Abstract: Processes of polymerizing olefin monomers.

Abstract: Embodiments are directed to polymer compositions and foams including polymer compositions. Embodiments of the polymer composition may include at least 55 wt. %, based on the total weight of the polymer composition, of a polyolefin elastomer having an ethylene content of from greater than 50 wt. % to less than 80 wt. % and a cross-linkable blend comprising: (i) from 1 wt. % to 99 wt. %, based on the total weight of the cross-linkable blend, of an E/X/Y polymer and (ii) from 1 wt. % to 99 wt. %, based on the total weight of the cross-linkable blend, of an epoxycontaining polymer.

Abstract: An encapsulant film is made from a composition comprising (A) a non-polar ethylene-based polymer; (B) an organic peroxide; (C) a silane coupling agent; and (D) a co-agent comprising a compound of Structure I wherein R1-R6 each is independently selected from the group consisting of hydrogen, a C1-C8 hydrocarbyl group, a C1-C36 substituted hydrocarbyl group, and combinations thereof.

Abstract: A process to prepare an alpha composition comprising a first ethylene/alpha-olefin/interpolymer fraction and a second ethylene/alpha-olefin/interpolymer fraction; said process comprising polymerizing, in one reactor, a reaction mixture, comprising ethylene and an alpha-olefin, a biphenyl phenol metal complex selected from Structure 1, as described herein, and a biphenyl phenol metal complex selected from Structure 2, as described herein; and alpha compositions prepared therefrom.

Abstract: Foam compositions comprise at least an ethylene/?-olefin interpolymer. The ethylene/?-olefin interpolymers of the present disclosure are multi-block copolymers comprising at least one soft block and at least one hard block. The foam compositions can further comprise a blowing agent and a cross-linking agent. Methods of making the foam compositions and foamed articles made from the foam compositions are also described.

Abstract: Disclosed herein is a film comprising a polymer blend, the polymer blend comprising a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190° C. Disclosed herein too is a method of manufacturing a film comprising blending a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole to form a polymer blend; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190° C.; and forming the polymer blend into a film.

Abstract: An encapsulant film is made from a composition comprising (A) a non-polar ethylene-based polymer; (B) an organic peroxide; (C) a silane coupling agent; and (D) a co-agent comprising a compound of Structure I wherein R1-R6 each is independently selected from the group consisting of hydrogen, a C1-C8 hydrocarbyl group, a C1-C36 substituted hydrocarbyl group, and combinations thereof.

Abstract: A formulation of a poly(propylene-co-ethylene) elastomer copolymer and a poly(ethylene-co-1-octene) block copolymer; a method of making the formulation; a manufactured article comprising or made from the formulation; and a method of using the manufactured article.

Abstract: A painted article includes a primer layer between a substrate and a paint layer, of which the substrate is the product of a substrate forming composition including an olefin block copolymer and a polypropylene polymer having a density from 0.89 g/cm3 and 0.92 g/cm3. The substrate is free of (1) phthalate-based plasticizer, (2) halogen-containing polymer, and (3) leachable, small polymeric units derived from styrene monomer.

Abstract: A formulation of a poly(propylene-co-ethylene) elastomer copolymer and a poly(ethylene-co-1-octene) block copolymer; a method of making the formulation; a manufactured article comprising or made from the formulation; and a method of using the manufactured article.

Abstract: Disclosed herein is a film comprising a polymer blend, the polymer blend comprising a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190° C. Disclosed herein too is a method of manufacturing a film comprising blending a first polyolefin elastomer having a weight average molecular weight of 120,000 to 350,000 grams per mole; and a second polyolefin elastomer having a weight average molecular weight of 15,000 to 75,000 grams per mole to form a polymer blend; wherein the overall melt index of the polymer blend is less than 8 g/10 minutes when measured as per ASTM D1238 at 2.16 kilograms at 190° C.; and forming the polymer blend into a film.

