Abstract: This invention provides a number of phosphorous and arsenic reducing agents to eliminate gas formation and polymerization of Li/MnO2 and other lithium cells caused by the formation of dialcohol. The phosphorous reducing agents when added to the Li/MnO2 and other lithium battery electrolytes cause the phosphorous compound and alcohol to react and produce ether and orthophosphorous acid, which prevents gas formation and the polymerization of Li/MnO2 cells caused by the formation of dialcohol. The preferred reducing agent is phosphoric acid tri-ester. The arsenic reducing agents when added to the Li/MnO2 and other lithium battery electrolytes cause the arsenic compound and alcohol to react and produce ether and orthoarsenic acid, which also prevents gas formation and the polymerization of Li/MnO2 cells caused by the formation of dialcohol.

Abstract: A method is provided of preparing an impregnated cathode with enhanced thionic emission from a porous billet by impregnating the billed with a suitable impregnant in the presence of an oxygen deficient compound. Additives such as Ir, Os, and Rh react in such a way as to increase emission by reacting to generate oxygen deficient compounds such as WO.sub.2. Moreover, intermediate oxygen sufficient products formed in the chemical reactions can be used as impregnants providing they generate oxygen deficient compounds in the presence of the active emissive material.

Abstract: A method is provided of preparing an impregnated cathode with enhanced thionic emission from a porous billet by impregnating the billed with a suitable impregnant in the presence of an oxygen deficient compound. Additives such as Ir, Os, and Rh react in such a way as to increase emission by reacting to generate oxygen deficient compounds such as WO.sub.2. Moreover, intermediate oxygen sufficient products formed in the chemical reactions can be used as impregnants providing they generate oxygen deficient compounds in the presence of the active emissive material.

Abstract: A thermionic cathode having an overcoating of emissive material having a position including a mixture Aluminum Tungstate and Scandium Tungstate which react, when heated, to provide the cathode with enhanced electron emissions.

Abstract: A method is provided of preparing an impregnated cathode with enhanced thionic emission from a porous billet by impregnating the billet with a suitable impregnant in the presence of an oxygen deficient compound.

Abstract: An improved scandate cathode is made from a hollow cylinder of a metal that ill not react with Sc.sub.2 (WO.sub.4).sub.3. The first step in making such a cathode is to insert a metal plug at the bottom of the cylinder to a height that will allow the remaining volume of the cylinder to be filled with the reactants WO.sub.3 and Sc.sub.2 O.sub.3. Next, the reactants are heated in a vacuum to about 1100.degree. C. to form the reaction product Sc.sub.2 (WO.sub.4).sub.3. The plug is then removed from the cylinder, the cylinder is inverted, and BaH.sub.2 is added to the volume of the cylinder that had been occupied by the plug. Finally, the cylinder is heated to decompose the BaH.sub.2.

Abstract: A long life high current density cathode is made from a mixture of aluminum xide and tungsten oxide powders by processing the powders into a fused powder, adding barium hydride to the fused powder, inverting the fused powder and heating to decompose the barium hydride and obtain barium metal.

Abstract: A cathode is made from a mixture of tungsten and iridium powders using a ction product formed from reacting a Group III A metal powder with barium peroxide powder as an impregnant.

Abstract: A long life high current density cathode is made from a mixture of tungsten nd iridium powders by processing the mixture of powders with an activator into a porous billet, and then impregnating the billet with a quaternary compound including barium, oxygen, a metal selected from the group consisting of osmium, iridium, rhodium, and rhenium, and a metal selected from the group consisting of strontium, calcium, scandium and titanium, by firing the billet in a dry hydrogen furnace at a temperature at which the impregnant melts.

Abstract: A cathode is made from tungsten powder using as an impregnant the product rmed from adding about 1 mole of a member selected from the group consisting of zirconium, zirconium dioxide, hafnium, hafnium dioxide, uranium, uranium dioxide, titanium, and titanium dioxide to about 50 to about 100 moles of a compound selected from the group consisting of Ba.sub.3 Al.sub.2 O.sub.6, Ba.sub.3 WO.sub.6, and Ba.sub.4 Al.sub.2 O.sub.7.

Abstract: A long life high current density cathode is made from a mixture of tungsten nd iridium powders by processing the mixture of powders with an activator into a porus billet, and then impregnating the billet with a mixture of barium peroxide and a coated emitter by firing the billet in a dry hydrogen furnace at a temperature at which the impregnant melts.

Abstract: A cathode is made from a mixture of tungsten and iridium powders using a ction product formed from reacting barium peroxide with an excess of tungsten as the impregnant.

Abstract: A tungsten-iridium billet is impregnated with a chemical mixture of barium xide, strontium oxide, and aluminum oxide, the impregnated billet heated, and the surface of the impregnated billet desired for emission exposed to an overcoating of rhodium.

Abstract: A cathode is made from a mixture of tungsten and aluminum powders.

Abstract: A long life high current density cathode is made from a mixture of tungsten nd iridium powders by processing the mixture of powders with an activator into a porous billet, and then impregnating the billet with a low melting point impregnant by firing the billet in a dry hydrogen furnace at a temperature at which the impregnant melts.

Abstract: A cathode is made from a mixture of tungsten and iridium powders using a ium iridiate formed from barium peroxide and iridium oxide as the impregnant.

Abstract: A cathode is made from a mixture of tungsten and iridium powders using a ium peroxide containing material as the impregnant.

Abstract: A long life high current density cathode is made from a mixture of tungsten nd iridium powders using a bariumaluminoiridiate as the impregnant.

Abstract: A long life high current density cathode is made from a mixture of tungsten nd iridium powders using a barium iridiate as the impregnant by processing the mixture of powders with an activator into a porous billet, and then impregnating the billet with a barium iridiate by firing the billet in a dry hydrogen furnace at a temperature at which the impregnant melts.

Abstract: A cathode is made from a mixture of tungsten and iridium powders using a ontium peroxide containing material as the impregnant.