Patents by Inventor Llewellyn J. Leyshon
Llewellyn J. Leyshon has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6790585Abstract: The present invention relates to a method for developing an exposed high contrast photographic silver halide material, said photographic material comprising a support bearing at least one silver halide emulsion layer, containing at least one hydrazide nucleating agent. According to the invention, the nucleating agent has the formula (I) and the photographic material is developed in a hydroquinone-free developer, comprising a main developing agent of the ascorbic acid or ascorbic acid salt type, and as auxiliary developing agent a mixture of 3-pyrazolidones of which at least one has the formula (II): wherein at least one of the radicals R3 to R9 contains a solubilizing group. This combination enables photographic materials with ultrahigh contrast to be obtained.Type: GrantFiled: June 19, 2003Date of Patent: September 14, 2004Assignee: Eastman Kodak CompanyInventors: Jacques Roussilhe, Siu C. Tsoi, John D. Goddard, Llewellyn J. Leyshon
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Patent number: 6756189Abstract: Disclosed is a colour photographic element containing one or more cyan dye-forming couplers, a UV absorber and a specific class of stabiliser, and an imaging process used therewith. The element exhibits improved stability.Type: GrantFiled: October 11, 2002Date of Patent: June 29, 2004Assignee: Eastman Kodak CompanyInventors: Danuta Gibson, Llewellyn J. Leyshon, David Clarke
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Patent number: 6713226Abstract: The present invention relates to an ultrahigh contrast photographic material comprising a support bearing a silver halide emulsion layer, containing at least one hydrazide nucleating agent in the emulsion layer and/or a hydrophilic colloid layer, wherein the nucleating agent comprises 2 to 4 hydrazide moieties which are linked directly to one another or to one another by a linking group. The material optionally contains a booster compound in the emulsion layer or hydrophilic colloid layer to enhance the ultrahigh contrast and to promote activity, or a booster compound may be present in the developer solution. The nucleating agents show unexpectedly good nucleation and low sensitivity to variation in development conditions and their synthesis is consistent, efficient and robust.Type: GrantFiled: June 19, 2003Date of Patent: March 30, 2004Assignee: Eastman Kodak CompanyInventors: John D. Goddard, Llewellyn J. Leyshon
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Patent number: 6699650Abstract: There is provided a photographic element comprising at least one silver halide emulsion layer having associated therewith a novel phenolic cyan dye-forming coupler of formula (I) wherein X is hydrogen or a group that can be split off by the reaction of the coupler with an oxidised colour developing agent, and one of Y and Z is the group wherein each R is independently an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; R1 is hydrogen or an unsubstituted or substituted alkyl or aryl group, R2 is an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; R3 is hydrogen or an unsubstituted or substituted alkyl or aryl group, n is 1 or 2, and the otheType: GrantFiled: May 22, 2001Date of Patent: March 2, 2004Assignee: Eastman Kodak CompanyInventors: David Clarke, Llewellyn J. Leyshon, Katie E. Smith
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Publication number: 20040023149Abstract: The present invention relates to a method for developing an exposed high contrast photographic silver halide material, said photographic material comprising a support bearing at least one silver halide emulsion layer, containing at least one hydrazide nucleating agent.Type: ApplicationFiled: June 19, 2003Publication date: February 5, 2004Inventors: Jacques Roussilhe, Siu C. Tsoi, John D. Goddard, Llewellyn J. Leyshon
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Publication number: 20040005511Abstract: The present invention relates to an ultrahigh contrast photographic material comprising a support bearing a silver halide emulsion layer, containing at least one hydrazide nucleating agent in the emulsion layer and/or a hydrophilic colloid layer, wherein the nucleating agent comprises 2 to 4 hydrazide moieties which are linked directly to one another or to one another by a linking group. The material optionally contains a booster compound in the emulsion layer or hydrophilic colloid layer to enhance the ultrahigh contrast and to promote activity, or a booster compound may be present in the developer solution.Type: ApplicationFiled: June 19, 2003Publication date: January 8, 2004Applicant: Eastman Kodak CompanyInventors: John D. Goddard, Llewellyn J. Leyshon
