Abstract: The present disclosure relates to a self-supporting electrocatalytic material and a preparation method thereof, the self-supporting electrocatalytic material is a Cu2O/WO3/CF self-supporting electrocatalytic material. The Cu2O/WO3/CF self-supporting electrocatalytic material comprises: a foamed copper substrate, and Cu2O and WO3 grown in situ on the foamed copper substrate.

Abstract: The present disclosure relates to a W18O49/COO/CoWO4/NF self-supporting electrocatalytic material and a preparation method thereof, the W18O49/CoO/CoWO4/NF self-supporting electrocatalytic material comprising: a foamed nickel substrate and a W18O49/CoO/CoWO4 composite material formed in-situ on a foamed nickel substrate. Preferably, the W18O49/CoO/CoWO4 composite material is CoO/CoWO4 composite nanosheets and W18O49 nanowires distributed among the CoO/CoWO4 composite nanosheets.

Abstract: The present disclosure relates to a W18O49/CoO/NF self-supporting electrocatalytic material and a preparation method thereof, the W18O49/CoO/NF self-supporting electrocatalytic material comprises: a foamed nickel substrate, and a W18O49/CoO composite nano material generated on the foamed nickel substrate in situ; preferably, wherein the W18O49/CoO composite nano material comprises CoO nanosheets attached directly to the foamed nickel substrate, and W18O49 nanowires attached to the nanosheets.

Abstract: The present invention relates to a core-shell Fe2P@C—Fe3C electrocatalyst and a preparation method and application thereof. The core-shell Fe2P@C—Fe3C electrocatalyst comprises a carbon nanotube as a matrix which is formed by a carbon layer with FeC3 nano-dots distributed therein, and Fe2P@C embedded in the carbon nanotube. The Fe2P@C has a core-shell structure and is formed by coating Fe2P with carbon.

Abstract: The invention relates to an ultra-thin carbon-layer composite material modified by nickel nanoclusters and vanadium carbide particles, and its preparation method and application. The composite material comprises a two-dimensional ultra-thin carbon-layer as a matrix, in which nickel clusters and vanadium carbide nanoparticles are embedded to form coupling interfaces between Ni and C, VC and C, and Ni and VC. The thickness of the two-dimensional ultra-thin carbon-layer is less than 10 nm.

Abstract: The invention relates to a V-Ni2P/g-C3N4 photocatalyst, a preparation method, and application thereof. The V-Ni2P/g-C3N4 photocatalyst is a composite material of V-Ni2P and g-C3N4, wherein V-Ni2P has the spherical structure formed by nanosheets; the mass ratio of the V-Ni2P and g-C3N4 is (0.01 to 0.2):1.

Abstract: A preparation method of a tetragonal NaV2O5.H2O nanosheet-like powder includes steps of: (Step 1) simultaneously adding NaVO3 and Na2S.9H2O into deionized water, and then magnetically stirring, and obtaining a black turbid solution; (Step 2) sealing after putting the black turbid solution into an inner lining of a reaction kettle, fixing the sealed inner lining in an outer lining of the reaction kettle, placing the reaction kettle into a homogeneous reactor, and then performing a hydrothermal reaction; and (Step 3) after completing the hydrothermal reaction, naturally cooling the reaction kettle to the room temperature, and then alternately cleaning through water and alcohol, and then collecting a product, drying the product, and finally obtaining the tetragonal NaV2O5.H2O nanosheet-like powder with a thickness in a range of 30-60 nm and a single crystal structure grown along a (002) crystal orientation.

Abstract: Provided is a three-phase system V2O3/VN/Mo2C nanoelectrode material, and a preparation method and application thereof. The nanoelectrode material comprises V2O3 particles, VN particles, and Mo2C particles. The V2O3 particles, VN particles, and Mo2C particles are interlaced in lattice stripes and are uniformly distributed. The mass ratio of the V2O3, VN and Mo2C is (1 to 4):(10 to 40):(4 to 16). The above-mentioned three kinds of nanoparticles are intertwined to form more incoherent interface area. The increase in the area of the incoherent interface area will cause more defects, so that more active sites are provided, and the hydrogen production performance is improved.

Abstract: Provided is a high-efficiency vanadium nitride/molybdenum carbide heterojunction hydrogen production electrocatalyst, and a preparation method and application thereof. The electrocatalyst has a heterojunction structure formed by coupling VN and Mo2C, wherein the mass ratio of VN and Mo2C is 20:1 to 50:1. The electrocatalyst couples nano-VN and Mo2C to form a VN/Mo2C heterojunction, so that the active center is increased, and the balance of the reaction kinetics of H+ adsorption and H2 desorption is facilitated, thereby greatly improving the activity of the electrocatalyst.

Abstract: The present disclosure relates to a self-supporting electrocatalytic material and a preparation method thereof, the self-supporting electrocatalytic material is a Cu2O/WO3/CF self-supporting electrocatalytic material. The Cu2O/WO3/CF self-supporting electrocatalytic material comprises: a foamed copper substrate, and Cu2O and WO3 grown in situ on the foamed copper substrate.

Abstract: The present disclosure relates to a W18O49/COO/CoWO4/NF self-supporting electrocatalytic material and a preparation method thereof, the W18O49/CoO/CoWO4/NF self-supporting electrocatalytic material comprising: a foamed nickel substrate and a W18O49/CoO/CoWO4 composite material formed in-situ on a foamed nickel substrate. Preferably, the W18O49/CoO/CoWO4 composite material is CoO/CoWO4 composite nanosheets and W18O49 nanowires distributed among the CoO/CoWO4 composite nanosheets.

