Abstract: The present disclosure presents nanostructure-based localized surface plasmon resonance systems and related methods.

Abstract: A method for dynamic characterization of an electrochemical system (such as a lithium-ion battery) is provided, comprising exciting an electrochemical system with a plurality of double-pulse sequences, each comprising a constant-current discharge pulse, a constant-current charge pulse having the same pulse width and pulse amplitude, and a zero-current period between the pulses; and calculating an impulse response, using a recursive or matrix-based method, to dynamically characterize the electrochemical system. A constant state-of-charge is maintained in the electrochemical system. Therefore the signal-to-noise ratio is high due to the repetition of the driving sequence. This method may be employed for on-line determination of the impedance spectrum of an electrochemical system, since the cycling profile can be easily integrated into charge/discharge profiles. Batteries (and other devices) can be diagnosed at high speed and with high accuracy. The double-pulse sequence is robust for fairly noisy systems.

Abstract: Some variations provide a method for real-time estimation of state of charge and state of power of a battery, comprising: (a) cycling a battery with a driving profile; (b) utilizing a recursive algorithm that relates battery terminal voltage to battery current, wherein the algorithm includes open-circuit voltage and a finite-impulse-response filter to dynamically model kinetic voltage; measuring the battery terminal voltage and the battery current at least at a first time and a second time during cycling; calculating battery open-circuit voltage and finite-impulse-response filter parameters; calculating battery state of charge based on the open-circuit voltage; and calculating battery state of power based on the open-circuit voltage and the finite-impulse-response filter parameters. An extended Kalman filtering technique is incorporated for real-time updating of FIR model parameters.

Abstract: A method for dynamic characterization of an electrochemical system (such as a lithium-ion battery) is provided, comprising exciting an electrochemical system with a plurality of double-pulse sequences, each comprising a constant-current discharge pulse, a constant-current charge pulse having the same pulse width and pulse amplitude, and a zero-current period between the pulses; and calculating an impulse response, using a recursive or matrix-based method, to dynamically characterize the electrochemical system. A constant state-of-charge is maintained in the electrochemical system. Therefore the signal-to-noise ratio is high due to the repetition of the driving sequence. This method may be employed for on-line determination of the impedance spectrum of an electrochemical system, since the cycling profile can be easily integrated into charge/discharge profiles. Batteries (and other devices) can be diagnosed at high speed and with high accuracy. The double-pulse sequence is robust for fairly noisy systems.