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Publication number: 20030232289Abstract: Disclosed is a colour photographic element containing one or more cyan dye-forming couplers, a UV absorber and a specific class of stabiliser, and an imaging process used therewith. The element exhibits improved stability.Type: ApplicationFiled: October 11, 2002Publication date: December 18, 2003Applicant: Eastman Kodak CompanyInventors: Danuta Gibson, Llewellyn J. Leyshon, David Clarke
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Patent number: 6444412Abstract: The invention relates to a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith one or more dye-forming couplers and a stabilizer compound of formula (I): wherein R1 and R2 are independently selected from hydrogen or an unsubstituted or substituted alkyl, aryl, alkoxy, aryloxy or amino group or may combine to complete a 5-10 membered heterocyclic ring which may contain in addition to the silicon atom one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; each Z independently represents the atoms necessary to complete a substituted or unsubstituted arene or heteroaromatic ring system; X is a single bond or a linking group having a single atom which connects the arene rings or heteroaromatic ring systems; or X forms, together with substituents ortho to X on the arene rings or heteroaromatic ring systems, a fused unsubstituted or substituted 5-, 6- or 7-membered ring, which may contType: GrantFiled: August 21, 2001Date of Patent: September 3, 2002Assignee: Eastman Kodak CompanyInventors: David Clarke, Llewellyn J. Leyshon, Christopher P. Moore
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Patent number: 6444417Abstract: The invention relates to a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith (A) a cyan dye-forming coupler of formula (I) and (B) a bisphenol derivative compound of formula (II): wherein the substituents are as described in the specification.Type: GrantFiled: August 21, 2001Date of Patent: September 3, 2002Assignee: Eastman Kodak CompanyInventors: David Clarke, Llewellyn J. Leyshon, Katie E. Smith
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Publication number: 20020064735Abstract: The invention relates to a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith (A) a cyan dye-forming coupler of formula (I) and (B) a bisphenol derivative compound of formula (II): 1Type: ApplicationFiled: August 21, 2001Publication date: May 30, 2002Applicant: Eastman Kodak CompanyInventors: David Clarke, Llewellyn J. Leyshon, Katie E. Smith
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Publication number: 20020058212Abstract: The invention relates to a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith one or more dye-forming couplers and a stabilizer compound of formula (I): 1Type: ApplicationFiled: August 21, 2001Publication date: May 16, 2002Applicant: Eastman Kodak CompanyInventors: David Clarke, Llewellyn J. Leyshon, Christopher P. Moore
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Patent number: 6312881Abstract: In accordance with one embodiment of the invention, a photographic element is disclosed comprising a silver halide emulsion layer having associated therewith an acetanilide-based yellow dye forming coupler and a stabilizer compound of the formula S-I: wherein R0 represents an aryl or heterocyclic group; Ra is H or a substituent group; L represents an alkylene linking group and p represents 0 or 1; and Rb is a substituent group, provided that substituent groups represented by Ra and Rb may be joined to form a ring. The presence of substituted amine compounds of formula S-I improves the efficiency of dye formation reaction for acetanilide-based couplers. When used in combination with known bis-phenolic stabilizers, substantial improvements in the light stability of the image dyes can be also be obtained.Type: GrantFiled: January 14, 2000Date of Patent: November 6, 2001Assignee: Eastman Kodak CompanyInventors: Danuta Gibson, James S. Honan, Llewellyn J. Leyshon, Thomas A. Rosiek, Brian Thomas
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Patent number: 6245480Abstract: The invention relates to an ultrahigh contrast photographic material comprising a support bearing a silver halide emulsion layer, containing a hydrazide nucleating agent in the emulsion layer or a hydrophilic colloid layer, characterised in that the nucleating agent of formula (I) comprises (a) two nicotinamide moieties, which may be the same or different, which are linked by a linking group, and (b) a hydrazide moiety linked to only one of the nicotinamide moieties. The nucleator of formula (I) may be in combination with a nucleator of formula (II) which comprises a dimeric molecule comprising two monomers linked by a linking group, each monomer of which (a) may be the same or different and (b) comprises a hydrazide moiety and a nicotinamide moiety. The photographic material provides unexpectedly good nucleation in the absence of, or with reduced amounts of, booster and in a developer whose pH is variable, and further with lower chemical spread and pepper fog.Type: GrantFiled: June 12, 2000Date of Patent: June 12, 2001Assignee: Eastman Kodak CompanyInventors: Judith A. Bogie, Philip J. Coldrick, John D. Goddard, Llewellyn J. Leyshon
