Patents by Inventor Loren D. Brake

Loren D. Brake has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6103653
    Abstract: This invention provides an attrition resistant catalyst composition and method for producing such composition. The catalyst is comprised of an acidic zeolite, rho or chabazite, and a particulate binder, kaolin, bentonite, alpha-alumina, or titania, which can be optionally modified by treatment with a compound containing Si, Al, P or B. This invention further provides a process for producing methylamines, preferably dimethylamine, comprising reacting methanol and/or dimethyl ether and ammonia in the presence of a catalytic amount of an attrition resistant catalyst of the invention.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: August 15, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Konstantinos Kourtakis, Horacio Enrique Bergna, George Carl Sonnichsen, David Richard Corbin, Loren D. Brake
  • Patent number: 6100211
    Abstract: This invention provides an attrition resistant catalyst composition and method for producing such composition. The catalyst is comprised of an acidic zeolite, rho or chabazite, and a particulate binder, kaolin, bentonite, alpha-alumina, or titania, which can be optionally modified by treatment with a compound containing Si, Al, P or B. This invention further provides a process for producing methylamines, preferably dimethylamine, comprising reacting methanol and/or dimethyl ether and ammonia in the presence of a catalytic amount of an attrition resistant catalyst of the invention.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: August 8, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Konstantinos Kourtakis, Horacio Enrique Bergna, George Carl Sonnichsen, David Richard Corbin, Loren D. Brake
  • Patent number: 5569785
    Abstract: This invention provides an attrition resistant catalyst composition and method for producing such composition. The catalyst is comprised of an acidic zeolite, rho or chabazite, and a particulate binder, kaolin, bentonite, alpha-alumina, or titania, which can be optionally modified by treatment with a compound containing Si, Al, P or B.This invention further provides a process for producing methylamines, preferably dimethylamine, comprising reacting methanol and/or dimethyl ether and ammonia in the presence of a catalytic amount of an attrition resistant catalyst of the invention.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: October 29, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Konstantinos Kourtakis, Horacio E. Bergna, George C. Sonnichsen, David R. Corbin, Loren D. Brake
  • Patent number: 5482909
    Abstract: The present invention relates to an improved catalyst for the selective synthesis of monomethylamine (MMA) and dimethylamine (DMA) at the expense of trimethylamine (TMA) for a starting feed of methanol and/or dimethyl ether and ammonia. The current industrial catalyst for this process is a standard SiO.sub.2 /Al.sub.2 O.sub.3 material. The present invention combines this standard catalyst with microporous carbon molecular sieves (CMS) to form a composite material (i.e., a CMS/SiO.sub.2 /Al.sub.2 O.sub.3 material) with higher selectivity for the desired products MMA and DMA. The invention also relates to methods of making the improved catalyst and a process of using the improved catalyst material in the production of MMA and DMA.
    Type: Grant
    Filed: July 21, 1994
    Date of Patent: January 9, 1996
    Assignees: University of Delaware, E. I. Du Pont de Nemours & Co., Inc.
    Inventors: Henry C. Foley, George C. Sonnichsen, Loren D. Brake, Ravindra K. Mariwala, Davis S. Lafyatis
  • Patent number: 5470814
    Abstract: The present invention relates to an improved catalyst for the selective synthesis of monomethylamine (MMA) and dimethylamine (DMA) at the expense of trimethylamine (TMA) for a starting feed of methanol and/or dimethyl ether and ammonia. The current industrial catalyst for this process is a standard SiO.sub.2 /Al.sub.2 O.sub.3 material. The present invention combines this standard catalyst with microporous carbon molecular sieves (CMS) to form a composite material (i.e., a CMS/SiO.sub.2 /Al.sub.2 O.sub.3 material) with higher selectivity for the desired products MMA and DMA. The invention also relates to methods of making the improved catalyst and a process of using the improved catalyst material in the production of MMA and DMA.
    Type: Grant
    Filed: July 21, 1994
    Date of Patent: November 28, 1995
    Assignees: University of Delaware, E. I. Du Pont de Nemours & Co., Inc.
