Abstract: Fluorine is substituted for other halogen atoms on the 1-carbon atom of a compound which contains a 1,1,1-trihalomethyl group (trichloromethyl) by contacting said compound or a precursor thereof with liquid HF in the presence of a mixture of antimony pentahalide with a least an approximately equimolar amount of antimony trihalide. The antimony halides may be added as the chlorides and in situ converted to fluorides and/or chlorofluorides, which are believed to be the essential agents. Additional starting material and antimony pentahalide may be added in the course of the reaction which proceeds stepwise. When the reactant is 1,1,1,3-tetrachloropropane the reaction can be continued to produce 3-chloro-1,1,1-trifluoropropane which, upon reaction with alkali, yields 3,3,3-trifluoropropene, of known utility in making fluorosilicones.

Abstract: Fluorine is substituted for other halogen atoms on the 1-carbon atom of a compound which contains a 1,1,1-trihalomethyl group (trichloromethyl) by contacting said compound or a precursor thereof with liquid HF in the presence of a mixture of antimony pentahalide with at least an approximately equimolar amount of antimony trihalide. The antimony halides may be added as the chlorides and in situ converted to fluorides and/or chlorofluorides, which are believed to be the essential agents. Additional starting material and antimony pentahalide may be added in the course of the reaction which proceeds stepwise. When the reactant is 1,1,1,3-tetrachloropropane the reaction can be continued to produce 3-chloro-1,1,1-trifluoropropane which, upon reaction with alkali, yields 3,3,3-trifluoropropane, of known utility in making fluorosilicones.