Abstract: The present disclosure provides a food contact article. The food contact article includes a polymeric composition composed of a neat olefin block copolymer. The food contact article exhibits a total color change value, ?E, of less than 20. The polymeric composition provides an article that is suitable for food contact application, the article having softness and stain resistance.

Abstract: A painted article includes a primer layer between a substrate and a paint layer, of which the substrate is the product of a substrate forming composition including an olefin block copolymer and a polypropylene polymer having a density from 0.89 g/cm3 and 0.92 g/cm3. The substrate is free of (1) phthalate-based plasticizer, (2) halogen-containing polymer, and (3) leachable, small polymeric units derived from styrene monomer.

Abstract: The present disclosure provides a food contact article. The food contact article includes a polymeric composition composed of a neat olefin block copolymer. The food contact article exhibits a total color change value, ?E, of less than 20. The polymeric composition provides an article that is suitable for food contact application, the article having softness and stain resistance.

Abstract: Disclosed are olefin block copolymer formulations comprising polyethylene and polypropylene that provide improved adhesion properties to polypropylene while maintaining desired flexural modulus characteristics and are particularly suited for overmolded goods.

Abstract: Substantially isotaclic propylene interpolyraets comprise (A) at least 60 weight percent (wt %) units derived from propylene, and (B) between greater than zero and 40 wt % units derived from ethylene, the propylene interpolyrner further characterized by at least one of the following properties: (1) a ratio of less than 1 measured at interpolyraer number average molecular weight (Mn), (2) a relative compositional drift of less than 50%, arid (3) propylene chain segments having a chain isotacticity triad index of at least 70 mole percent.

Abstract: Substantially isotaclic propylene interpolyraets comprise (A) at least 60 weight percent (wt %) units derived from propylene, and (B) between greater than zero and 40 wt % units derived from ethylene, the propylene interpolyrner further characterized by at least one of the following properties: (1) a ratio of less than 1 measured at interpolyraer number average molecular weight (Mn), (2) a relative compositional drift of less than 50%, arid (3) propylene chain segments having a chain isotacticity triad index of at least 70 mole percent.

Abstract: The present invention includes a composition comprising a coupled impact propylene copolymer. Preferably, the coupled impact propylene copolymer has an elastomeric phase that is present in an amount of at least 9 weight percent of the coupled propylene copolymer. Articles formed from the coupled propylene copolymer exhibit improved directionally balanced impact properties as compared with articles formed form comparable noncoupled impact propylene copolymers and also exhibit improved ductile-to-brittle transition temperatures compared with comparable noncoupled impact propylene copolymers. The invention also includes methods for making the coupled impact propylene copolymers using coupling agents, preferably, poly(sulfonyl azides). The invention further includes articles of manufacture that are made from the coupled impact propylene copolymer of the invention.

Abstract: The present invention includes a coextruded film having at least two layers. The first layer contains a coupled propylene polymer and the second layer contains an in-reactor blend of a linear low density polyethylene fraction and a substantially linear polyethylene fraction. Alternatively, the second layer may include a homogeneously branched linear polyethylene. Preferably, the first layer makes up about 50 weight percent or less of the overall coextruded film structure. The first layer may also contain a polyethylene, such as a linear low density polyethylene, a low density polyethylene, a high density polyethylene, substantially linear polyethylene, a homogeneously branched linear polyethylene, an in-reactor blend of linear low density polyethylene and a substantially linear polyethyelene, and blends thereof.

Abstract: The present invention includes a composition comprising a coupled impact propylene copolymer. Preferably, the coupled impact propylene copolymer has an elastomeric phase that is present in an amount of at least 9 weight percent of the coupled propylene copolymer. Articles formed from the coupled propylene copolymer exhibit improved directionally balanced impact properties as compared with articles formed form comparable noncoupled impact propylene copolymers and also exhibit improved ductile-to-brittle transition temperatures compared with comparable noncoupled impact propylene copolymers. The invention also includes methods for making the coupled impact propylene copolymers using coupling agents, preferably, poly(sulfonyl azides). The invention further includes articles of manufacture that are made from the coupled impact propylene copolymer of the invention.