Patents by Inventor Longjie Zhou

Longjie Zhou has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10749166
    Abstract: Provided is an all-solid-state lithium rechargeable cell, comprising: a) a cathode, wherein the cathode comprises: a1) a composite of VS4 and graphene; and a2) a solid catholyte; and b) a lithium-based anode. In particular, the all-solid-state lithium rechargeable cell of the present disclosure may exhibit high initial discharge capacities, high initial Coulombic efficiencies, good reversible capacities, excellent cycling stabilities, high energy densities as well as outstanding safeties.
    Type: Grant
    Filed: November 9, 2015
    Date of Patent: August 18, 2020
    Assignee: Robert Bosch GmbH
    Inventors: Xiaoxiong Xu, Xiayin Yao, Gang Peng, Longjie Zhou, Yunhua Chen
  • Publication number: 20190067684
    Abstract: Provided is an all-solid-state lithium rechargeable cell, comprising: a) a cathode, wherein the cathode comprises: a1) a composite of VS4 and graphene; and a2) a solid catholyte; and b) a lithium-based anode.
    Type: Application
    Filed: November 9, 2015
    Publication date: February 28, 2019
    Inventors: Xiaoxiong Xu, Xiayin Yao, Gang Peng, Longjie Zhou, Yunhua Chen
  • Patent number: 10109847
    Abstract: The present invention provides a sulfur-carbon composite material, said composite material comprising a porous carbon substrate containing both micropores and mesopores and sulfur, wherein the sulfur is only contained in the micropores of the carbon substrate. Moreover, a lithium-sulfur battery with its cathode comprising said sulfur-carbon composite material and the method for preparing such material is also provided.
    Type: Grant
    Filed: December 5, 2012
    Date of Patent: October 23, 2018
    Assignees: Robert Bosch GmbH, Institute of Chemistry, Chinese Academy of Sciences
    Inventors: Yuguo Guo, Huan Ye, Sen Xin, NaHong Zhao, Longjie Zhou
  • Patent number: 9972836
    Abstract: An SiOx/Si/C composite material, includes SiOx/Si composite particles and a carbon coating layer coated on the SiOx/Si composite particles. The SiOx/Si composite particles include nano-silicon crystallites embedded in an SiOx (0<x?2) amorphous matrix phase. The SiOx/Si composite particles have an Si:O molar ratio of 5:1-1.1:1, preferably 2:1-1.2:1. A process for producing an SiOx/Si/C composite material, includes a) milling SiO powder together with a metal reductant in a molar ratio of 125:1-10:1, preferably 2:11-5:1, b) totally removing the oxidation product of the metal reductant to obtain SiOx/Si composite particles, and c) coating the SiOx/Si composite particles with carbon to obtain the SiOx/Si/C composite material.
    Type: Grant
    Filed: April 27, 2013
    Date of Patent: May 15, 2018
    Assignee: Robert Bosch GmbH
    Inventors: Jun Yang, Xuejiao Feng, Jingjun Zhang, Longjie Zhou, Yuqian Dou
  • Patent number: 9960421
    Abstract: The present invention relates to a sulfur-containing composite with a core-shell structure for lithium-sulfur battery, wherein the substrate of the core contains macropores and/or mesopores and optionally micropores, and the substrate of the shell is a microporous coating layer; as well as a process for preparing said sulfur-containing composite, an electrode material and a lithium-sulfur battery comprising said sulfur-containing composite.
    Type: Grant
    Filed: September 30, 2013
    Date of Patent: May 1, 2018
    Assignees: Robert Bosch GmbH, Institute of Chemistry, Chinese Academy of Science
    Inventors: Yaxia Yin, Longjie Zhou, Bernd Schumann, Juan Zhang, NaHong Zhao, Yuguo Guo, Huan Ye
  • Patent number: 9819013
    Abstract: The present invention relates to a sulfur-carbon composite made from microporous-carbon-coated carbon nanotube (CNT@MPC) composites, in particular a sulfur-carbon composite, which comprises a carbon-carbon composite substrate (CNT@MPC) and sulfur loaded into said carbon-carbon composite substrate (CNT@MPC); as well as a method for preparing said sulfur-carbon composite, an electrode material and a lithium-sulfur battery comprising said sulfur-carbon composite.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: November 14, 2017
    Assignee: Robert Bosch GmbH
    Inventors: Yuguo Guo, Sen Xin, Nahong Zhao, Longjie Zhou
  • Patent number: 9773581
    Abstract: The present invention provides a cathode material for a Li—S battery. The cathod material comprises dehydrogenized acrylonitrile based polymer, sulfur and GNS (Graphene NanoSheet), wherein the cathode material particles are spherical, the content of dehydrogenized acrylonitrile based polymer is 20-79 wt %, the content of sulfur is 20-79 wt % and the content of GNS is 1-30 wt %. Also provided a method for preparing a cathode material, a cathode made of the cathod material and a Li—S battery comprising the cathode.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: September 26, 2017
    Assignees: Robert Bosch GmbH, Shanghai Jiaotong University
    Inventors: Jiulin Wang, Lichao Yin, Jun Yang, NaHong Zhao, Longjie Zhou
  • Patent number: 9748573
    Abstract: A mesoporous silicon compound includes a mesoporous silicon phase, a metal silicide phase, and a carbon phase. The metal silicide is embedded in mesoporous silicon particles, the surfaces of which are coated with a carbon layer. A weight ratio of elemental silicon to the metal element is from 2:3 to 900:1. The pores of the mesoporous silicon particles have a size distribution from two nanometers to eighty nanometers.
