Abstract: The present invention relates to ionomers comprising a reaction product of the reaction between a halogenated isoolefin copolymer and at least one phosphorus based nucleophile comprising at least one pendant vinyl group. The present invention also relates to a method of preparing and curing these ionomers.

Abstract: The present invention relates to ionomers comprising a reaction product of the reaction between a halogenated isoolefin copolymer and at least one phosphorus based nucleophile comprising at least one pendant vinyl group. The present invention also relates to a method of preparing and curing these ionomers.

Abstract: The present invention provides an optically transparent peroxide cured article made from a peroxide curable butyl rubber ionomer comprising repeating units derived from the reaction product of one or more multiolefin monomers and at least one nitrogen or phosphorous based nucleophile comprising a pendant vinyl group. A process is also disclosed for making the optically transparent article.

Abstract: Surface modification methods based on a combination of plasma and chemical treatments render an unfilled butyl rubber surface highly reactive toward organosilanes, allowing formation of an organosilane self-assembled monolayer (SAM). Plasma oxidation of the butyl rubber surface followed by vapour deposition of SiCl4 produces a hydrophilic surface suitable for anchoring organosilanes. Fabrication of SAMs on this hydrophilic butyl rubber surface with n-octadecyltrichlorosilane (OTS) and trichloro(1H,1H,2H,2H-perfluorooctyl)silane (FOTS) via vapour deposition resulted in a 15% and 25% decrease in gas permeability, respectively, with no change in optical transparency of the butyl rubber.

Abstract: This invention relates to elastomeric coatings for electronics. Disclosed is a electronic device comprising a substrate layer, a conductive layer and an encapsulant layer. The encapsulant layer comprises at least a butyl rubber material. The butyl rubber encapsulant prevents a change in resistivity of the conductive layer following exposure to nitric acid vapour for 12 hours or hydrochloric acid vapour for 10 hours.

Abstract: The present invention relates to functionalized copolymers of isoolefins and olefinic monomers, particularly to azidated copolymers. The present invention also relates to methods of preparing such azidated copolymers. The functionalized copolymers are used in various technology areas such as surface modification, adhesion, drug delivery, compatibilization of polymer blends or motor oil and fuel additives, and in providing clean cured products without contaminant leaching and/or side products.

Abstract: The present invention relates to curing of polymers, particularly to self curing of polymers. The present invention provides a process for curing of copolymers of isoolefins and olefinic monomers. The process includes the step of reacting the copolymer with an azidation reagent to form an azidated copolymer and then heating the azidated copolymer at a suitable temperature to cure the polymer.

Abstract: The present invention relates to ionomers comprising a reaction product of the reaction between a halogenated isoolefin copolymer and at least one phosphorus based nucleophile comprising at least one pendant vinyl group. The present invention also relates to a method of preparing and curing these ionomers.

Abstract: The present invention relates to arborescent polymers comprising isoolefins and styrenic monomers, as well as processes for making same. In particular, the invention relates to highly branched block copolymers comprising an arborescent core with a high glass-transition temperature (Tg) and branches attached to the core terminated in polymer endblock segments with a low Tg. The copolymers of the invention desirably exhibit thermoplastic elastomeric properties and, in one embodiment, are desirably suited to biomedical applications.

Abstract: The present invention relates to a liquid ?-olefin vinyl acetate compound containing a liquid ?-olefin vinyl acetate copolymer. Compositions according to the present invention have improved resistance to premature vulcanization as well as good physical properties and aging resistance. The present invention is also directed to a vulcanized compound containing a liquid ethylene vinyl acetate copolymer.

Abstract: The present invention relates to an elastomer rubber composition containing a carboxylated rubber polymer and a fluorinated additive. The present invention is also directed to an elastomer composition containing a hydrogenated carboxylated nitrile rubber and a fluorinated additive.

Abstract: The invention relates to peroxide cured thermoplastic vulcanizates comprising a thermoplastic and an isomonoolefin-multiolefin elastomer, such as butyl rubber. More particularly, the invention relates to peroxide cured thermoplastic vulcanizates wherein the elastomer comprises at least 3.5 mol % of multiolefin in order to facilitate peroxide curing. The thermoplastic vulcanizates according to the present invention are useful in the preparation of shaped articles for high purity applications, such as condenser caps, medical components and fuel cell components.

Abstract: The present invention relates to an elastomer rubber composition containing a carboxylated rubber polymer and a fluorinated additive. The present invention is also directed to an elastomer composition containing a hydrogenated carboxylated nitrile rubber and a fluorinated additive.

Abstract: The present invention relates to polymer composites containing at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) in the range of from 50–30 at least one filler and optionally at least one cross-linking agent, a process for preparing said polymer composite wherein at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) in the range of from 50–30, at least one filler and optionally at least one cross-linking agent are mixed and a process for the manufacture of a shaped article including the step of injection molding a polymer composite containing at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) in the range of from 50-30, at least one filler and at least one cross-linking agent.

Abstract: The present invention relates to a liquid ?-olefin vinyl acetate compound containing a liquid ?-olefin vinyl acetate copolymer. Compositions according to the present invention have improved resistance to premature vulcanization as well as good physical properties and aging resistance. The present invention is also directed to a vulcanized compound containing a liquid ethylene vinyl acetate copolymer.

Abstract: The present invention relates to an elastomeric composition containing a rubber and an oxidized polyethylene. The present invention also relates to elastomeric compositions containing a carboxylated nitrile rubber and an oxidized polyethylene. Compositions according to the present invention have improved physical properties including, tensile strength, tear strength, and improved scorch resistance. The present invention is also directed to an elastomer composition containing hydrogenated carboxylated nitrile rubber and a low molecular weight oxidized polyethylene having improved physical properties and scorch resistance.

Abstract: The present invention relates to a rubber compound containing at least one hydrogenated carboxylated nitrile rubber, at least one hydrogenated nitrile rubber and at least one magnetic compound, a curable rubber compound containing said rubber compound and at least one vulcanization agent and a magnetic shaped article containing said rubber compound.

Abstract: The present invention relates to a polymer blend containing of at least two different hydrogenated nitrile rubbers and at least one olefin-vinylacetate or olefin-acrylate rubber, a rubber compound containing said polymer blend and at least one filler, a curable rubber compound containing said rubber compound and at least one vulcanization agent and a shaped article containing said rubber compound.

Abstract: The present invention relates to polymer composites containing at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) in the range of from 50-30 at least one filler and optionally at least one cross-linking agent, a process for preparing said polymer composite wherein at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) in the range of from 50-30, at least one filler and optionally at least one cross-linking agent are mixed and a process for the manufacture of a shaped article including the step of injection molding a polymer composite containing at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) in the range of from 50-30, at least one filler and at least one cross-linking agent.

Abstract: A conjugate is formed by blending a polyamide with a hydrogenated carboxylated nitrile rubber at elevated temperature. The conjugate is readily formable by molding or extrusion, and it displays excellent heat, oil-resistant and barrier properties that render it suitable for use, for example, in many automotive under-the-hood applications.