    Inventors: Henry C. Foley, George C. Sonnichsen, Loren D. Brake, Ravindra K. Mariwala, David S. Lafyatis
  • Patent number: 5354893
    Abstract: The present invention relates to an improved catalyst for the selective synthesis of monomethylamine (MMA) and dimethylamine (DMA) at the expense of trimethylamine (TMA) for a starting feed of methanol and/or dimethyl ether and ammonia. The current industrial catalyst for this process is a standard SiO.sub.2 /Al.sub.2 O.sub.3 material. The present invention combines this standard catalyst with microporous carbon molecular sieves (CMS) to form a composite material (i.e., a CMS/SiO.sub.2 /Al.sub.2 O.sub.3 material) with higher selectivity for the desired products MMA and DMA. The invention also relates to methods of making the improved catalyst and a process of using the improved catalyst material in the production of MMA and DMA.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: October 11, 1994
    Assignees: The University of Delaware, E. I. Du Pont de Nemours Company, Inc.
    Inventors: Henry C. Foley, George C. Sonnichsen, Loren D. Brake, Ravindra K. Mariwala, David S. Lafyatis
  • Patent number: 5268507
    Abstract: Depolymerizing high molecular weight polyhydroxy acid by reacting with an amine to produce an amide derivative.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: December 7, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Loren D. Brake
  • Patent number: 5264617
    Abstract: Depolymerizing polyhydroxy acid by heating with the alcohol of 1-6 carbon atoms in the presence of an acid catalyst to produce an alkyl ester.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: November 23, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Loren D. Brake
  • Patent number: 5264614
    Abstract: Polyhydroxyacid (PHA) is recovered by heating under pressure in the presence of a C.sub.1 -C.sub.6 alcohol, and optionally also water.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: November 23, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Loren D. Brake
  • Patent number: 5264626
    Abstract: Rapid recovery from waste of high molecular weight polyhydroxyacid content by depolymerizing the PHA in acidic water.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: November 23, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Loren D. Brake, Narayanan S. Subramanian
  • Patent number: 5229528
    Abstract: Recovery of polyhydroxy acids (PHAs) from waste containing high molecular weight polyhydroxy acid polymer by depolymerizing the PHA in water at elevated temperature and pressure.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: July 20, 1993
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Loren D. Brake, Narayanan S. Subramanian
  • Patent number: 5091584
    Abstract: A formaldehyde/amine adduct useful in water treatment having improved stability made by reacting formaldehyde and a secondary amine, limiting the water content of the adduct to no more than 30 weight percent, optionally, adding an alcohol.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: February 25, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Loren D. Brake
  • Patent number: 5030762
    Abstract: A formaldehyde/amine adduct useful in water treatment having improved stability made by reacting formaldehyde and a secondary amine, limiting the water content of the adduct to no more that 30 weight percent, optionally, adding an alcohol.
    Type: Grant
    Filed: February 28, 1989
    Date of Patent: July 9, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Loren D. Brake
  • Patent number: 4605788
    Abstract: In the preparation of dimethyl ether by the catalytic dehydration of methanol, reaction rate is enhanced and catalyst coking and byproduct formation are significantly reduced when an aluminosilicate containing a high level of alumina is used as the catalyst.
    Type: Grant
    Filed: August 26, 1985
    Date of Patent: August 12, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Loren D. Brake
  • Patent number: 4595785
    Abstract: In the preparation of dimethyl ether by the catalytic dehydration of methanol, reaction rate is enhanced and catalyst coking and byproduct formation are significantly reduced when an aluminotitanate containing 0.1-20% of titania and 80-99.9% of alumina is used as the catalyst.
    Type: Grant
    Filed: March 4, 1985
    Date of Patent: June 17, 1986
    Assignee: E. I. DuPont de Nemours and Company
    Inventor: Loren D. Brake
  • Patent number: 4370503
    Abstract: In the catalytic preparation of methylamines from methanol or dimethyl ether and ammonia using a silica-alumina catalyst, catalyst coking and byproduct formation are reduced and reaction speed and catalyst thermal stability are enhanced when a catalyst containing a high level of alumina is used.
    Type: Grant
    Filed: March 24, 1981
    Date of Patent: January 25, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Loren D. Brake