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Patent number: 6071683Abstract: The present invention relates to a silver halide photographic element comprising a dye-forming coupler of formula (I) ##STR1## wherein R.sup.1 is selected from an alkyl group, an aryl group, a 5-10 membered heterocyclic group containing one or more O, N or S atoms, each of which groups is unsubstituted or substituted, or a substituted amino group;R.sup.2 is an unsubstituted alkyl group having a secondary or tertiary carbon atom attached to the oxygen atom;X is hydrogen or a coupling-off group; andR.sup.3 is a substituent and n is 0 to 4; orwherein R.sup.2, as defined above, and an R.sup.3 substituent may together with the O atom form a 5-10 membered heterocyclic group which may contain one or more further heteroatoms selected from O, N and S, said group being unsubstituted or substituted; andwherein at least one of R.sup.1, R.sup.2 and R.sup.Type: GrantFiled: August 7, 1998Date of Patent: June 6, 2000Assignee: Eastman Kodak CompanyInventors: John D. Goddard, Danuta Gibson, Llewellyn J. Leyshon, Brian Thomas
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Patent number: 6004738Abstract: The invention provides a photographic element comprising a light sensitive silver halide emulsion layer containing a cyan dye-forming coupler of formula (I), a phenolic solvent of formula (II) and a bisphenol derivative compound of formula (III): wherein the substituents are as defined herein the specification.Type: GrantFiled: October 30, 1997Date of Patent: December 21, 1999Assignee: Eastman Kodak CompanyInventors: Philip T. Lau, Stanley W. Cowan, David Clarke, Llewellyn J. Leyshon
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Patent number: 5021333Abstract: A photographic yellow dye-forming coupler is represented by the formula: ##STR1## wherein: R.sup.1 is alkyl of 1 to 4 carbon atoms;ball is a ballast group of such size and configuration as to render the coupler nondiffusible in a photographic element;Y is CO, PO.sub.3 or SO.sub.2 ;X is an aryloxy coupling-off group; andn is 1 or, when Y is PO.sub.3, n is 2.Such a coupler is useful in a color photographic silver halide element and process to provide improved activity.Type: GrantFiled: August 24, 1990Date of Patent: June 4, 1991Assignee: Eastman Kodak CompanyInventors: Llewellyn J. Leyshon, Paul R. Buckland, Paul A. Burns
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Patent number: 4782011Abstract: A photographic element comprising a support having thereon at least one silver halide emulsion layer having associated therewith a dye-forming coupler and a dye stabilizer comprising a bisphenol derivative having two linked phenol rings, one of the phenolic hydroxy groups being substituted and at least one of the phenol rings being substituted.In a preferred embodiment, the bisphenol derivative has the following formula: ##STR1## wherein A is a substituted or unsubstituted alkyl, cycloalkyl, alkenyl, aryl, acyl, alkylsulfonyl or arylsulfonyl group;X is a single bond or a linking group selected from alkylidene, a heteroatom or sulfonyl; and,each R independently represents one or more substituents, each substituent independently being a substituted or unsubstituted alkyl, alkenyl, cycloalkyl or aryl group; or each R in combination with the benzene ring to which it is attached independently represents the atoms necessary to complete a fused ring system.Type: GrantFiled: April 8, 1987Date of Patent: November 1, 1988Assignee: Eastman Kodak CompanyInventors: John D. Goddard, Nigel E. Milner, Llewellyn J. Leyshon
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Patent number: 4777121Abstract: Pyrazolo[3,2-c]-s-triazole dye-forming couplers containing in the 6-position a substituted or unsubstituted tertiary alkyl group and in the 3-position a substituted or unsubstituted aryl group in photographic materials and processes provide dyes of improved light stability. These couplers are particularly useful in combination with alkoxybenzene dye image stabilizers.Type: GrantFiled: December 3, 1987Date of Patent: October 11, 1988Assignee: Eastman Kodak CompanyInventors: Paul R. Buckland, Llewellyn J. Leyshon
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Patent number: 4749645Abstract: A photographic element comprising a silver halide emulsion layer having associated therewith a compound having the formula ##STR1## wherein Y is --O--, --S--, --NH-- or --NR.sup.1 --;n is 0 or 1;each R.sup.1 independently is the residue of a phosphorus acid;each Z independently represents the atoms necessary to complete a substituted or unsubstituted benzene ring; and,X is a single bond or a linking group having a single atom which separates the two benzene rings.Use of the compound provides increased stability of the dye image obtained during photographic processing.Type: GrantFiled: September 30, 1987Date of Patent: June 7, 1988Assignee: Eastman Kodak CompanyInventors: John D. Goddard, Llewellyn J. Leyshon