    Type: Grant
    Filed: August 3, 2012
    Date of Patent: August 29, 2017
    Assignee: Robert Bosch GmbH
    Inventors: Jun Yang, Pengfei Gao, Jingjun Zhang, Longjie Zhou
  • Publication number: 20170054143
    Abstract: The present invention relates to a method for preparing a graphene/HE-NCM composite, wherein more than one HE-NCM particles of the formula (1) xLi2MnO3.(1?x)LiNiyCozMn1-y-zO2, wherein 0<x<1, 0<y<1, and 0<z<1, are in electrical contact with each other via one or multiple graphene flakes, said method including: a) dispersing HE-NCM particles in a solution of graphene oxide by ultrasonication to give a dispersion; b) lyophilization of the dispersion to give a graphene oxide/HE-NCM composite; c) thermal decomposition of the graphene oxide/HE-NCM composite to give the graphene/HE-NCM composite. The present invention further relates to a graphene/HE-NCM composite for lithium ion battery prepared by said method, an electrode material and a lithium ion battery comprising said graphene/HE-NCM composite.
    Type: Application
    Filed: February 18, 2014
    Publication date: February 23, 2017
    Inventors: Mengyan Hou, Chuanling Li, Rongrong Jiang, Jinlong Liu, Lei Wang, Longjie Zhou, Yongyao Xia, Long Chen, Shaoshuai Guo
  • Patent number: 9577248
    Abstract: The present invention relates to a sulfur-carbon composite, comprising a pyrolysis microporous carbon sphere (PMCS) substrate and sulfur loaded into said pyrolysis microporous carbon sphere (PMCS) substrate; as well as a method for preparing said sulfur-carbon composite, an electrode material and a lithium-sulfur battery comprising said sulfur-carbon composite.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: February 21, 2017
    Assignee: Robert Bosch GmbH
    Inventors: Yuguo Guo, Sen Xin, Nahong Zhao, Longjie Zhou
  • Patent number: 9379381
    Abstract: A silicon/carbon composite comprises mesoporous silicon particles and carbon coating provided on the silicon particles, wherein the silicon particles have two pore size distribution of 2-4 nm and 20-40 nm. A process of preparing the silicon/carbon composite comprises the steps of preparing mesoporous silicon particles via a mechanochemical reaction between SiCl4 and Li33Si4 under ball milling and subsequent thermal treatment and washing process, and coating the mesoporous silicon particles with carbon. An anode for lithium ion battery comprises the silicon/carbon composite. A lithium ion battery comprises the silicon/carbon composite.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: June 28, 2016
    Assignee: Robert Bosch GmbH
    Inventors: Jun Yang, Xuejiao Feng, Jingjun Zhang, Longjie Zhou
  • Publication number: 20160079591
    Abstract: An SiOx/Si/C composite material, includes SiOx/Si composite particles and a carbon coating layer coated on the SiOx/Si composite particles. The SiOx/Si composite particles include nano-silicon crystallites embedded in an SiOx (0<x?2) amorphous matrix phase. The SiOx/Si composite particles have an Si:O molar ratio of 5:1-1.1:1, preferably 2:1-1.2:1. A process for producing an SiOx/Si/C composite material, includes a) milling SiO powder together with a metal reductant in a molar ratio of 125:1-10:1, preferably 2:11-5:1, b) totally removing the oxidation product of the metal reductant to obtain SiOx/Si composite particles, and c) coating the SiOx/Si composite particles with carbon to obtain the SiOx/Si/C composite material.
    Type: Application
    Filed: April 27, 2013
    Publication date: March 17, 2016
    Applicants: ROBERT BOSCH GMBH, SHANGHAI JIAOTONG UNIVERSITY
    Inventors: Jun Yang, Xuejiao Feng, Jingjun Zhang, Longjie Zhou, Yuqian Dou
  • Publication number: 20150303457
    Abstract: The present invention provides a cathode material for a Li—S battery. The cathod material comprises dehydrogenized acrylonitrile based polymer, sulfur and GNS (Graphene Nano Sheet), wherein the cathode material particles are spherical, the content of dehydrogenized acrylonitrile based polymer is 20-79 wt %, the content of sulfur is 20-79 wt % and the content of GNS is 1-30 wt %. Also provided a method for preparing a cathode material, a cathode made of the cathod material and a Li—S battery comprising the cathode.
