Abstract: The present invention describes a composition of thermosetting resins, in particular epoxy resins, combined with modified polysiloxane networks to form a continuos interpenetrated network characterized by the presence of metals such as boron, molybdenum and tungsten, linked to Si via an oxygen atom. These compositions, can be used to make adhesives, composites and coatings that exhibit excellent hardness, chemical resistance, fast curing, damp tolerance and are self priming with slow release of a corrosion inhibitor or of functional additives. The material of the present invention can be used in particular as a coating, in the marine field, for yachts and for large metal vessels, such as oil tankers and more in particular for cargo or ballast tanks and on hulls. It can be used for the maintenance and protection of trains, automotive vehicles and in electric applications such as for the production of dielectric shields and in those fields where high performance is needed.