly Si, Ge and/or Sn as anode active material particles.

Abstract: Electrolytes, lithium ion cells and corresponding methods are provided, for extending the cycle life of fast charging lithium ion batteries. The electrolytes are based on fluoroethylene carbonate (FEC) and/or vinylene carbonate (VC) as the cyclic carbonate component, and possibly on ethyl acetate (EA) and/or ethyl methyl carbonate (EMC) as the linear component. Proposed electrolytes extend the cycle life by factors of two or more, as indicated by several complementary measurements.

Abstract: Electrolytes are provided, as well as fast charging lithium ion batteries with the electrolytes and corresponding methods—which enhance the safety and performance of the fast charging lithium ion batteries. The electrolytes comprise four-carbon chain ester(s) such as ethyl butyrate and/or butyl acetate as a significant part of the linear solvent (e.g., at least half and up to the full volume) and possibly vinyl carbonate as the cyclic carbonate solvent, in addition to lithium salt(s) and possibly additives. The use of vinyl carbonate enhances the ion conductivity of the electrolyte, while the use of four-carbon chain ester(s) such as ethyl butyrate and/or butyl acetate enhances the safety of the battery.

Abstract: Electrolytes, lithium ion cells and corresponding methods are provided, for extending the cycle life of fast charging lithium ion batteries. The electrolytes are based on fluoroethylene carbonate (FEC) and/or vinylene carbonate (VC) as the cyclic carbonate component, and possibly on ethyl acetate (EA) and/or ethyl methyl carbonate (EMC) as the linear component. Proposed electrolytes extend the cycle life by factors of two or more, as indicated by several complementary measurements.

Abstract: An anode material for a lithium ion device includes an active material including silicon nanoparticles and boron carbide nanoparticles. The boron carbide nanoparticles are at least one order of magnitude smaller than the silicon nanoparticles. The weight percentage of the silicon is between about 4 to 35 weight % of the total weight of the anode material and the weight percentage of the boron carbide is between about 2.5 to about 25.6% of the total weight of the anode material. The active material may include carbon at a weight percentage of between 5 to about 60 weight % of the total weight of the anode material. Additional materials, methods of making and devices are taught.

Abstract: Electrolytes, lithium ion cells and corresponding methods are provided, for extending the cycle life of fast charging lithium ion batteries. The electrolytes are based on fluoroethylene carbonate (FEC) and/or vinylene carbonate (VC) as the cyclic carbonate component, and possibly on ethyl acetate (EA) and/or ethyl methyl carbonate (EMC) as the linear component. Proposed electrolytes extend the cycle life by factors of two or more, as indicated by several complementary measurements.

Abstract: An anode material for a lithium ion device includes an active material including silicon nanoparticles and boron carbide nanoparticles. The boron carbide nanoparticles are at least one order of magnitude smaller than the silicon nanoparticles. The weight percentage of the silicon is between about 4 to 35 weight % of the total weight of the anode material and the weight percentage of the boron carbide is between about 2.5 to about 25.6% of the total weight of the anode material. The active material may include carbon at a weight percentage of between 5 to about 60 weight % of the total weight of the anode material. Additional materials, methods of making and devices are taught.

Abstract: Methods for manufacturing multi-functional electrode (MFE) devices for fast-charging of energy-storage devices are provided. The method includes assembling first MFE structure for forming a suitable electrochemical half-couple, the first MFE structure having a first fast-charging component (FCC) and a first MFE assembly and a counter-electrode structure for forming a complementary electrochemical half-couple and supplying an internal voltage controller (IVC) for applying a bias potential to the first MFE structure and/or the counter-electrode structure, the bias potential is set in accordance with the first MFE structure and said counter-electrode structure. The IVC is configured to regulate an intra-electrode potential gradient between the first FCC and the first MFE assembly to control a charge rate from the first FCC to the first MFE assembly.

Abstract: Methods for manufacturing multi-functional electrode (MFE) devices for fast-charging of energy-storage devices are provided. The method includes assembling first MFE structure for forming a suitable electrochemical half-couple, the first MFE structure having a first fast-charging component (FCC) and a first MFE assembly and a counter-electrode structure for forming a complementary electrochemical half-couple and supplying an internal voltage controller (IVC) for applying a bias potential to the first MFE structure and/or the counter-electrode structure, the bias potential is set in accordance with the first MFE structure and said counter-electrode structure. The IVC is configured to regulate an intra-electrode potential gradient between the first FCC and the first MFE assembly to control a charge rate from the first FCC to the first MFE assembly.

Abstract: An anode material for a lithium ion device includes an active material including silicon and boron. The weight percentage of the silicon is between about 4 to 35 weight % of the total weight of the anode material and the weight percentage of the boron is between about 2 to 20 weight % of the total weight of the anode material. The active material may include carbon at a weight percentage of between between 5 to about 60 weight % of the total weight of the anode material. Additional materials, methods of making and devices are taught.

Abstract: The present invention discloses multi-functional electrode (MFE) devices for fast-charging of energy-storage devices. MFE devices include: a multi-functional electrode (MFE) device for fast-charging of energy-storage devices, the device including: a first MFE structure for forming a suitable electrochemical half-couple, the first MFE structure having a first fast-charging component (FCC) and a first MFE assembly; a counter-electrode structure for forming a complementary electrochemical half-couple to the first MFE structure; and an internal voltage controller (IVC) for applying a bias potential to the first MFE structure and/or the counter-electrode structure, whereby the bias potential is set in accordance with the chemical nature of the first MFE structure and the counter-electrode structure. Preferably, the IVC is configured to regulate an intra-electrode potential gradient between the first FCC and the first MFE assembly, thereby controlling a charge rate from the first FCC to the first MFE assembly.

Abstract: The present invention discloses multi-functional electrode (MFE) devices for fast-charging of energy-storage devices. MFE devices include: a multi-functional electrode (MFE) device for fast-charging of energy-storage devices, the device including: a first MFE structure for forming a suitable electrochemical half-couple, the first MFE structure having a first fast-charging component (FCC) and a first MFE assembly; a counter-electrode structure for forming a complementary electrochemical half-couple to the first MFE structure; and an internal voltage controller (IVC) for applying a bias potential to the first MFE structure and/or the counter-electrode structure, whereby the bias potential is set in accordance with the chemical nature of the first MFE structure and the counter-electrode structure. Preferably, the IVC is configured to regulate an intra-electrode potential gradient between the first FCC and the first MFE assembly, thereby controlling a charge rate from the first FCC to the first MFE assembly.

Abstract: A system and method for bio-electricity production are provided. The system includes a microorganism fuel cell in which the anode compartment comprises a microorganism cell having displayed thereon an enzyme to oxidize the substrate and generate electrons. Microorganism cells, such as bacteria or yeast, may be transformed to display enzymes such as oxidases, alcohol dehydrigenases and glucoamylases.

Abstract: A system and method for bio-electricity production are provided. The system includes a microorganism fuel cell in which the anode compartment comprises a microorganism cell having displayed thereon an enzyme to oxidize the substrate and generate electrons. Microorganism cells, such as bacteria or yeast, may be transformed to display enzymes such as oxidases, alcohol dehydrigenases and glucoamylases.