    Type: Application
    Filed: November 30, 2012
    Publication date: October 22, 2015
    Inventors: Jiulin Wang, Lichao Yin, Jun Yang, NaHong Zhao, Longjie Zhou
  • Publication number: 20150303458
    Abstract: The present invention provides a sulfur-carbon composite material, said composite material comprising a porous carbon substrate containing both micropores and mesopores and sulfur, wherein the sulfur is only contained in the micropores of the carbon substrate. Moreover, a lithium-sulfur battery with its cathode comprising said sulfur-carbon composite material and the method for preparing such material is also provided.
    Type: Application
    Filed: December 5, 2012
    Publication date: October 22, 2015
    Inventors: Yuguo Guo, Huan Ye, Sen Xin, NaHong Zhao, Longjie Zhou
  • Publication number: 20150024276
    Abstract: A silicon/carbon composite comprises mesoporous silicon particles and carbon coating provided on the silicon particles, wherein the silicon particles have two pore size distribution of 2-4 nm and 20-40 nm. A process of preparing the silicon/carbon composite comprises the steps of preparing mesoporous silicon particles via a mechanochemical reaction between SiCl4 and Li33Si4 under ball milling and subsequent thermal treatment and washing process, and coating the mesoporous silicon particles with carbon. An anode for lithium ion battery comprises the silicon/carbon composite. A lithium ion battery comprises the silicon/carbon composite.
    Type: Application
    Filed: November 30, 2011
    Publication date: January 22, 2015
    Applicant: Robert Bosch GmbH
    Inventors: Jun Yang, Xuejiao Feng, Jingjun Zhang, Longjie Zhou
  • Publication number: 20140342233
    Abstract: The present invention relates to a sulfur-carbon composite, comprising a pyrolysis microporous carbon sphere (PMCS) substrate and sulfur loaded into said pyrolysis microporous carbon sphere (PMCS) substrate; as well as a method for preparing said sulfur-carbon composite, an electrode material and a lithium-sulfur battery comprising said sulfur-carbon composite.
    Type: Application
    Filed: November 29, 2011
    Publication date: November 20, 2014
    Applicant: ROBERT BOSCH GMBH
    Inventors: Yuguo Guo, Sen Xin, Nahong Zhao, Longjie Zhou
  • Publication number: 20140342234
    Abstract: The present invention relates to a sulfur-carbon composite made from microporous-carbon-coated carbon nanotube (CNT@MPC) composites, in particular a sulfur-carbon composite, which comprises a carbon-carbon composite substrate (CNT@MPC) and sulfur loaded into said carbon-carbon composite substrate (CNT@MPC); as well as a method for preparing said sulfur-carbon composite, an electrode material and a lithium-sulfur battery comprising said sulfur-carbon composite.
    Type: Application
    Filed: November 29, 2011
    Publication date: November 20, 2014
    Applicant: ROBERT BOSCH GMBH
    Inventors: Yuguo Guo, Sen Xin, Nahong Zhao, Longjie Zhou
  • Publication number: 20140234721
    Abstract: A mesoporous silicon compound includes a mesoporous silicon phase, a metal silicide phase, and a carbon phase. The metal silicide is embedded in mesoporous silicon particles, the surfaces of which are coated with a carbon layer. A weight ratio of elemental silicon to the metal element is from 2:3 to 900:1. The pores of the mesoporous silicon particles have a size distribution from two nanometers to eighty nanometers.
    Type: Application
    Filed: August 3, 2012
    Publication date: August 21, 2014
    Applicant: Robert Bosch GmbH
    Inventors: Jun Yang, Pengfei Gao, Jingjun Zhang, Longjie Zhou
  • Publication number: 20130335179
    Abstract: High corrosion resistant sintered NdFeB magnets are provided with a composition by mass % of NdxRx1Fe100-(x+x1+y+y1+z)TyMy1Bz, where 24?x?33, 0?x1?15, 1.43?y?16.43, 0.1?y1?0.6, 0.91?z?1.07, R is one or more selected from the group consisting of Dy, Tb, Pr, Ce and Gd, T is one or more selected from the group consisting of Co, Cu and Al, M is one or more selected from the group consisting of Nb, Zr, Ti, Cr and Mo, and M is distributed within the grain boundary phase of the NdFeB magnets.
    Type: Application
    Filed: October 14, 2011
    Publication date: December 19, 2013
    Inventors: Renjie Chen, Aru Yan, Dong Li, Qiaoying Zhou, Longjie Zhou, Alexandra Wilde
  • Publication number: 20130316244
    Abstract: An electrode is formed of a ternary composite of silicon, carbon, and carbon filter foil, for lithium ion batteries. Also described is a method for manufacturing silicon/carbon/carbon fiber foil composite electrode for lithium batteries, including: mixing silicon and an organic substance capable of forming carbon after heat treatment, in a solvent, to form a slurry; immersing the carbon fiber foil in said slurry until the slurry coats on and penetrates into the carbon fiber foil; and heating the carbon fiber foil, which has been coated and penetrated with the slurry, in an inert gas atmosphere or all inert gas atmosphere mixed with a reductive gas at a temperature of at least 400° C. for at least 2 hours.
    Type: Application
    Filed: November 23, 2011
    Publication date: November 28, 2013
    Inventors: Jingjun Zhang, Longjie Zhou, Jun Yang, Haiping Jia