Abstract: The present disclosure relates to a W18O49/CoO/NF self-supporting electrocatalytic material and a preparation method thereof, the W18O49/CoO/NF self-supporting electrocatalytic material comprises: a foamed nickel substrate, and a W18O49/CoO composite nano material generated on the foamed nickel substrate in situ; preferably, wherein the W18O49/CoO composite nano material comprises CoO nanosheets attached directly to the foamed nickel substrate, and W18O49 nanowires attached to the nanosheets.

Abstract: The invention relates to a V—Ni2P/g-C3N4 photocatalyst, a preparation method, and application thereof. The V—Ni2P/g-C3N4 photocatalyst is a composite material of V—Ni2P and g-C3N4, wherein V—Ni2P has the spherical structure formed by nanosheets; the mass ratio of the V—Ni2P and g-C3N4 is (0.01 to 0.2):1.

Abstract: The present invention relates to a core-shell Fe2P@C—Fe3C electrocatalyst and a preparation method and application thereof. The core-shell Fe2P@C—Fe3C electrocatalyst comprises a carbon nanotube as a matrix which is formed by a carbon layer with FeC3 nano-dots distributed therein, and Fe2P@C embedded in the carbon nanotube. The Fe2P@C has a core-shell structure and is formed by coating Fe2P with carbon.

Abstract: The invention relates to an ultra-thin carbon-layer composite material modified by nickel nanoclusters and vanadium carbide particles, and its preparation method and application. The composite material comprises a two-dimensional ultra-thin carbon-layer as a matrix, in which nickel clusters and vanadium carbide nanoparticles are embedded to form coupling interfaces between Ni and C, VC and C, and Ni and VC. The thickness of the two-dimensional ultra-thin carbon-layer is less than 10 nm.

Abstract: A preparation method of a tetragonal NaV2O5.H2O nanosheet-like powder includes steps of: (Step 1) simultaneously adding NaVO3 and Na2S.9H2O into deionized water, and then magnetically stirring, and obtaining a black turbid solution; (Step 2) sealing after putting the black turbid solution into an inner lining of a reaction kettle, fixing the sealed inner lining in an outer lining of the reaction kettle, placing the reaction kettle into a homogeneous reactor, and then performing a hydrothermal reaction; and (Step 3) after completing the hydrothermal reaction, naturally cooling the reaction kettle to the room temperature, and then alternately cleaning through water and alcohol, and then collecting a product, drying the product, and finally obtaining the tetragonal NaV2O5.H2O nanosheet-like powder with a thickness in a range of 30-60 nm and a single crystal structure grown along a (002) crystal orientation.

Abstract: A preparation method of a tetragonal NaV2O5.H2O nanosheet-like powder includes steps of: (S1) simultaneously adding NaVO3 and Na2S.9H2O into deionized water, and then magnetically stirring, and obtaining a black turbid solution; (S2) sealing after putting the black turbid solution into an inner lining of a reaction kettle, fixing the sealed inner lining in an outer lining of the reaction kettle, placing the reaction kettle into a homogeneous reactor, and then performing a hydrothermal reaction; and (S3) after completing the hydrothermal reaction, naturally cooling the reaction kettle to the room temperature, and then alternately cleaning through water and alcohol, and then collecting a product, drying the product, and finally obtaining the tetragonal NaV2O5.H2O nanosheet-like powder with a thickness in a range of 30-60 nm and a single crystal structure grown along a (002) crystal orientation.

Abstract: A composite material preparation system comprises a sealed reaction kettle for containing reactants and base materials; temperature and pressure detecting units for detecting the temperature and pressure inside the reaction kettle; and a heating unit for hydrothermally induced heating, based on the detected temperature and pressure values. The heating unit comprises an induction coil, an induction heating device, and a control mechanism for controlling the generation of an induction frequency of the induction heating device. The reaction kettle is located in the induction coil, both ends of the induction coil are mounted on an outer wall of the induction heating device, and the induction coil and the induction heating device have circulating water introduced inside. The device can prepare a composite material having good interface bonding, by utilizing induced heating under the premise of controllable temperature and pressure, and by utilizing the characteristic that the reactants themselves are heated.

Abstract: A preparation method of a tetragonal NaV2O5.H2O nanosheet-like powder includes steps of: (S1) simultaneously adding NaVO3 and Na2S.9H2O into deionized water, and then magnetically stirring, and obtaining a black turbid solution; (S2) sealing after putting the black turbid solution into an inner lining of a reaction kettle, fixing the sealed inner lining in an outer lining of the reaction kettle, placing the reaction kettle into a homogeneous reactor, and then performing a hydrothermal reaction; and (S3) after completing the hydrothermal reaction, naturally cooling the reaction kettle to the room temperature, and then alternately cleaning through water and alcohol, and then collecting a product, drying the product, and finally obtaining the tetragonal NaV2O5.H2O nanosheet-like powder with a thickness in a range of 30-60 nm and a single crystal structure grown along a (002) crystal orientation.

Abstract: Provided is a method for the preparation of a porous hollow shell WO3/WS2 nanomaterial, comprising: (1) adding a hexavalent tungsten salt to a sol A comprising mesocarbon microbeads, and stirring to obtain a sol B; (2) drying and grinding the sol B, and then heating a resulting powder at 200-500° C. for 0.5-2 hours to obtain a porous hollow shell WO3 nanocrystalline material; (3) placing the porous hollow shell WO3 nanocrystalline material obtained by Step 2 and a sulfur powder separately in a vacuum furnace, controlling such that a degree of vacuum is ?0.01 to ?0.1 MPa and a temperature is 200-500° C., and reacting for 0.5-3 hours to obtain a WO3/WS2 porous hollow shell nanocrystalline material. Also provided is a porous hollow shell WO3/WS2 nanocrystalline material obtained by the method.